**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 694-53-1 |Phenylsilane | 98% | 211-772-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.The toxicological properties of this material have
not been fully investigated.Moisture sensitive.Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Ingestion of large amounts may cause CNS
depression.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Aspiration may
lead to pulmonary edema. Vapors may cause dizziness or suffocation.
May cause burning sensation in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Flush skin with
plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Flammable liquid
and vapor. Will be easily ignited by heat, sparks or flame.
Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
For large fires, use water spray, fog or alcohol-resistant foam. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from heat and
flame. Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use
adequate general or local explosion-proof ventilation to keep
airborne levels to acceptable levels.
Exposure Limits
CAS# 694-53-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 120 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 7 deg C ( 44.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .8770g/cm3
Molecular Formula: C6H8Si
Molecular Weight: 108.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 694-53-1: VV4825000
LD50/LC50:
CAS# 694-53-1: Inhalation, mouse: LC50 = 14500 mg/m3/2H; Oral,
mouse: LD50 = 700 mg/kg.
Carcinogenicity:
Phenylsilane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 694-53-1: No information available.
Canada
CAS# 694-53-1 is listed on Canada's NDSL List.
CAS# 694-53-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 694-53-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chlorobenzotrichloride, 99%
| 2136-89-2 |
|
1,5-Diaminopentane, 98%
| 462-94-2 |
|
2-Methyl-5-Phenylbenzoxazole, 97%
| 61931-68-8 |
|
Meta-nitro-alpha,alpha,alpha-trifluoro- toluene, 99%
| 98-46-4 |
|
4-Methylsulphonylphenylhydrazine Hydrochloride, 95+%
| 877-66-7 |
|
Ethyl cyclohexylacetate, 98+%
| 5452-75-5 |
|
Glycylglycine, 99+% (titr.)
| 556-50-3 |
|
2,3-Dimethoxybenzyl Alcohol 99%
| 5653-67-8 |
|
1-Pyrrolidinecarbonyl chloride, 99%
| 1192-63-8 |
|
2,2,2-Trifluoroethanol-d3, 99+ atom% D
| 75-89-8 |
|
N-Alpha-Benzoyl-L-Arginine Ethyl Ester Hydrochloride, 99+%
| 2645-08-1 |
|
3-Methylpyrazole, 99%
| 1453-58-3 |
|
Lithium Aluminum Hydride, Tablets, 97%
| 16853-85-3 |
|
Europium(iii) oxide, 99.99%
| 1308-96-9 |
|
Cerium(IV) Oxide, 99.9%
| 1306-38-3 |
|
(1,2-Dibromoethyl)benzene, 99%
| 93-52-7 |
|
(S)-(-)-2-Amino-3-(1-naphthyl)propanoic acid, 99% (99% e.e.)
| 55516-54-6 |
|
Acid Green 41
| 4430-16-4 |
|
1,9-Dibromononane, 97%
| 4549-33-1 |
|
2-Ethoxyethyl Ether, 98+%
| 112-36-7 |
|
4-Chlorobenzylamine,98 %
| 104-86-9 |
|
Omega-aminocaprylic acid 99+%
| 1002-57-9 |
|
1-Naphthoyl chloride, 99%
| 879-18-5 |
|
1-Phenyl-1H-tetrazole-5-thiol cyclohexylamine salt, 99+% (titr.)
| 102853-44-1 |
|
Formaldehyde solution 37%
| 50-00-0 |
|
DL-Alanine-Beta-Naphthylamide Hydrochloride, 98%
| 74144-49-3 |
|
N-Acetyl-D-Galactosamine, 97%
| 14131-60-3 |
|
Nitromethane-d3, 99 atom % d
| 13031-32-8 |
|
Bromohydroquinone (Techn), 90% (GC)
| 583-69-7 |
|
Phenylsilane, 98%
| 694-53-1 |
|
l-(+)-Arabinose, 99+%
| 87-72-9 |
|
1,4-Cyclohexanedione, 98%
| 637-88-7 |
|
2,2-Diphenyl-1-Picrylhydrazyl, 97% (UV-Vis)
| 1898-66-4 |
|
Strontium Hydroxide Octahydrate, 98%
| 18480-07-4 |
|
1,4-Dichloro-2-fluorobenzene, 99+%
| 348-59-4 |
|
3,5-Dichloro-4-Pyridinol, 95%
| 17228-71-6 |
|
4-Cyanophenyl 4-Heptylbenzoate, 99+%
| 38690-76-5 |
|
alpha-Bromo-p-xylene, 98%
| 104-81-4 |
|
n-Methylphenethylamine, 99%
| 589-08-2 |
|
Phenyl-P-Benzoquinone, 99% (UV-Vis)
| 363-03-1 |
|
Diethyl 2,4-Dimethylpyrrole-3,5-Dicarboxylate, 97%
| 2436-79-5 |
|
Methyl isobutyrate, 99%
| 547-63-7 |
|
1-Piperidinecarbonitrile, 97+%
| 1530-87-6 |
|
(-)-Limonene, 92%
| 5989-54-8 |
|
Triethyl Methanetricarboxylate,98%
| 6279-86-3 |
|
Ethyl chloroacetate, p.a.
| 105-39-5 |
|
1,2:5,6-di-o-isopropylidene-alpha-d-ribo-3 -hexulofuranose, 98%
| 2847-00-9 |
|
Acenaphthenequinone, 95%
| 82-86-0 |
|
alpha,alpha'-Dibromo-o-xylene, 96%
| 91-13-4 |
|
DL-Cysteine, 99%
| 3374-22-9 |
|
|