**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 874-60-2 |p-Toluoyl chloride | 98.0 | 212-864-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.Combustible
liquid.Water-reactive.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Causes severe burns.
Prolonged or repeated skin contact may cause severe exacerbation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further
exposure.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Combustible
liquid. Containers may explode when heated. Containers may explode
when heated or if contaminated with water. Reacts with water to form
acidic gases which when in contact with metal may liberate flammable
and/or hydrogen gas.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Do not get water on spilled
substances or inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 874-60-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to light yellow
Odor: pungent odor
pH: Not available.
Vapor Pressure: 2 mm Hg @20C
Viscosity: Not available.
Boiling Point: 225.0 - 227.0 deg C
Freezing/Melting Point: -2 deg C
Autoignition Temperature: Not available.
Flash Point: 82 deg C ( 179.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.1690g/cm3
Molecular Formula: C8H7ClO
Molecular Weight: 154.60
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, contact with water, strong oxidants.
Incompatibilities with Other Materials:
Water - alcohols - oxidizing agents - strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 874-60-2: XV1660000
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
p-Toluoyl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 874-60-2: 2
Canada
CAS# 874-60-2 is listed on Canada's NDSL List.
CAS# 874-60-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 874-60-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/14/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl N-(Diphenylmethylene)glycinate, 98%
| 69555-14-2 |
|
Methyl 4-(hydroxymethyl)benzoate, 98%
| 6908-41-4 |
|
Glyoxylic acid monohydrate, 98%
| 298-12-4 |
|
Trimethylhydroquinone, 97%
| 700-13-0 |
|
2,5-Difluoroaniline, 99%
| 367-30-6 |
|
Phosphoenolpyruvic acid cyclohexylamine salt, 98% (titr.)
| 10526-80-4 |
|
Exo-2-Chloro-5,5-Ethylenedioxy-Bicyclo[2.2.1]Heptane-Syn-7-Carboxylic
| 64812-08-4 |
|
6-Methyl-2-pyridinecarboxaldehyde, 97%
| 1122-72-1 |
|
Methyl methylsulfinylmethyl sulfide, 97%
| 33577-16-1 |
|
Trans-2,3-Dibromo-2-Butene-1,4-Diol, 97%
| 3234-02-4 |
|
1-Bromo-2,5-Dichloro-3-Fluorobenzene, 98%
| 0-00-1 |
|
(r)-(-)-Methyl mandelate, 98+%
| 20698-91-3 |
|
3-Bromo-4-Chlorobenzotrifluoride, 98+%
| 454-78-4 |
|
3-Nitrophthalic anhydride, 97%
| 641-70-3 |
|
Phenylphosphonic dichloride, 97%
| 824-72-6 |
|
5-tert-Butyl-m-xylene, 98%
| 98-19-1 |
|
2,4-Dibromophenol, 99% (GC)
| 615-58-7 |
|
Ytterbium(iii) oxide, 99%
| 1314-37-0 |
|
1,3-Indanedione, 97%
| 606-23-5 |
|
Nitrilotriacetic Acid, 99%
| 139-13-9 |
|
3-Ethoxypropionaldehyde diethyl acetal, 95%
| 7789-92-6 |
|
N-(Alpha, Alpha, Alpha-Trifluoro-M-Tolyl)Piperazine, 98%(Titr.)
| 15532-75-9 |
|
p-Bromoaniline
| 106-40-1 |
|
3-Hydroxy-3,7,11-Trimethyl-1,6,10-Dodecatriene, mixture of cis-trans,
| 7212-44-4 |
|
N-(Gamma-L-Glutamyl)-Alpha-Naphthylamide Monohydrate, 99%
| 81012-91-1 |
|
Acridine Yellow, 98% (UV-Vis)
| 135-49-9 |
|
Dibutyltin oxide, 98%
| 818-08-6 |
|
Dimethyl 4-nitrophthalate
| 610-22-0 |
|
1-Octadecene, Tech., 90%
| 112-88-9 |
|
Dibenzyl Malonate, Tech., 90%
| 15014-25-2 |
|
3-O-methyldopamine hydrochloride, p.a.
| 1477-68-5 |
|
3-Hydroxybenzophenone, 99%
| 13020-57-0 |
|
2,5-Dichloronitrobenzene, 99%
| 89-61-2 |
|
Diphenylsilanediol, 95%
| 947-42-2 |
|
Allyl glycidyl ether, 99+ %
| 106-92-3 |
|
(+)-Dihydrocarvone, 98%, mixture of isomers
| 5524-05-0 |
|
Semicarbazide Hydrochloride,98%
| 563-41-7 |
|
3-Fluoro-4-Nitrotoluene, 99+%
| 446-34-4 |
|
2,3-Dichloronitrobenzene, 99%
| 3209-22-1 |
|
N-(3-Bromo-2,4,6-Trimethylphenylcarbamoylmethyl)Iminodiacetic Acid,
| 78266-06-5 |
|
(3R,4R)-(-)-D-Erythronolactone, 99.5+%
| 15667-21-7 |
|
2-Phenylcyclohexanone, 98%
| 1444-65-1 |
|
4,4'-Dimethoxystilbene, 97%
| 4705-34-4 |
|
Ethyl-2-(2-Aminothiazol-4-yl)-2-Hydroxyimino Acetate, 97%,
| 64485-82-1 |
|
Benzo[b]tellurophene, 96%
| 0-01-0 |
|
Ethyl Isocyanoacetate, 97+% (GC)
| 2999-46-4 |
|
Chlorodiphenylphosphine, Tech., 95%
| 1079-66-9 |
|
4-Hydroxyephedrine hydrochloride, 99+%
| 7437-54-9 |
|
p-Toluoyl chloride, 98%
| 874-60-2 |
|
2,4-Difluoronitrobenzene, 99%
| 446-35-5 |
|
|