**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-92-3 |Allyl glycidyl ether | > 99 | 203-442-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20/22 37/38 40 41 43 62 52/53 68
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation and if swallowed. Irritating to
respiratory system and skin. Limited evidence of a carcinogenic
effect. Risk of serious damage to eyes. May cause sensitization by
skin contact. Possible risk of impaired fertility. Harmful to
aquatic organisms, may cause long-term adverse effects in the
aquatic environment.Possible risk of irreversible effects.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause reversible inflammation
and corneal injury with opacity.
Skin:
Causes severe skin irritation. May cause skin sensitization, an
allergic reaction, which becomes evident upon re-exposure to this
material. May be harmful if absorbed through the skin.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed. May cause central nervous
system depression.
Inhalation:
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Aspiration may lead to pulmonary edema. May cause burning sensation,
coughing, wheezing, laryngitis, shortness of breath, headache,
nausea, and vomiting. Inhalation at high concentrations may cause CNS
depression and asphixiation. Harmful if inhaled.
Chronic:
Repeated exposure may cause sensitization dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Use
water spray to keep fire-exposed containers cool. Flammable liquid
and vapor. Containers may explode when heated. Runoff from fire
control or dilution water may cause pollution. Vapors are heavier
than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. In case of fire,
use carbon dioxide, dry chemical powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Absorb spill using
an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust. Use a
spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Use
and store under nitrogen. Use only in a chemical fume hood. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Do not breathe vapor.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Deep freeze (below -20C).
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible
exposure limits.
Exposure Limits
CAS# 106-92-3:
United States OSHA: ; 10 ppm Ceiling; 45 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 23 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 48 mg/m3 VLE
France - VME: 5 ppm VME; 22 mg/m3 VME
Malaysia: 1 ppm TWA; 4.6 mg/m3 TWA
Netherlands: 0.1 ppm MAC; 0.5 mg/m3 MAC
Spain: 1 ppm VLA-ED; 4.7 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: characteristic odor - pleasant odor
pH: Not available.
Vapor Pressure: 4.7 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 154 deg C @ 760 mmHg
Freezing/Melting Point: (forms glass) -100 deg C
Autoignition Temperature: Not available.
Flash Point: 48 deg C ( 118.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 14.1% in water slightly soluble
Specific Gravity/Density: .9620 g/cm3
Molecular Formula: C6H10O2
Molecular Weight: 114.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-92-3: RR0875000
LD50/LC50:
CAS# 106-92-3: Draize test, rabbit, eye: 97 mg Severe; Draize test,
rabbit, eye: 750 ug/24H Severe; Draize test, rabbit, skin: 485 mg/3D
Moderate; Draize test, rabbit, skin: 2 mg/24H Severe; Inhalation,
mouse: LC50 = 270 ppm/4H; Inhalation, rat: LC50 = 670 ppm/8H; Oral,
mouse: LD50 = 390 mg/kg; Oral, rat: LD50 = 1600 mg/kg; Skin, rabbit:
LD50 = 2550 mg/kg.
Carcinogenicity:
Allyl glycidyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish, Goldfish: LD50 = 78 mg/L/24H. (Conditions of bioassay not
specified). Fish, Goldfish: LD50 = 30 mg/L/96H. (Conditions of
bioassay not specified).
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ALLYL GLYCIDYL ETHER
Hazard Class: 3
UN Number: 2219
Packing Group: III
IMO
Shipping Name: ALLYL GLYCIDYL ETHER
Hazard Class: 3.3
UN Number: 2219
Packing Group: III
RID/ADR
Shipping Name: ALLYL GLYCIDYL ETHER
Hazard Class: 3
UN Number: 2219
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20/22 Harmful by inhalation and if swallowed.
R 37/38 Irritating to respiratory system and skin.
R 40 Limited evidence of a carcinogenic effect.
R 41 Risk of serious damage to eyes.
R 43 May cause sensitization by skin contact.
R 52/53 Harmful to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 62 Possible risk of impaired fertility.
R 68 Possible risk of irreversible effects.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 106-92-3: 3
Canada
CAS# 106-92-3 is listed on Canada's DSL List.
CAS# 106-92-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-92-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 10/30/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl N-(Diphenylmethylene)glycinate, 98%
| 69555-14-2 |
|
Methyl 4-(hydroxymethyl)benzoate, 98%
| 6908-41-4 |
|
Glyoxylic acid monohydrate, 98%
| 298-12-4 |
|
Trimethylhydroquinone, 97%
| 700-13-0 |
|
2,5-Difluoroaniline, 99%
| 367-30-6 |
|
Phosphoenolpyruvic acid cyclohexylamine salt, 98% (titr.)
| 10526-80-4 |
|
Exo-2-Chloro-5,5-Ethylenedioxy-Bicyclo[2.2.1]Heptane-Syn-7-Carboxylic
| 64812-08-4 |
|
6-Methyl-2-pyridinecarboxaldehyde, 97%
| 1122-72-1 |
|
Methyl methylsulfinylmethyl sulfide, 97%
| 33577-16-1 |
|
Trans-2,3-Dibromo-2-Butene-1,4-Diol, 97%
| 3234-02-4 |
|
1-Bromo-2,5-Dichloro-3-Fluorobenzene, 98%
| 0-00-1 |
|
(r)-(-)-Methyl mandelate, 98+%
| 20698-91-3 |
|
3-Bromo-4-Chlorobenzotrifluoride, 98+%
| 454-78-4 |
|
3-Nitrophthalic anhydride, 97%
| 641-70-3 |
|
Phenylphosphonic dichloride, 97%
| 824-72-6 |
|
5-tert-Butyl-m-xylene, 98%
| 98-19-1 |
|
2,4-Dibromophenol, 99% (GC)
| 615-58-7 |
|
Ytterbium(iii) oxide, 99%
| 1314-37-0 |
|
1,3-Indanedione, 97%
| 606-23-5 |
|
Nitrilotriacetic Acid, 99%
| 139-13-9 |
|
3-Ethoxypropionaldehyde diethyl acetal, 95%
| 7789-92-6 |
|
N-(Alpha, Alpha, Alpha-Trifluoro-M-Tolyl)Piperazine, 98%(Titr.)
| 15532-75-9 |
|
p-Bromoaniline
| 106-40-1 |
|
3-Hydroxy-3,7,11-Trimethyl-1,6,10-Dodecatriene, mixture of cis-trans,
| 7212-44-4 |
|
N-(Gamma-L-Glutamyl)-Alpha-Naphthylamide Monohydrate, 99%
| 81012-91-1 |
|
Acridine Yellow, 98% (UV-Vis)
| 135-49-9 |
|
Dibutyltin oxide, 98%
| 818-08-6 |
|
Dimethyl 4-nitrophthalate
| 610-22-0 |
|
1-Octadecene, Tech., 90%
| 112-88-9 |
|
Dibenzyl Malonate, Tech., 90%
| 15014-25-2 |
|
3-O-methyldopamine hydrochloride, p.a.
| 1477-68-5 |
|
3-Hydroxybenzophenone, 99%
| 13020-57-0 |
|
2,5-Dichloronitrobenzene, 99%
| 89-61-2 |
|
Diphenylsilanediol, 95%
| 947-42-2 |
|
Allyl glycidyl ether, 99+ %
| 106-92-3 |
|
(+)-Dihydrocarvone, 98%, mixture of isomers
| 5524-05-0 |
|
Semicarbazide Hydrochloride,98%
| 563-41-7 |
|
3-Fluoro-4-Nitrotoluene, 99+%
| 446-34-4 |
|
2,3-Dichloronitrobenzene, 99%
| 3209-22-1 |
|
N-(3-Bromo-2,4,6-Trimethylphenylcarbamoylmethyl)Iminodiacetic Acid,
| 78266-06-5 |
|
(3R,4R)-(-)-D-Erythronolactone, 99.5+%
| 15667-21-7 |
|
2-Phenylcyclohexanone, 98%
| 1444-65-1 |
|
4,4'-Dimethoxystilbene, 97%
| 4705-34-4 |
|
Ethyl-2-(2-Aminothiazol-4-yl)-2-Hydroxyimino Acetate, 97%,
| 64485-82-1 |
|
Benzo[b]tellurophene, 96%
| 0-01-0 |
|
Ethyl Isocyanoacetate, 97+% (GC)
| 2999-46-4 |
|
Chlorodiphenylphosphine, Tech., 95%
| 1079-66-9 |
|
4-Hydroxyephedrine hydrochloride, 99+%
| 7437-54-9 |
|
p-Toluoyl chloride, 98%
| 874-60-2 |
|
2,4-Difluoronitrobenzene, 99%
| 446-35-5 |
|
|