**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107-21-1 |Ethylene glycol | ca. 100 | 203-473-3
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.Hygroscopic.
Potential Health Effects
Eye:
Causes redness and pain. Contact with liquid causes irritation.
Skin:
May cause reddening of the skin. Contact with liquid causes
irritation.
Ingestion:
May cause kidney damage. May cause nausea and vomiting.
Inhalation:
May cause respiratory tract irritation.
Chronic:
May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure to fresh air immediately. If breathing is
difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Ethanol may inhibit methanol metabolism.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Containers may explode in the heat of a fire.
Vapors may be heavier than air. They can spread along the ground
and collect in low or confined areas. Runoff from fire control or
dilution water may cause pollution.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Water or foam may cause frothing. Use water
spray to cool fire-exposed containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Keep container tightly closed. Avoid
ingestion and inhalation.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: odorless
pH: Not available.
Vapor Pressure: .05 mm Hg @ 20C
Viscosity: mPas 20 deg C
Boiling Point: 195 deg C @ 760.00mm Hg
Freezing/Melting Point: -13 deg C
Autoignition Temperature: 410 deg C ( 770.00 deg F)
Flash Point: 111 deg C ( 231.80 deg F)
Explosion Limits, lower: 3.20 vol %
Explosion Limits, upper: 15.30 vol %
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 1.1200g/cm3
Molecular Formula: C2H6O2
Molecular Weight: 62.06
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, oxidizing agents, strong bases, strong acids, bromine
trifluoride, chlorine trifluoride, liquid chlorine, nitric acid,
perchlorates, sodium hydroxide, sodium peroxide, sulfuric acid,
oxygen, potassium permanganate, ozone, chlorosulfonic acid, oleum,
chromium trioxide, bromine pentafluoride, chromic anhydride,
phosphorus pentasulfide, titanium butoxide, ammonium dichromate,
sodium chloride, silver chlorate, uranyl nitrate.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107-21-1: KW2975000
LD50/LC50:
CAS# 107-21-1: Draize test, rabbit, eye: 500 mg/24H Mild; Draize
test, rabbit, eye: 100 mg/1H Mild; Draize test, rabbit, eye: 1440
mg/6H Moderate; Oral, mouse: LD50 = 5500 mg/kg; Oral, rat: LD50 =
4700 mg/kg; Skin, rabbit: LD50 = 9530 uL/kg.
Carcinogenicity:
Ethylene glycol -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 41000 mg/L; 96 Hr.; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 27500-41000 mg/L; 96 Hr.; UnspecifiedFish:
Goldfish: LC50 = 27500-41000 mg/L; 96 Hr.; UnspecifiedWater flea
LC50 = 46300 mg/L; 48 Hr.; UnspecifiedBacteria: Phytobacterium
phosphoreum: EC50 =620 mg/L; 30 minutes; Microtox testGoldfish LD50=
>5000mg/L/24Hr Guppies LC50= 493,000ppm/7D Shrimp (salt water) LC50=
>100ppm/48Hr
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
S 2 Keep out of reach of children.
S 15 Keep away from heat.
S 17 Keep away from combustible material.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 107-21-1: 0
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 107-21-1 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 107-21-1: OEL-AUSTRALIA:TWA 60 mg/m3;STEL 120 mg/m3
OEL-BELGIUM:STEL 50 ppm (127 mg/m3)
OEL-DENMARK:STEL 50 ppm (130 mg/m3)
OEL-DENMARK:TWA 10 mg/m3
OEL-FINLAND:TWA 10 mg/m3;STEL 20 mg/m3
OEL-FINLAND:TWA 50 ppm (125 mg/m3);STEL 75 ppm (190 mg/m3)
OEL-FRANCE:STEL 50 ppm (125 mg/m3)
OEL-HUNGARY:STEL 50 mg/m3;Skin
OEL-THE NETHERLANDS:TWA 10 mg/m3
OEL-THE NETHERLANDS:TWA 50 ppm (125 mg/m3)
OEL-RUSSIA:STEL 5 mg/m3
OEL-SWEDEN:TWA 50 ppm (130 mg/m3);STEL 75 ppm (19 mg/m3)
OEL-SWITZERLAND:TWA 1 mg/m3
OEL-SWITZERLAND:TWA 50 ppm (125 mg/m3)
OEL-UNITED KINGDOM:TWA 10 mg/m3
OEL-UNITED KINGDOM:TWA 60 mg/m3;STEL 125 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 107-21-1 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/12/1999 Revision #5 Date: 1/21/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium hydroxide, 50 wt% solution in water
| 1310-73-2 |
|
Sodium Deuteroxide, 40 wt. % Solution in D2O, 99+ Atom % D
| 7732-18-5 |
|
3,4,7,8-Tetramethyl-1,10-Phenanthroline, 99+%
| 1660-93-1 |
|
1,2,4-Trichlorobenzene, 99+%
| 120-82-1 |
|
1,2,4-Trichlorobenzene, 99%
| 120-82-1 |
|
Tetramethylene sulfoxide, 98+%
| 1600-44-8 |
|
Isoamyl nitrite, 90%, stabilized over molecular sieves
| 110-46-3 |
|
Benzyl chloroformate, 97%, stabilized with 0.1% anhydrous sodium
| 75-44-5 |
|
Dysprosium fluoride, 99.5%
| 13569-80-7 |
|
Erbium fluoride, 99%
| 13760-83-3 |
|
Praseodymium fluoride, anhydrous, 99.9%
| 13709-46-1 |
|
Styrene oxide, 98+%
| 96-09-3 |
|
Samarium fluoride, 99.9%
| 13765-24-7 |
|
Zirconium fluoride, 99.5%
| 7783-64-4 |
|
2,4,5-Trichlorothiophenol, Tech., 90%
| 3773-14-6 |
|
1,3-Benzenedisulfonyl Chloride, 98% (titr.)
| 585-47-7 |
|
Lutetium Fluoride, Anhydrous, 99.9%
| 13760-81-1 |
|
Zinc fluoride, hydrate 99% (ca 4 mole H2O)
| 7783-49-5 |
|
Indium fluoride, 99%
| 7783-52-0 |
|
Manganese(III) fluoride, 99%
| 7783-53-1 |
|
Aluminum fluoride, 99.9+%
| 7784-18-1 |
|
Chloromethyl-4-Chlorophenoxy Dimethylsilane, 98%
| |
|
Chloromethyl-4-Chlorophenyl Dimethylsilane , 97% (GC)
| 770-89-8 |
|
alpha,beta-Dichloroacrylonitrile, 98%
| 22410-58-8 |
|
Cyanimidodithiocarbonic Acid Monomethyl Ester Monopotassium Salt, 98%
| 10191-61-4 |
|
5-Chloromethylthio-3-Methylmercapto-1,2,4- Thiadiazole, 95% (GC)
| 0-00-0 |
|
N-Chloromethylbenzothiazole-2-Thione, 98%
| 41526-42-5 |
|
N-Chloroacetyl Urethane, 98%
| 6092-47-3 |
|
Aluminum phosphate, 99%
| 7784-30-7 |
|
Gallium Sulfate, Anhydrous, 99.99%
| 13494-91-2 |
|
Aluminum sulfate, 99.99%
| 10043-01-3 |
|
Aluminum sulfate octadecahydrate, c.p.
| 7784-31-8 |
|
Aluminum sulfate octadecahydrate, reagent ACS
| 7784-31-8 |
|
Vanadium (IV) chloride
| 7632-51-1 |
|
Tetraethylammonium Chloride, 98% (Titr.)
| 56-34-8 |
|
Octane, 99+%
| 111-65-9 |
|
n-Octane, c.p.
| 111-65-9 |
|
Ether, stabilized, p.a.
| 60-29-7 |
|
Ether, stabilized, 99+%
| 60-29-7 |
|
Ether, spectro grade, stabilized, 99+%
| 60-29-7 |
|
Ethylene glycol, 99+%, anhydrous
| 107-21-1 |
|
Ethylene glycol, 95% (GC)
| 107-21-1 |
|
Ethylene glycol, p.a.
| 107-21-1 |
|
alpha-D-Lactose, monohydrate, reagent ACS
| 5989-81-1 |
|
alpha-Lactose monohydrate, 99.5+% (Lactose Monohydrate)
| 5989-81-1 |
|
Sodium antimonate, 96+%
| 15432-85-6 |
|
Hafnium Iodide, 99.8%
| 13777-23-6 |
|
Phosphoric acid (N-phenylsulfonylamide)dichloride
| 16767-55-8 |
|
N-Phenyliminophosphoric acid trichloride
| 5290-43-7 |
|
N-Phenyl-N'-Cyanoformamidine, 98%
| 59425-37-5 |
|
|