**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7783-53-1 |Manganese(III) fluoride | 99 | 232-006-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Prolonged contact with the skin, especially
if the skin is wet or moist, causes necrosis.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Chronic inhalation or ingestion may result in manganism
characterized by neurological symptoms such as headache, apathy, and
weakness of the legs, followed by psychosis and neurological symptoms
similar to those of Parkinson's disease. May impair fertility. Other
chronic effects from inhaling high amounts of manganese include an
increased incidence of cough and bronchitis and susceptibility to
infectious lung disease.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation. Do
not expose spill to water. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Keep container tightly closed. Do not
get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 7783-53-1:
United Kingdom, WEL - TWA: (listed as manganese, inorganic
compounds): 0.5 mg/m3 TWA
United Kingdom, WEL - STEL: (listed as manganese, inorganic
compounds): 1.5 mg/m3 STEL
United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan
compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3
(as Mn)
Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex
organic compounds, as Mn)
Malaysia: (listed as manganese, inorganic compounds): 0.2 mg/m3 T
(as Mn)
Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE
(as Mn)
Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC
Mn)
Spain: (listed as manganese, inorganic compounds): 0.2 mg/m3 VLA-
(as Mn)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: red-purple
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Hydrolysis.
Specific Gravity/Density: 3.54
Molecular Formula: F3Mn
Molecular Weight: 111.93
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Moisture, excess heat.
Incompatibilities with Other Materials:
Strong bases, water, strong reducing agents, organic matter,
combustible organics.
Hazardous Decomposition Products:
Fluoride fumes, oxides of manganese.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7783-53-1: OP0882600
LD50/LC50:
CAS# 7783-53-1: Inhalation, mouse: LC50 = 320 mg/m3; Oral, mouse:
LD50 = 86 mg/kg.
Carcinogenicity:
Manganese(III) fluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 7783-53-1: No information available.
Canada
CAS# 7783-53-1 is listed on Canada's NDSL List.
CAS# 7783-53-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7783-53-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/27/1998 Revision #3 Date: 9/03/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium hydroxide, 50 wt% solution in water
| 1310-73-2 |
|
Sodium Deuteroxide, 40 wt. % Solution in D2O, 99+ Atom % D
| 7732-18-5 |
|
3,4,7,8-Tetramethyl-1,10-Phenanthroline, 99+%
| 1660-93-1 |
|
1,2,4-Trichlorobenzene, 99+%
| 120-82-1 |
|
1,2,4-Trichlorobenzene, 99%
| 120-82-1 |
|
Tetramethylene sulfoxide, 98+%
| 1600-44-8 |
|
Isoamyl nitrite, 90%, stabilized over molecular sieves
| 110-46-3 |
|
Benzyl chloroformate, 97%, stabilized with 0.1% anhydrous sodium
| 75-44-5 |
|
Dysprosium fluoride, 99.5%
| 13569-80-7 |
|
Erbium fluoride, 99%
| 13760-83-3 |
|
Praseodymium fluoride, anhydrous, 99.9%
| 13709-46-1 |
|
Styrene oxide, 98+%
| 96-09-3 |
|
Samarium fluoride, 99.9%
| 13765-24-7 |
|
Zirconium fluoride, 99.5%
| 7783-64-4 |
|
2,4,5-Trichlorothiophenol, Tech., 90%
| 3773-14-6 |
|
1,3-Benzenedisulfonyl Chloride, 98% (titr.)
| 585-47-7 |
|
Lutetium Fluoride, Anhydrous, 99.9%
| 13760-81-1 |
|
Zinc fluoride, hydrate 99% (ca 4 mole H2O)
| 7783-49-5 |
|
Indium fluoride, 99%
| 7783-52-0 |
|
Manganese(III) fluoride, 99%
| 7783-53-1 |
|
Aluminum fluoride, 99.9+%
| 7784-18-1 |
|
Chloromethyl-4-Chlorophenoxy Dimethylsilane, 98%
| |
|
Chloromethyl-4-Chlorophenyl Dimethylsilane , 97% (GC)
| 770-89-8 |
|
alpha,beta-Dichloroacrylonitrile, 98%
| 22410-58-8 |
|
Cyanimidodithiocarbonic Acid Monomethyl Ester Monopotassium Salt, 98%
| 10191-61-4 |
|
5-Chloromethylthio-3-Methylmercapto-1,2,4- Thiadiazole, 95% (GC)
| 0-00-0 |
|
N-Chloromethylbenzothiazole-2-Thione, 98%
| 41526-42-5 |
|
N-Chloroacetyl Urethane, 98%
| 6092-47-3 |
|
Aluminum phosphate, 99%
| 7784-30-7 |
|
Gallium Sulfate, Anhydrous, 99.99%
| 13494-91-2 |
|
Aluminum sulfate, 99.99%
| 10043-01-3 |
|
Aluminum sulfate octadecahydrate, c.p.
| 7784-31-8 |
|
Aluminum sulfate octadecahydrate, reagent ACS
| 7784-31-8 |
|
Vanadium (IV) chloride
| 7632-51-1 |
|
Tetraethylammonium Chloride, 98% (Titr.)
| 56-34-8 |
|
Octane, 99+%
| 111-65-9 |
|
n-Octane, c.p.
| 111-65-9 |
|
Ether, stabilized, p.a.
| 60-29-7 |
|
Ether, stabilized, 99+%
| 60-29-7 |
|
Ether, spectro grade, stabilized, 99+%
| 60-29-7 |
|
Ethylene glycol, 99+%, anhydrous
| 107-21-1 |
|
Ethylene glycol, 95% (GC)
| 107-21-1 |
|
Ethylene glycol, p.a.
| 107-21-1 |
|
alpha-D-Lactose, monohydrate, reagent ACS
| 5989-81-1 |
|
alpha-Lactose monohydrate, 99.5+% (Lactose Monohydrate)
| 5989-81-1 |
|
Sodium antimonate, 96+%
| 15432-85-6 |
|
Hafnium Iodide, 99.8%
| 13777-23-6 |
|
Phosphoric acid (N-phenylsulfonylamide)dichloride
| 16767-55-8 |
|
N-Phenyliminophosphoric acid trichloride
| 5290-43-7 |
|
N-Phenyl-N'-Cyanoformamidine, 98%
| 59425-37-5 |
|
|