**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 77253-67-9 |2,2,2-Trifluoroethanol-d3 | >99 | 278-649-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 10 20/21/22 38 41 62
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation, in contact with skin and if
swallowed. Irritating to skin. Risk of serious damage to eyes.
Possible risk of impaired fertility.
Potential Health Effects
Eye:
Causes severe eye irritation. May result in corneal injury.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
May cause anemia and other blood cell abnormalities.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Get medical aid. Wash
clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable liquid and vapor. Vapors are heavier than
air and may travel to a source of ignition and flash back. Vapors can
spread along the ground and collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Do not ingest or inhale. Discard contaminated shoes. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Use only with
adequate ventilation.
Storage:
Keep away from heat, sparks, and flame. Keep container closed when
not in use. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 75-89-8:
Russia: 10 mg/m3 TWA
CAS# 77253-67-9:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: alcohol-like
pH: 5-7 (10% aq soln)
Vapor Pressure: 70 mm Hg @ 25 deg C
Viscosity: 1.75 cP 25.00 deg
Boiling Point: 73.6 deg C
Freezing/Melting Point: -45 deg C
Autoignition Temperature: 480 deg C ( 896.00 deg F)
Flash Point: 29 deg C ( 84.20 deg F)
Explosion Limits, lower: 5.5%
Explosion Limits, upper: 42%
Decomposition Temperature: 315 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.45 g/cm3
Molecular Formula: C2D3F3O
Molecular Weight: 103.06
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, electrical sparks, exposure to flame, heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-89-8: KM5250000
CAS# 77253-67-9 unlisted.
LD50/LC50:
CAS# 75-89-8: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize
test, rabbit, skin: 750 ug/24H Severe; Inhalation, mouse: LC50 = 2900
mg/m3/2H; Inhalation, mouse: LC50 = 2900 mg/m3/2H; Inhalation, rat:
LC50 = 470 ppm/6H; Oral, mouse: LD50 = 366 mg/kg; Oral, rat: LD50 =
240 mg/kg; Skin, rabbit: LD50 = 390 uL/kg; Skin, rat: LD50 = 1680
mg/kg.
CAS# 77253-67-9.
Carcinogenicity:
2,2,2-Trifluoroethanol -
Not listed by ACGIH, IARC, or NTP.
2,2,2-Trifluoroethanol-d3 -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALCOHOLS, N.O.S.*
Hazard Class: 3
UN Number: 1987
Packing Group: III
IMO
Shipping Name: ALCOHOLS, N.O.S.
Hazard Class: 3.3
UN Number: 1987
Packing Group: III
RID/ADR
Shipping Name: ALCOHOLS, FLAMMABLE, N.O.S.
Hazard Class: 3
UN Number: 1987
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
R 62 Possible risk of impaired fertility.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-89-8: 1
CAS# 77253-67-9: No information available.
Canada
CAS# 75-89-8 is listed on Canada's DSL List.
CAS# 75-89-8 is not listed on Canada's Ingredient Disclosure List.
CAS# 77253-67-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-89-8 is listed on the TSCA inventory.
CAS# 77253-67-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #8 Date: 3/21/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Chlorobenzotrichloride, 99%
| 2136-89-2 |
|
1,5-Diaminopentane, 98%
| 462-94-2 |
|
2-Methyl-5-Phenylbenzoxazole, 97%
| 61931-68-8 |
|
Meta-nitro-alpha,alpha,alpha-trifluoro- toluene, 99%
| 98-46-4 |
|
4-Methylsulphonylphenylhydrazine Hydrochloride, 95+%
| 877-66-7 |
|
Ethyl cyclohexylacetate, 98+%
| 5452-75-5 |
|
Glycylglycine, 99+% (titr.)
| 556-50-3 |
|
2,3-Dimethoxybenzyl Alcohol 99%
| 5653-67-8 |
|
1-Pyrrolidinecarbonyl chloride, 99%
| 1192-63-8 |
|
2,2,2-Trifluoroethanol-d3, 99+ atom% D
| 75-89-8 |
|
N-Alpha-Benzoyl-L-Arginine Ethyl Ester Hydrochloride, 99+%
| 2645-08-1 |
|
3-Methylpyrazole, 99%
| 1453-58-3 |
|
Lithium Aluminum Hydride, Tablets, 97%
| 16853-85-3 |
|
Europium(iii) oxide, 99.99%
| 1308-96-9 |
|
Cerium(IV) Oxide, 99.9%
| 1306-38-3 |
|
(1,2-Dibromoethyl)benzene, 99%
| 93-52-7 |
|
(S)-(-)-2-Amino-3-(1-naphthyl)propanoic acid, 99% (99% e.e.)
| 55516-54-6 |
|
Acid Green 41
| 4430-16-4 |
|
1,9-Dibromononane, 97%
| 4549-33-1 |
|
2-Ethoxyethyl Ether, 98+%
| 112-36-7 |
|
4-Chlorobenzylamine,98 %
| 104-86-9 |
|
Omega-aminocaprylic acid 99+%
| 1002-57-9 |
|
1-Naphthoyl chloride, 99%
| 879-18-5 |
|
1-Phenyl-1H-tetrazole-5-thiol cyclohexylamine salt, 99+% (titr.)
| 102853-44-1 |
|
Formaldehyde solution 37%
| 50-00-0 |
|
DL-Alanine-Beta-Naphthylamide Hydrochloride, 98%
| 74144-49-3 |
|
N-Acetyl-D-Galactosamine, 97%
| 14131-60-3 |
|
Nitromethane-d3, 99 atom % d
| 13031-32-8 |
|
Bromohydroquinone (Techn), 90% (GC)
| 583-69-7 |
|
Phenylsilane, 98%
| 694-53-1 |
|
l-(+)-Arabinose, 99+%
| 87-72-9 |
|
1,4-Cyclohexanedione, 98%
| 637-88-7 |
|
2,2-Diphenyl-1-Picrylhydrazyl, 97% (UV-Vis)
| 1898-66-4 |
|
Strontium Hydroxide Octahydrate, 98%
| 18480-07-4 |
|
1,4-Dichloro-2-fluorobenzene, 99+%
| 348-59-4 |
|
3,5-Dichloro-4-Pyridinol, 95%
| 17228-71-6 |
|
4-Cyanophenyl 4-Heptylbenzoate, 99+%
| 38690-76-5 |
|
alpha-Bromo-p-xylene, 98%
| 104-81-4 |
|
n-Methylphenethylamine, 99%
| 589-08-2 |
|
Phenyl-P-Benzoquinone, 99% (UV-Vis)
| 363-03-1 |
|
Diethyl 2,4-Dimethylpyrrole-3,5-Dicarboxylate, 97%
| 2436-79-5 |
|
Methyl isobutyrate, 99%
| 547-63-7 |
|
1-Piperidinecarbonitrile, 97+%
| 1530-87-6 |
|
(-)-Limonene, 92%
| 5989-54-8 |
|
Triethyl Methanetricarboxylate,98%
| 6279-86-3 |
|
Ethyl chloroacetate, p.a.
| 105-39-5 |
|
1,2:5,6-di-o-isopropylidene-alpha-d-ribo-3 -hexulofuranose, 98%
| 2847-00-9 |
|
Acenaphthenequinone, 95%
| 82-86-0 |
|
alpha,alpha'-Dibromo-o-xylene, 96%
| 91-13-4 |
|
DL-Cysteine, 99%
| 3374-22-9 |
|
|