**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 98-46-4 |3-nitrobenzotrifluoride | 99.0 | 202-670-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 98-46-4:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: straw-colored
Odor: aromatic odor
pH: Not available.
Vapor Pressure: .3 mm Hg @25C
Viscosity: Not available.
Boiling Point: 200.0 - 205.0 deg C @ 760.00m
Freezing/Melting Point: -5 deg C
Autoignition Temperature: Not available.
Flash Point: 87 deg C ( 188.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.4360g/cm3
Molecular Formula: C7H4F3NO2
Molecular Weight: 191.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen fluoride
gas, nitrogen, fluorine.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 98-46-4: XT3500000
LD50/LC50:
CAS# 98-46-4: Inhalation, mouse: LC50 = 880 mg/m3/2H; Inhalation,
rat: LC50 = 870 mg/m3; Oral, mouse: LD50 = 520 mg/kg; Oral, rat:
LD50 = 610 mg/kg.
Carcinogenicity:
3-nitrobenzotrifluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITROBENZOTRIFLUORIDES
Hazard Class: 6.1
UN Number: 2306
Packing Group: II
IMO
Shipping Name: NITROBENZOTRIFLUORIDES, LIQUID
Hazard Class: 6.1
UN Number: 2306
Packing Group: II
RID/ADR
Shipping Name: NITROBENZOTRIFLUORIDES
Hazard Class: 6.1
UN Number: 2306
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 98-46-4: No information available.
Canada
CAS# 98-46-4 is listed on Canada's NDSL List.
CAS# 98-46-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 98-46-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chlorobenzotrichloride, 99%
| 2136-89-2 |
|
1,5-Diaminopentane, 98%
| 462-94-2 |
|
2-Methyl-5-Phenylbenzoxazole, 97%
| 61931-68-8 |
|
Meta-nitro-alpha,alpha,alpha-trifluoro- toluene, 99%
| 98-46-4 |
|
4-Methylsulphonylphenylhydrazine Hydrochloride, 95+%
| 877-66-7 |
|
Ethyl cyclohexylacetate, 98+%
| 5452-75-5 |
|
Glycylglycine, 99+% (titr.)
| 556-50-3 |
|
2,3-Dimethoxybenzyl Alcohol 99%
| 5653-67-8 |
|
1-Pyrrolidinecarbonyl chloride, 99%
| 1192-63-8 |
|
2,2,2-Trifluoroethanol-d3, 99+ atom% D
| 75-89-8 |
|
N-Alpha-Benzoyl-L-Arginine Ethyl Ester Hydrochloride, 99+%
| 2645-08-1 |
|
3-Methylpyrazole, 99%
| 1453-58-3 |
|
Lithium Aluminum Hydride, Tablets, 97%
| 16853-85-3 |
|
Europium(iii) oxide, 99.99%
| 1308-96-9 |
|
Cerium(IV) Oxide, 99.9%
| 1306-38-3 |
|
(1,2-Dibromoethyl)benzene, 99%
| 93-52-7 |
|
(S)-(-)-2-Amino-3-(1-naphthyl)propanoic acid, 99% (99% e.e.)
| 55516-54-6 |
|
Acid Green 41
| 4430-16-4 |
|
1,9-Dibromononane, 97%
| 4549-33-1 |
|
2-Ethoxyethyl Ether, 98+%
| 112-36-7 |
|
4-Chlorobenzylamine,98 %
| 104-86-9 |
|
Omega-aminocaprylic acid 99+%
| 1002-57-9 |
|
1-Naphthoyl chloride, 99%
| 879-18-5 |
|
1-Phenyl-1H-tetrazole-5-thiol cyclohexylamine salt, 99+% (titr.)
| 102853-44-1 |
|
Formaldehyde solution 37%
| 50-00-0 |
|
DL-Alanine-Beta-Naphthylamide Hydrochloride, 98%
| 74144-49-3 |
|
N-Acetyl-D-Galactosamine, 97%
| 14131-60-3 |
|
Nitromethane-d3, 99 atom % d
| 13031-32-8 |
|
Bromohydroquinone (Techn), 90% (GC)
| 583-69-7 |
|
Phenylsilane, 98%
| 694-53-1 |
|
l-(+)-Arabinose, 99+%
| 87-72-9 |
|
1,4-Cyclohexanedione, 98%
| 637-88-7 |
|
2,2-Diphenyl-1-Picrylhydrazyl, 97% (UV-Vis)
| 1898-66-4 |
|
Strontium Hydroxide Octahydrate, 98%
| 18480-07-4 |
|
1,4-Dichloro-2-fluorobenzene, 99+%
| 348-59-4 |
|
3,5-Dichloro-4-Pyridinol, 95%
| 17228-71-6 |
|
4-Cyanophenyl 4-Heptylbenzoate, 99+%
| 38690-76-5 |
|
alpha-Bromo-p-xylene, 98%
| 104-81-4 |
|
n-Methylphenethylamine, 99%
| 589-08-2 |
|
Phenyl-P-Benzoquinone, 99% (UV-Vis)
| 363-03-1 |
|
Diethyl 2,4-Dimethylpyrrole-3,5-Dicarboxylate, 97%
| 2436-79-5 |
|
Methyl isobutyrate, 99%
| 547-63-7 |
|
1-Piperidinecarbonitrile, 97+%
| 1530-87-6 |
|
(-)-Limonene, 92%
| 5989-54-8 |
|
Triethyl Methanetricarboxylate,98%
| 6279-86-3 |
|
Ethyl chloroacetate, p.a.
| 105-39-5 |
|
1,2:5,6-di-o-isopropylidene-alpha-d-ribo-3 -hexulofuranose, 98%
| 2847-00-9 |
|
Acenaphthenequinone, 95%
| 82-86-0 |
|
alpha,alpha'-Dibromo-o-xylene, 96%
| 91-13-4 |
|
DL-Cysteine, 99%
| 3374-22-9 |
|
|