**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-44-4 |2,2-Dichlorodiethylether | >99 | 203-870-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 10 26/27/28 68
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Very toxic by inhalation, in contact with skin and if
swallowed.Possible risk of irreversible effects.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which
increases the flow of tears). May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes mild skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation. May
cause irritation of the respiratory tract with burning pain in the
nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
Prolonged inhalation may cause respiratory tract inflammation and
lung damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
POISON material. If inhaled, get medical aid immediately. Remove
victim to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors are
heavier than air and may travel to a source of ignition and flash
back. Vapors can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. Use water spray to cool
and disperse vapors and protect personnel.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Do not
get in eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Use only with adequate
ventilation. Keep away from heat, sparks and flame. Do not breathe
vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Containers should be dated when opened and tested
periodically for the presence of peroxides. Should crystals form in
a peroxidizable liquid, peroxidation may have occurred and the
product should be considered extremely dangerous. In this instance,
the container should only be opened remotely by professionals. All
peroxidizable substances should be stored away from heat and light
and be protected from ignition sources.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 111-44-4:
United States OSHA: ; 15 ppm Ceiling; 90 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 29 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 59 mg/m3 VLE
France - VME: 5 ppm VME; 30 mg/m3 VME
Germany: 10 ppm TWA; 59 mg/m3 TWA
Germany: Skin absorber
Japan: 15 ppm OEL; 88 mg/m3 OEL
Malaysia: 5 ppm TWA; 29 mg/m3 TWA
Netherlands: 5 ppm MAC; 30 mg/m3 MAC
Russia: 2 mg/m3 TWA
Spain: 5 ppm VLA-ED; 30 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 60 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: pungent odor
pH: Not available.
Vapor Pressure: 1.55 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 178.5 deg C @ 760 mm Hg
Freezing/Melting Point: -52 deg C
Autoignition Temperature: 369 deg C ( 696.20 deg F)
Flash Point: 55 deg C ( 131.00 deg F)
Explosion Limits, lower: 2.7 vol %
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density: 1.2200 g/cm3
Molecular Formula: C4H8Cl2O
Molecular Weight: 143.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May form peroxides
in the absence of inhibitors. Forms hydrochloric acid with water.
Conditions to Avoid:
Ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-44-4: KN0875000
LD50/LC50:
CAS# 111-44-4: Dermal, guinea pig: LD50 = 300 mg/kg; Draize test,
rabbit, eye: 100 mg Severe; Inhalation, mouse: LC50 = 650 mg/m3/2H;
Inhalation, rat: LC50 = 330 mg/m3/4H; Inhalation, rat: LC50 = 330
mg/m3; Oral, mouse: LD50 = 209 mg/kg; Oral, mouse: LD50 = 112 mg/kg;
Oral, rabbit: LD50 = 126 mg/kg; Oral, rat: LD50 = 75 mg/kg; Skin,
rabbit: LD50 = 90 mg/kg.
Carcinogenicity:
2,2-Dichlorodiethylether -
California: carcinogen, initial date 4/1/88
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Bluegill/Sunfish: LC50 = 600 mg/L; 96 Hr.; Static
conditionWater flea Daphnia: EC50 = 238 mg/L; 48 Hr.; Static
condition
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 2,2'-DICHLORODIETHYL ETHER
Hazard Class: 6.1 (3)
UN Number: 1916
Packing Group: II
IMO
Shipping Name: 2,2'-DICHLORODIETHYL ETHER
Hazard Class: 6.1 (3)
UN Number: 1916
Packing Group: II
RID/ADR
Shipping Name: 2,2-DICHLOROETHYL ETHER
Hazard Class: 6.1
UN Number: 1916
Packing group: II
USA RQ: CAS# 111-44-4: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 10 Flammable.
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 27 Take off immediately all contaminated clothing.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 111-44-4: 2
Canada
CAS# 111-44-4 is listed on Canada's NDSL List.
CAS# 111-44-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-44-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/08/1999 Revision #3 Date: 7/12/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N-Butyl Chloride
| 109-69-3 |
|
2,4-Hexadiene, 99%, Mixture of Isomers
| 592-46-1 |
|
3,5-Dichloro-2-Hydroxybenzenesulfonyl Chloride, 90-95%(Cl)
| 23378-88-3 |
|
1-Cyano-3-methylisothiourea, sodium salt, 94+%
| 67944-71-2 |
|
3-Methylbutyraldehyde, 98%
| 590-86-3 |
|
Styrene-d8, stabilized, 98+ atom% D
| 100-42-5 |
|
Calcium Iodide Tetrahydrate, 99%
| 13640-62-5 |
|
n-Butylamine
| 109-73-9 |
|
Glycine Tert-Butyl Ester Hydrochloride 99% (tlc)
| 27532-96-3 |
|
1-Bromo-2,4,5-Trifluorobenzene 99%
| 327-52-6 |
|
Decane
| 124-18-5 |
|
4'-Methoxyacetanilide, 99+%
| 51-66-1 |
|
2,6-Pyridinedimethanol, 98%
| 1195-59-1 |
|
4-Cyanobenzyltriphenylphosphonium chloride, 98%
| 20430-33-5 |
|
3-Amino-2,4,6-Triiodobenzoic Acid, 99+%
| 3119-15-1 |
|
Tert.-butyl sulfide, 98%
| 107-47-1 |
|
Methoxyacetic acid, 98%
| 625-45-6 |
|
2,4-Dichloropyrimidine, 97%
| 3934-20-1 |
|
2-Propanethiol, 98%
| 75-33-2 |
|
2,2'-Dimethoxybiphenyl, 98%
| 4877-93-4 |
|
3,5-Diiodo-l-tyrosine
| 300-39-0 |
|
Butyl 4-hydroxybenzoate
| 94-26-8 |
|
Ethynylestradiol 3-methyl ether, 97%
| 72-33-3 |
|
Triallylamine, 98%
| 102-70-5 |
|
1-Hydroxy-2,2,4,5,5-pentamethyl-3-imidazoline, 98%
| 39753-73-6 |
|
11-alpha-Hydroxyprogesterone, 95%
| 80-75-1 |
|
4-Phenylbutyric Acid, 97% (Titr.)
| 1821-12-1 |
|
Triisopentylamine, 99% (GC)
| 645-41-0 |
|
2'-Deoxycytidine Monohydrate, 99+%
| 951-77-9 |
|
8-(Diethylamino)Octyl 3,4,5-Trimethoxy-Benzoate Hydrochloride, 97%
| 53460-46-1 |
|
Hexamethylbenzene
| 87-85-4 |
|
2,2-Dichlorodiethylether, 99+%
| 111-44-4 |
|
3,3'-Carbonylbis(7-methoxycoumarin)
| 64267-17-0 |
|
2-Benzoylpyridine, 99+%
| 91-02-1 |
|
d-(-)-s-Acetyl-beta-mercaptoisobutyric acid, 99%
| 76497-39-7 |
|
1,3-Propanedithiol, 98% (gc)
| 109-80-8 |
|
3-Methylphenethyl Alcohol , 98%
| 1875-89-4 |
|
Oxalyl dihydrazide, 98%
| 996-98-5 |
|
Diphenylboric acid, ethanolamine complex 98%
| 524-95-8 |
|
N-Methylmorpholine
| 109-02-4 |
|
Hexacosane, 99%
| 630-01-3 |
|
Chromotropic Acid, Sodium Salt(Techn), 60% (Titr.)
| 3888-44-6 |
|
2-Chlorobenzyl Alcohol, 99%
| 17849-38-6 |
|
Di-n-octylamine (Pract), 95% (GC)
| 1120-48-5 |
|
1,2,4-Benzenetricarboxylic anhydride, 97%
| 552-30-7 |
|
Triphenylcarbenium hexafluorophosphate, 99%
| 437-17-2 |
|
(2R,3S)-2-Amino-3-Phenylthiobutanoic Acid, Hydrochloride, 99+% (80%
| 0-01-1 |
|
Hexafluorophosphoric Acid, 60 WT% Solution in Water
| 7732-18-5 |
|
4-(4-Anilinophenylazo)Benzenesulfonic Acid Sodium Salt, Indicator
| 554-73-4 |
|
5-Bromo-2-thiophenecarboxaldehyde, 97%
| 4701-17-1 |
|
|