**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 104-86-9 |4-Chlorobenzylamine | 98 | 203-245-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Air sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Contact with eyes may cause severe irritation,
and possible eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Place under an inert
atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from
heat, sparks and flame. Do not get on skin or in eyes. Do not ingest
or inhale. Handle under an inert atmosphere. Store protected from
air. Discard contaminated shoes. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Corrosives area. Do not expose to air.
Store under an inert atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 104-86-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear almost colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 215 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 90 deg C ( 194.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: immiscible with water
Specific Gravity/Density: 1.1640g/cm3
Molecular Formula: C7H8ClN
Molecular Weight: 141.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to air, excess
heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide,
nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 104-86-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Chlorobenzylamine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 8
UN Number: 2735
Packing Group: III
IMO
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing Group: III
RID/ADR
Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.
Hazard Class: 8
UN Number: 2735
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 104-86-9: No information available.
Canada
CAS# 104-86-9 is listed on Canada's NDSL List.
CAS# 104-86-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 104-86-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/10/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chlorobenzotrichloride, 99%
| 2136-89-2 |
|
1,5-Diaminopentane, 98%
| 462-94-2 |
|
2-Methyl-5-Phenylbenzoxazole, 97%
| 61931-68-8 |
|
Meta-nitro-alpha,alpha,alpha-trifluoro- toluene, 99%
| 98-46-4 |
|
4-Methylsulphonylphenylhydrazine Hydrochloride, 95+%
| 877-66-7 |
|
Ethyl cyclohexylacetate, 98+%
| 5452-75-5 |
|
Glycylglycine, 99+% (titr.)
| 556-50-3 |
|
2,3-Dimethoxybenzyl Alcohol 99%
| 5653-67-8 |
|
1-Pyrrolidinecarbonyl chloride, 99%
| 1192-63-8 |
|
2,2,2-Trifluoroethanol-d3, 99+ atom% D
| 75-89-8 |
|
N-Alpha-Benzoyl-L-Arginine Ethyl Ester Hydrochloride, 99+%
| 2645-08-1 |
|
3-Methylpyrazole, 99%
| 1453-58-3 |
|
Lithium Aluminum Hydride, Tablets, 97%
| 16853-85-3 |
|
Europium(iii) oxide, 99.99%
| 1308-96-9 |
|
Cerium(IV) Oxide, 99.9%
| 1306-38-3 |
|
(1,2-Dibromoethyl)benzene, 99%
| 93-52-7 |
|
(S)-(-)-2-Amino-3-(1-naphthyl)propanoic acid, 99% (99% e.e.)
| 55516-54-6 |
|
Acid Green 41
| 4430-16-4 |
|
1,9-Dibromononane, 97%
| 4549-33-1 |
|
2-Ethoxyethyl Ether, 98+%
| 112-36-7 |
|
4-Chlorobenzylamine,98 %
| 104-86-9 |
|
Omega-aminocaprylic acid 99+%
| 1002-57-9 |
|
1-Naphthoyl chloride, 99%
| 879-18-5 |
|
1-Phenyl-1H-tetrazole-5-thiol cyclohexylamine salt, 99+% (titr.)
| 102853-44-1 |
|
Formaldehyde solution 37%
| 50-00-0 |
|
DL-Alanine-Beta-Naphthylamide Hydrochloride, 98%
| 74144-49-3 |
|
N-Acetyl-D-Galactosamine, 97%
| 14131-60-3 |
|
Nitromethane-d3, 99 atom % d
| 13031-32-8 |
|
Bromohydroquinone (Techn), 90% (GC)
| 583-69-7 |
|
Phenylsilane, 98%
| 694-53-1 |
|
l-(+)-Arabinose, 99+%
| 87-72-9 |
|
1,4-Cyclohexanedione, 98%
| 637-88-7 |
|
2,2-Diphenyl-1-Picrylhydrazyl, 97% (UV-Vis)
| 1898-66-4 |
|
Strontium Hydroxide Octahydrate, 98%
| 18480-07-4 |
|
1,4-Dichloro-2-fluorobenzene, 99+%
| 348-59-4 |
|
3,5-Dichloro-4-Pyridinol, 95%
| 17228-71-6 |
|
4-Cyanophenyl 4-Heptylbenzoate, 99+%
| 38690-76-5 |
|
alpha-Bromo-p-xylene, 98%
| 104-81-4 |
|
n-Methylphenethylamine, 99%
| 589-08-2 |
|
Phenyl-P-Benzoquinone, 99% (UV-Vis)
| 363-03-1 |
|
Diethyl 2,4-Dimethylpyrrole-3,5-Dicarboxylate, 97%
| 2436-79-5 |
|
Methyl isobutyrate, 99%
| 547-63-7 |
|
1-Piperidinecarbonitrile, 97+%
| 1530-87-6 |
|
(-)-Limonene, 92%
| 5989-54-8 |
|
Triethyl Methanetricarboxylate,98%
| 6279-86-3 |
|
Ethyl chloroacetate, p.a.
| 105-39-5 |
|
1,2:5,6-di-o-isopropylidene-alpha-d-ribo-3 -hexulofuranose, 98%
| 2847-00-9 |
|
Acenaphthenequinone, 95%
| 82-86-0 |
|
alpha,alpha'-Dibromo-o-xylene, 96%
| 91-13-4 |
|
DL-Cysteine, 99%
| 3374-22-9 |
|
|