**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 824-72-6 |Phosphonic dichloride, phenyl- | 97 | 212-534-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. Aspiration may
lead to pulmonary edema. May cause systemic effects. Inhalation may
produce burning sensation, coughing, wheezing, laryngitis, shortness
of breath, headache, nausea, and vomiting.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Water hydrolyzes material liberating acidic
gas which in contact with metal surfaces can generate flammable
and/or explosive hydrogen gas.
Extinguishing Media:
DO NOT USE WATER! Use dry chemical, carbon dioxide, or appropriate
foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Absorb spill using an absorbent, non-combustible
material such as earth, sand, or vermiculite. Do not use combustible
materials such as sawdust. Provide ventilation. Do not get water
inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Keep container tightly closed. Do
not get on skin or in eyes. Do not ingest or inhale. Use with
adequate ventilation. Use and store under nitrogen. Do not allow
contact with water. Use only in a chemical fume hood. Discard
contaminated shoes. Do not breathe vapor.
Storage:
Keep container closed when not in use. Corrosives area. Store
protected from moisture. Store in a cool, dry area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 824-72-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: pungent odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 258 deg C @ 760.00mmHg
Freezing/Melting Point: 3 deg C
Autoignition Temperature: Not applicable.
Flash Point: 204 deg C ( 399.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: decomposes
Specific Gravity/Density: 1.3750g/cm3
Molecular Formula: C6H5Cl2OP
Molecular Weight: 194.98
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if exposed to moist air or water.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, water.
Hazardous Decomposition Products:
Hydrogen chloride, phosphine, carbon monoxide, oxides of phosphorus,
carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 824-72-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Phosphonic dichloride, phenyl- -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 824-72-6: 3
Canada
CAS# 824-72-6 is listed on Canada's DSL List.
CAS# 824-72-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 824-72-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/09/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl N-(Diphenylmethylene)glycinate, 98%
| 69555-14-2 |
|
Methyl 4-(hydroxymethyl)benzoate, 98%
| 6908-41-4 |
|
Glyoxylic acid monohydrate, 98%
| 298-12-4 |
|
Trimethylhydroquinone, 97%
| 700-13-0 |
|
2,5-Difluoroaniline, 99%
| 367-30-6 |
|
Phosphoenolpyruvic acid cyclohexylamine salt, 98% (titr.)
| 10526-80-4 |
|
Exo-2-Chloro-5,5-Ethylenedioxy-Bicyclo[2.2.1]Heptane-Syn-7-Carboxylic
| 64812-08-4 |
|
6-Methyl-2-pyridinecarboxaldehyde, 97%
| 1122-72-1 |
|
Methyl methylsulfinylmethyl sulfide, 97%
| 33577-16-1 |
|
Trans-2,3-Dibromo-2-Butene-1,4-Diol, 97%
| 3234-02-4 |
|
1-Bromo-2,5-Dichloro-3-Fluorobenzene, 98%
| 0-00-1 |
|
(r)-(-)-Methyl mandelate, 98+%
| 20698-91-3 |
|
3-Bromo-4-Chlorobenzotrifluoride, 98+%
| 454-78-4 |
|
3-Nitrophthalic anhydride, 97%
| 641-70-3 |
|
Phenylphosphonic dichloride, 97%
| 824-72-6 |
|
5-tert-Butyl-m-xylene, 98%
| 98-19-1 |
|
2,4-Dibromophenol, 99% (GC)
| 615-58-7 |
|
Ytterbium(iii) oxide, 99%
| 1314-37-0 |
|
1,3-Indanedione, 97%
| 606-23-5 |
|
Nitrilotriacetic Acid, 99%
| 139-13-9 |
|
3-Ethoxypropionaldehyde diethyl acetal, 95%
| 7789-92-6 |
|
N-(Alpha, Alpha, Alpha-Trifluoro-M-Tolyl)Piperazine, 98%(Titr.)
| 15532-75-9 |
|
p-Bromoaniline
| 106-40-1 |
|
3-Hydroxy-3,7,11-Trimethyl-1,6,10-Dodecatriene, mixture of cis-trans,
| 7212-44-4 |
|
N-(Gamma-L-Glutamyl)-Alpha-Naphthylamide Monohydrate, 99%
| 81012-91-1 |
|
Acridine Yellow, 98% (UV-Vis)
| 135-49-9 |
|
Dibutyltin oxide, 98%
| 818-08-6 |
|
Dimethyl 4-nitrophthalate
| 610-22-0 |
|
1-Octadecene, Tech., 90%
| 112-88-9 |
|
Dibenzyl Malonate, Tech., 90%
| 15014-25-2 |
|
3-O-methyldopamine hydrochloride, p.a.
| 1477-68-5 |
|
3-Hydroxybenzophenone, 99%
| 13020-57-0 |
|
2,5-Dichloronitrobenzene, 99%
| 89-61-2 |
|
Diphenylsilanediol, 95%
| 947-42-2 |
|
Allyl glycidyl ether, 99+ %
| 106-92-3 |
|
(+)-Dihydrocarvone, 98%, mixture of isomers
| 5524-05-0 |
|
Semicarbazide Hydrochloride,98%
| 563-41-7 |
|
3-Fluoro-4-Nitrotoluene, 99+%
| 446-34-4 |
|
2,3-Dichloronitrobenzene, 99%
| 3209-22-1 |
|
N-(3-Bromo-2,4,6-Trimethylphenylcarbamoylmethyl)Iminodiacetic Acid,
| 78266-06-5 |
|
(3R,4R)-(-)-D-Erythronolactone, 99.5+%
| 15667-21-7 |
|
2-Phenylcyclohexanone, 98%
| 1444-65-1 |
|
4,4'-Dimethoxystilbene, 97%
| 4705-34-4 |
|
Ethyl-2-(2-Aminothiazol-4-yl)-2-Hydroxyimino Acetate, 97%,
| 64485-82-1 |
|
Benzo[b]tellurophene, 96%
| 0-01-0 |
|
Ethyl Isocyanoacetate, 97+% (GC)
| 2999-46-4 |
|
Chlorodiphenylphosphine, Tech., 95%
| 1079-66-9 |
|
4-Hydroxyephedrine hydrochloride, 99+%
| 7437-54-9 |
|
p-Toluoyl chloride, 98%
| 874-60-2 |
|
2,4-Difluoronitrobenzene, 99%
| 446-35-5 |
|
|