**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 120-82-1 |1,2,4-Trichlorobenzene | 99 | 204-428-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 22 38 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin. Very toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.
Potential Health Effects
Eye:
May cause severe eye irritation.
Skin:
Causes skin irritation. May cause dermatitis.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause a narcotic effect with
possible coma. May cause central nervous system depression.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Do NOT adminster adrenaline after exposure via inhalation or
ingestion.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Contact with
metals may evolve flammable hydrogen gas. Containers may explode when
heated. Combustible material; may burn but does not ignite readily.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, halon, or water
spray. Do NOT get water inside containers. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation. Do not
get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid
ingestion and inhalation.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 120-82-1:
United Kingdom, OES - TWA: 1 ppm TWA
United Kingdom, OES - STEL: 5 ppm STEL
Belgium - TWA: 2 ppm VLE; 15.1 mg/m3 VLE
Belgium - STEL: 5 ppm VLE; 38 mg/m3 VLE
France - VME: 5 ppm VME; 40 mg/m3 VME
Germany: 0.5 ppm TWA; 3.8 mg/m3 TWA
Malaysia: 5 ppm Ceiling; 37 mg/m3 Ceiling
Netherlands: 5 ppm STEL; 37.8 mg/m3 STEL
Netherlands: 2 ppm MAC; 15.1 mg/m3 MAC
Spain: 2 ppm VLA-ED; 15 mg/m3 VLA-ED
Spain: 5 ppm VLA-EC; 38 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Characteristic aromatic odor
pH: Not available.
Vapor Pressure: 2 hPa @ 50 deg C
Viscosity: Not available.
Boiling Point: 214 deg C @ 760 mm Hg
Freezing/Melting Point: 16 deg C
Autoignition Temperature: 571 deg C ( 1,059.80 deg F)
Flash Point: 105 deg C ( 221.00 deg F)
Explosion Limits, lower: 2.5 vol% @ 150
Explosion Limits, upper: 6.6 vol% @ 150
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.450g/cm3
Molecular Formula: C6H3Cl3
Molecular Weight: 181.45
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 120-82-1: DC2100000
LD50/LC50:
CAS# 120-82-1: Draize test, rabbit, skin: 1950 mg/13W (Intermittent)
Moderate; Oral, mouse: LD50 = 300 mg/kg; Oral, mouse: LD50 = 756
mg/kg; Oral, rat: LD50 = 756 mg/kg; Oral, rat: LD50 = 756 mg/kg;
Skin, rat: LD50 = 6139 mg/kg.
Carcinogenicity:
1,2,4-Trichlorobenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Acute fish toxicity: LC50 on Poecilia reticula: approx. 2,4 mg/l.
Duration of test: 14 d (Verschueren,K. Handb.of Environm. Data on
Org.Chem., 2 ed., 1983); LC50 on Lepomis macrochirus: approx. 3,4
mg/l (Buccafusco,R.J. et al. Bull.Environm.Toxicol.26,446-452,1981).
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TRICHLOROBENZENES, LIQUID
Hazard Class: 6.1
UN Number: 2321
Packing Group: III
IMO
Shipping Name: TRICHLOROBENZENES, LIQUID
Hazard Class: 6.1
UN Number: 2321
Packing Group: III
RID/ADR
Shipping Name: TRICHLOROBENZENES, LIQUID
Hazard Class: 6.1
UN Number: 2321
Packing group: III
USA RQ: CAS# 120-82-1: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 37/39 Wear suitable gloves and eye/face
protection.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 120-82-1: 3
Canada
CAS# 120-82-1 is listed on Canada's DSL List.
CAS# 120-82-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 120-82-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/08/1998 Revision #6 Date: 6/27/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium hydroxide, 50 wt% solution in water
| 1310-73-2 |
|
Sodium Deuteroxide, 40 wt. % Solution in D2O, 99+ Atom % D
| 7732-18-5 |
|
3,4,7,8-Tetramethyl-1,10-Phenanthroline, 99+%
| 1660-93-1 |
|
1,2,4-Trichlorobenzene, 99+%
| 120-82-1 |
|
1,2,4-Trichlorobenzene, 99%
| 120-82-1 |
|
Tetramethylene sulfoxide, 98+%
| 1600-44-8 |
|
Isoamyl nitrite, 90%, stabilized over molecular sieves
| 110-46-3 |
|
Benzyl chloroformate, 97%, stabilized with 0.1% anhydrous sodium
| 75-44-5 |
|
Dysprosium fluoride, 99.5%
| 13569-80-7 |
|
Erbium fluoride, 99%
| 13760-83-3 |
|
Praseodymium fluoride, anhydrous, 99.9%
| 13709-46-1 |
|
Styrene oxide, 98+%
| 96-09-3 |
|
Samarium fluoride, 99.9%
| 13765-24-7 |
|
Zirconium fluoride, 99.5%
| 7783-64-4 |
|
2,4,5-Trichlorothiophenol, Tech., 90%
| 3773-14-6 |
|
1,3-Benzenedisulfonyl Chloride, 98% (titr.)
| 585-47-7 |
|
Lutetium Fluoride, Anhydrous, 99.9%
| 13760-81-1 |
|
Zinc fluoride, hydrate 99% (ca 4 mole H2O)
| 7783-49-5 |
|
Indium fluoride, 99%
| 7783-52-0 |
|
Manganese(III) fluoride, 99%
| 7783-53-1 |
|
Aluminum fluoride, 99.9+%
| 7784-18-1 |
|
Chloromethyl-4-Chlorophenoxy Dimethylsilane, 98%
| |
|
Chloromethyl-4-Chlorophenyl Dimethylsilane , 97% (GC)
| 770-89-8 |
|
alpha,beta-Dichloroacrylonitrile, 98%
| 22410-58-8 |
|
Cyanimidodithiocarbonic Acid Monomethyl Ester Monopotassium Salt, 98%
| 10191-61-4 |
|
5-Chloromethylthio-3-Methylmercapto-1,2,4- Thiadiazole, 95% (GC)
| 0-00-0 |
|
N-Chloromethylbenzothiazole-2-Thione, 98%
| 41526-42-5 |
|
N-Chloroacetyl Urethane, 98%
| 6092-47-3 |
|
Aluminum phosphate, 99%
| 7784-30-7 |
|
Gallium Sulfate, Anhydrous, 99.99%
| 13494-91-2 |
|
Aluminum sulfate, 99.99%
| 10043-01-3 |
|
Aluminum sulfate octadecahydrate, c.p.
| 7784-31-8 |
|
Aluminum sulfate octadecahydrate, reagent ACS
| 7784-31-8 |
|
Vanadium (IV) chloride
| 7632-51-1 |
|
Tetraethylammonium Chloride, 98% (Titr.)
| 56-34-8 |
|
Octane, 99+%
| 111-65-9 |
|
n-Octane, c.p.
| 111-65-9 |
|
Ether, stabilized, p.a.
| 60-29-7 |
|
Ether, stabilized, 99+%
| 60-29-7 |
|
Ether, spectro grade, stabilized, 99+%
| 60-29-7 |
|
Ethylene glycol, 99+%, anhydrous
| 107-21-1 |
|
Ethylene glycol, 95% (GC)
| 107-21-1 |
|
Ethylene glycol, p.a.
| 107-21-1 |
|
alpha-D-Lactose, monohydrate, reagent ACS
| 5989-81-1 |
|
alpha-Lactose monohydrate, 99.5+% (Lactose Monohydrate)
| 5989-81-1 |
|
Sodium antimonate, 96+%
| 15432-85-6 |
|
Hafnium Iodide, 99.8%
| 13777-23-6 |
|
Phosphoric acid (N-phenylsulfonylamide)dichloride
| 16767-55-8 |
|
N-Phenyliminophosphoric acid trichloride
| 5290-43-7 |
|
N-Phenyl-N'-Cyanoformamidine, 98%
| 59425-37-5 |
|
|