**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-73-9 |n-Butylamine | >98 | 203-699-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 20/21/22 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation, in contact with skin and if
swallowed. Causes severe burns.
Potential Health Effects
Eye:
Causes severe eye burns. May result in corneal injury. Low vapor
concentrations may cause a temporary visual disturbance known as
'blue haze' or 'halo vision'.
Skin:
Harmful if absorbed through the skin. Causes skin burns.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Harmful if inhaled. May cause irritation of the respiratory tract
with burning pain in the nose and throat, coughing, wheezing,
shortness of breath and pulmonary edema.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Containers may explode in
the heat of a fire. May accumulate static electrical charges, and may
cause ignition of its own vapors. Extremely flammable liquid and
vapor. Vapor may cause flash fire. Vapors are heavier than air and
may travel to a source of ignition and flash back. Vapors can spread
along the ground and collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, "alcohol resistant" foam, or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation. Use water spray to cool
and disperse vapors, protect personnel, and dilute spills to form
nonflammable mixtures.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Do not
get in eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Take
precautionary measures against static discharges. Keep container
tightly closed. Discard contaminated shoes. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Use only with adequate ventilation.
Keep away from heat, sparks and flame. Do not breathe vapor or mist.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Isolate from oxidizing
materials and acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use adequate
general or local exhaust ventilation to keep airborne concentrations
below the permissible exposure limits.
Exposure Limits
CAS# 109-73-9:
United States OSHA: ; 5 ppm Ceiling; 15 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 15 mg/m3 VLE
France - VLE: 5 ppm VLE; 15 mg/m3 VLE
Germany: 5 ppm TWA; 15 mg/m3 TWA
Germany: Skin absorber
Japan: 5 ppm Ceiling; 15 mg/m3 Ceiling
Malaysia: 5 ppm Ceiling; 15 mg/m3 Ceiling
Russia: 10 mg/m3 TWA
Spain: 5 ppm VLA-EC (all isomers); 15 mg/m3 VLA-EC (all isomers)
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. Follow the OSHA
respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or
European Standard EN 149 approved respirator if
exposure limits are exceeded or if irritation or
other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: ammonia-like
pH: 11.8 (0.1M soln)
Vapor Pressure: 82 mm Hg @ 20 deg C
Viscosity: 0.5 mPa s 20 C
Boiling Point: 78 deg C
Freezing/Melting Point: -49 deg C
Autoignition Temperature: 312 deg C ( 593.60 deg F)
Flash Point: -12 deg C ( 10.40 deg F)
Explosion Limits, lower: 1.7%
Explosion Limits, upper: 9.8%
Decomposition Temperature: Not available.
Solubility in water: Soluble.
Specific Gravity/Density: 0.74 (water=1)
Molecular Formula: C4H11N
Molecular Weight: 73.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Becomes yellow over time.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, copper.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, nitrogen oxides (NOx) and ammonia
(NH3), amines.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-73-9: EO2975000
LD50/LC50:
CAS# 109-73-9: Dermal, guinea pig: LD50 = 500 uL/kg; Draize test,
rabbit, eye: 250 ug/24H Severe; Inhalation, mouse: LC50 = 800
mg/m3/2H; Oral, mouse: LD50 = 430 mg/kg; Oral, rat: LD50 = 366
mg/kg; Skin, rabbit: LD50 = 850 uL/kg.
Carcinogenicity:
n-Butylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 268 mg/L; 96 Hr.; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 24-32 mg/L; 96 Hr.; Static ConditionWater
flea Daphnia: LC50 = 75 mg/L; 24 Hr.; Static ConditionBacteria:
Phytobacterium phosphoreum: EC50 = 18.3-41.1 mg/L; 5,15,25,30
Minutes; Microtox test, 15 degrees C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: n-BUTYLAMINE
Hazard Class: 3 (8)
UN Number: 1125
Packing Group: II
IMO
Shipping Name: normal-BUTYLAMINE
Hazard Class: 3.2 (8)
UN Number: 1125
Packing Group: II
RID/ADR
Shipping Name: n-BUTYLAMINE
Hazard Class: 3
UN Number: 1125
Packing group: II
USA RQ: CAS# 109-73-9: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 35 Causes severe burns.
Safety Phrases:
S 3 Keep in a cool place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 109-73-9: 1
Canada
CAS# 109-73-9 is listed on Canada's DSL List.
CAS# 109-73-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-73-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/01/1999 Revision #4 Date: 4/07/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N-Butyl Chloride
| 109-69-3 |
|
2,4-Hexadiene, 99%, Mixture of Isomers
| 592-46-1 |
|
3,5-Dichloro-2-Hydroxybenzenesulfonyl Chloride, 90-95%(Cl)
| 23378-88-3 |
|
1-Cyano-3-methylisothiourea, sodium salt, 94+%
| 67944-71-2 |
|
3-Methylbutyraldehyde, 98%
| 590-86-3 |
|
Styrene-d8, stabilized, 98+ atom% D
| 100-42-5 |
|
Calcium Iodide Tetrahydrate, 99%
| 13640-62-5 |
|
n-Butylamine
| 109-73-9 |
|
Glycine Tert-Butyl Ester Hydrochloride 99% (tlc)
| 27532-96-3 |
|
1-Bromo-2,4,5-Trifluorobenzene 99%
| 327-52-6 |
|
Decane
| 124-18-5 |
|
4'-Methoxyacetanilide, 99+%
| 51-66-1 |
|
2,6-Pyridinedimethanol, 98%
| 1195-59-1 |
|
4-Cyanobenzyltriphenylphosphonium chloride, 98%
| 20430-33-5 |
|
3-Amino-2,4,6-Triiodobenzoic Acid, 99+%
| 3119-15-1 |
|
Tert.-butyl sulfide, 98%
| 107-47-1 |
|
Methoxyacetic acid, 98%
| 625-45-6 |
|
2,4-Dichloropyrimidine, 97%
| 3934-20-1 |
|
2-Propanethiol, 98%
| 75-33-2 |
|
2,2'-Dimethoxybiphenyl, 98%
| 4877-93-4 |
|
3,5-Diiodo-l-tyrosine
| 300-39-0 |
|
Butyl 4-hydroxybenzoate
| 94-26-8 |
|
Ethynylestradiol 3-methyl ether, 97%
| 72-33-3 |
|
Triallylamine, 98%
| 102-70-5 |
|
1-Hydroxy-2,2,4,5,5-pentamethyl-3-imidazoline, 98%
| 39753-73-6 |
|
11-alpha-Hydroxyprogesterone, 95%
| 80-75-1 |
|
4-Phenylbutyric Acid, 97% (Titr.)
| 1821-12-1 |
|
Triisopentylamine, 99% (GC)
| 645-41-0 |
|
2'-Deoxycytidine Monohydrate, 99+%
| 951-77-9 |
|
8-(Diethylamino)Octyl 3,4,5-Trimethoxy-Benzoate Hydrochloride, 97%
| 53460-46-1 |
|
Hexamethylbenzene
| 87-85-4 |
|
2,2-Dichlorodiethylether, 99+%
| 111-44-4 |
|
3,3'-Carbonylbis(7-methoxycoumarin)
| 64267-17-0 |
|
2-Benzoylpyridine, 99+%
| 91-02-1 |
|
d-(-)-s-Acetyl-beta-mercaptoisobutyric acid, 99%
| 76497-39-7 |
|
1,3-Propanedithiol, 98% (gc)
| 109-80-8 |
|
3-Methylphenethyl Alcohol , 98%
| 1875-89-4 |
|
Oxalyl dihydrazide, 98%
| 996-98-5 |
|
Diphenylboric acid, ethanolamine complex 98%
| 524-95-8 |
|
N-Methylmorpholine
| 109-02-4 |
|
Hexacosane, 99%
| 630-01-3 |
|
Chromotropic Acid, Sodium Salt(Techn), 60% (Titr.)
| 3888-44-6 |
|
2-Chlorobenzyl Alcohol, 99%
| 17849-38-6 |
|
Di-n-octylamine (Pract), 95% (GC)
| 1120-48-5 |
|
1,2,4-Benzenetricarboxylic anhydride, 97%
| 552-30-7 |
|
Triphenylcarbenium hexafluorophosphate, 99%
| 437-17-2 |
|
(2R,3S)-2-Amino-3-Phenylthiobutanoic Acid, Hydrochloride, 99+% (80%
| 0-01-1 |
|
Hexafluorophosphoric Acid, 60 WT% Solution in Water
| 7732-18-5 |
|
4-(4-Anilinophenylazo)Benzenesulfonic Acid Sodium Salt, Indicator
| 554-73-4 |
|
5-Bromo-2-thiophenecarboxaldehyde, 97%
| 4701-17-1 |
|
|