**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 547-63-7 |Methyl isobutyrate | 99% | 208-929-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation and possible burns.
Skin:
May cause skin irritation and possible burns.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Containers may explode in the heat of a fire.
Flammable liquid and vapor. May polymerize explosively when involved
in a fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. A vapor suppressing foam may be used to reduce
vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Ground and bond containers when
transferring material. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep away from heat,
sparks and flame. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Keep containers tightly
closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 547-63-7:
Russia: 10 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear almost colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 49 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 90 deg C @ 760.00mm Hg
Freezing/Melting Point: -84 - -85 deg C
Autoignition Temperature: Not available.
Flash Point: 55.4 deg F ( 13.00 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluable, miscible in alcohol and ether
Specific Gravity/Density: .8910g/cm3
Molecular Formula: C5H10O2
Molecular Weight: 102.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, strong oxidants, exposure to flame.
Incompatibilities with Other Materials:
Oxidizing agents - bases - acids - heat.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 547-63-7: NQ5425000
LD50/LC50:
CAS# 547-63-7: Inhalation, mouse: LC50 = 25500 mg/m3/2H.
Carcinogenicity:
Methyl isobutyrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 547-63-7: No information available.
Canada
CAS# 547-63-7 is listed on Canada's DSL List.
CAS# 547-63-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 547-63-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/26/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chlorobenzotrichloride, 99%
| 2136-89-2 |
|
1,5-Diaminopentane, 98%
| 462-94-2 |
|
2-Methyl-5-Phenylbenzoxazole, 97%
| 61931-68-8 |
|
Meta-nitro-alpha,alpha,alpha-trifluoro- toluene, 99%
| 98-46-4 |
|
4-Methylsulphonylphenylhydrazine Hydrochloride, 95+%
| 877-66-7 |
|
Ethyl cyclohexylacetate, 98+%
| 5452-75-5 |
|
Glycylglycine, 99+% (titr.)
| 556-50-3 |
|
2,3-Dimethoxybenzyl Alcohol 99%
| 5653-67-8 |
|
1-Pyrrolidinecarbonyl chloride, 99%
| 1192-63-8 |
|
2,2,2-Trifluoroethanol-d3, 99+ atom% D
| 75-89-8 |
|
N-Alpha-Benzoyl-L-Arginine Ethyl Ester Hydrochloride, 99+%
| 2645-08-1 |
|
3-Methylpyrazole, 99%
| 1453-58-3 |
|
Lithium Aluminum Hydride, Tablets, 97%
| 16853-85-3 |
|
Europium(iii) oxide, 99.99%
| 1308-96-9 |
|
Cerium(IV) Oxide, 99.9%
| 1306-38-3 |
|
(1,2-Dibromoethyl)benzene, 99%
| 93-52-7 |
|
(S)-(-)-2-Amino-3-(1-naphthyl)propanoic acid, 99% (99% e.e.)
| 55516-54-6 |
|
Acid Green 41
| 4430-16-4 |
|
1,9-Dibromononane, 97%
| 4549-33-1 |
|
2-Ethoxyethyl Ether, 98+%
| 112-36-7 |
|
4-Chlorobenzylamine,98 %
| 104-86-9 |
|
Omega-aminocaprylic acid 99+%
| 1002-57-9 |
|
1-Naphthoyl chloride, 99%
| 879-18-5 |
|
1-Phenyl-1H-tetrazole-5-thiol cyclohexylamine salt, 99+% (titr.)
| 102853-44-1 |
|
Formaldehyde solution 37%
| 50-00-0 |
|
DL-Alanine-Beta-Naphthylamide Hydrochloride, 98%
| 74144-49-3 |
|
N-Acetyl-D-Galactosamine, 97%
| 14131-60-3 |
|
Nitromethane-d3, 99 atom % d
| 13031-32-8 |
|
Bromohydroquinone (Techn), 90% (GC)
| 583-69-7 |
|
Phenylsilane, 98%
| 694-53-1 |
|
l-(+)-Arabinose, 99+%
| 87-72-9 |
|
1,4-Cyclohexanedione, 98%
| 637-88-7 |
|
2,2-Diphenyl-1-Picrylhydrazyl, 97% (UV-Vis)
| 1898-66-4 |
|
Strontium Hydroxide Octahydrate, 98%
| 18480-07-4 |
|
1,4-Dichloro-2-fluorobenzene, 99+%
| 348-59-4 |
|
3,5-Dichloro-4-Pyridinol, 95%
| 17228-71-6 |
|
4-Cyanophenyl 4-Heptylbenzoate, 99+%
| 38690-76-5 |
|
alpha-Bromo-p-xylene, 98%
| 104-81-4 |
|
n-Methylphenethylamine, 99%
| 589-08-2 |
|
Phenyl-P-Benzoquinone, 99% (UV-Vis)
| 363-03-1 |
|
Diethyl 2,4-Dimethylpyrrole-3,5-Dicarboxylate, 97%
| 2436-79-5 |
|
Methyl isobutyrate, 99%
| 547-63-7 |
|
1-Piperidinecarbonitrile, 97+%
| 1530-87-6 |
|
(-)-Limonene, 92%
| 5989-54-8 |
|
Triethyl Methanetricarboxylate,98%
| 6279-86-3 |
|
Ethyl chloroacetate, p.a.
| 105-39-5 |
|
1,2:5,6-di-o-isopropylidene-alpha-d-ribo-3 -hexulofuranose, 98%
| 2847-00-9 |
|
Acenaphthenequinone, 95%
| 82-86-0 |
|
alpha,alpha'-Dibromo-o-xylene, 96%
| 91-13-4 |
|
DL-Cysteine, 99%
| 3374-22-9 |
|
|