**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7783-64-4 |Zirconium fluoride | 99.5 | 232-018-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs
moisture from the air).The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Chronic exposure to fluoride compounds may cause systemic toxicity.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Do NOT get water inside containers. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Do not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Minimize dust generation and accumulation. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Use
only in a chemical fume hood. Wash clothing before reuse. Keep from
contact with moist air and steam.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from acids. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7783-64-4:
United Kingdom, WEL - TWA: (listed as zirconium compounds, n.o.s.
mg/m3 TWA (as Zr)
United Kingdom, WEL - STEL: (listed as zirconium compounds, n.o.s
10 mg/m3 STEL (as Zr)
United States OSHA: 5 mg/m3 TWA (listed under Zirconium).5 mg/m3
(as Zr) (listed under Zirconium compounds, n.o.s.).
Belgium - TWA: (listed as zirconium compounds, n.o.s.): 5 mg/m3 V
(as Zr)
Belgium - STEL: (listed as zirconium compounds, n.o.s.): 10 mg/m3
(as Zr)
Malaysia: (listed as zirconium compounds, n.o.s.): 5 mg/m3 TWA (a
Zr)
Netherlands: (listed as zirconium compounds, n.o.s.): 5 mg/m3 MAC
Zr)
Russia: 1 mg/m3 TWA
Spain: (listed as zirconium compounds, n.o.s.): 5 mg/m3 VLA-ED (a
Zr)
Spain: (listed as zirconium compounds, n.o.s.): 10 mg/m3 VLA-EC (
Zr)
Personal Protective Equipment
Eyes:
Wear chemical splash goggles. Wear appropriate
protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate protective
clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use. A NIOSH/MSHA
approved air purifying dust or mist respirator or
European Standard EN 149.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 905 deg C
Freezing/Melting Point: 640 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: in water: 1.388 g/100ml
Specific Gravity/Density:
Molecular Formula: F4Zr
Molecular Weight: 167.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Hydrogen fluoride gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7783-64-4: ZH7875000
LD50/LC50:
Not available.
Carcinogenicity:
Zirconium fluoride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 7783-64-4: No information available.
Canada
CAS# 7783-64-4 is listed on Canada's DSL List.
CAS# 7783-64-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7783-64-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/22/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Sodium hydroxide, 50 wt% solution in water
| 1310-73-2 |
|
Sodium Deuteroxide, 40 wt. % Solution in D2O, 99+ Atom % D
| 7732-18-5 |
|
3,4,7,8-Tetramethyl-1,10-Phenanthroline, 99+%
| 1660-93-1 |
|
1,2,4-Trichlorobenzene, 99+%
| 120-82-1 |
|
1,2,4-Trichlorobenzene, 99%
| 120-82-1 |
|
Tetramethylene sulfoxide, 98+%
| 1600-44-8 |
|
Isoamyl nitrite, 90%, stabilized over molecular sieves
| 110-46-3 |
|
Benzyl chloroformate, 97%, stabilized with 0.1% anhydrous sodium
| 75-44-5 |
|
Dysprosium fluoride, 99.5%
| 13569-80-7 |
|
Erbium fluoride, 99%
| 13760-83-3 |
|
Praseodymium fluoride, anhydrous, 99.9%
| 13709-46-1 |
|
Styrene oxide, 98+%
| 96-09-3 |
|
Samarium fluoride, 99.9%
| 13765-24-7 |
|
Zirconium fluoride, 99.5%
| 7783-64-4 |
|
2,4,5-Trichlorothiophenol, Tech., 90%
| 3773-14-6 |
|
1,3-Benzenedisulfonyl Chloride, 98% (titr.)
| 585-47-7 |
|
Lutetium Fluoride, Anhydrous, 99.9%
| 13760-81-1 |
|
Zinc fluoride, hydrate 99% (ca 4 mole H2O)
| 7783-49-5 |
|
Indium fluoride, 99%
| 7783-52-0 |
|
Manganese(III) fluoride, 99%
| 7783-53-1 |
|
Aluminum fluoride, 99.9+%
| 7784-18-1 |
|
Chloromethyl-4-Chlorophenoxy Dimethylsilane, 98%
| |
|
Chloromethyl-4-Chlorophenyl Dimethylsilane , 97% (GC)
| 770-89-8 |
|
alpha,beta-Dichloroacrylonitrile, 98%
| 22410-58-8 |
|
Cyanimidodithiocarbonic Acid Monomethyl Ester Monopotassium Salt, 98%
| 10191-61-4 |
|
5-Chloromethylthio-3-Methylmercapto-1,2,4- Thiadiazole, 95% (GC)
| 0-00-0 |
|
N-Chloromethylbenzothiazole-2-Thione, 98%
| 41526-42-5 |
|
N-Chloroacetyl Urethane, 98%
| 6092-47-3 |
|
Aluminum phosphate, 99%
| 7784-30-7 |
|
Gallium Sulfate, Anhydrous, 99.99%
| 13494-91-2 |
|
Aluminum sulfate, 99.99%
| 10043-01-3 |
|
Aluminum sulfate octadecahydrate, c.p.
| 7784-31-8 |
|
Aluminum sulfate octadecahydrate, reagent ACS
| 7784-31-8 |
|
Vanadium (IV) chloride
| 7632-51-1 |
|
Tetraethylammonium Chloride, 98% (Titr.)
| 56-34-8 |
|
Octane, 99+%
| 111-65-9 |
|
n-Octane, c.p.
| 111-65-9 |
|
Ether, stabilized, p.a.
| 60-29-7 |
|
Ether, stabilized, 99+%
| 60-29-7 |
|
Ether, spectro grade, stabilized, 99+%
| 60-29-7 |
|
Ethylene glycol, 99+%, anhydrous
| 107-21-1 |
|
Ethylene glycol, 95% (GC)
| 107-21-1 |
|
Ethylene glycol, p.a.
| 107-21-1 |
|
alpha-D-Lactose, monohydrate, reagent ACS
| 5989-81-1 |
|
alpha-Lactose monohydrate, 99.5+% (Lactose Monohydrate)
| 5989-81-1 |
|
Sodium antimonate, 96+%
| 15432-85-6 |
|
Hafnium Iodide, 99.8%
| 13777-23-6 |
|
Phosphoric acid (N-phenylsulfonylamide)dichloride
| 16767-55-8 |
|
N-Phenyliminophosphoric acid trichloride
| 5290-43-7 |
|
N-Phenyl-N'-Cyanoformamidine, 98%
| 59425-37-5 |
|
|