**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-22-5 |Isopropenyl Acetate | 99 | 203-562-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.Highly flammable.The toxicological properties of
this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this
material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. May cause central
nervous system depression.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Exposure produces
central nervous system depression. Vapors may cause dizziness or
suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Flammable liquid
and vapor. Vapors may be heavier than air. They can spread along
the ground and collect in low or confined areas. May polymerize
explosively when involved in a fire. Will be easily ignited by heat,
sparks or flame. Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
For large fires, use water spray, fog or alcohol-resistant foam. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 108-22-5:
Russia: 20 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 94 - 97 deg C @ 760.00mm Hg
Freezing/Melting Point: -93 deg C
Autoignition Temperature: 439 deg C ( 822.20 deg F)
Flash Point: 10 deg C ( 50.00 deg F)
Explosion Limits, lower: 1.80 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature:
Solubility in water: 3.25 g/100ml (20 c)
Specific Gravity/Density: .9090g/cm3
Molecular Formula: C5H8O2
Molecular Weight: 100.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-22-5: UD4200000
LD50/LC50:
CAS# 108-22-5: Draize test, rabbit, eye: 500 mg Moderate; Draize
test, rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500
mg/24H Mild; Oral, rat: LD50 = 3 gm/kg.
Carcinogenicity:
Isopropenyl Acetate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ISOPROPENYL ACETATE
Hazard Class: 3
UN Number: 2403
Packing Group: II
IMO
Shipping Name: ISOPROPENYL ACETATE
Hazard Class: 3.2
UN Number: 2403
Packing Group: II
RID/ADR
Shipping Name: ISOPROPENYL ACETATE
Hazard Class: 3
UN Number: 2403
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 28A After contact with skin, wash immediately with
plenty of water.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 108-22-5: 1
Canada
CAS# 108-22-5 is listed on Canada's DSL List.
CAS# 108-22-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-22-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/23/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Ethyl chloroacetate
| 105-39-5 |
|
1,2:3,4-Di-O-isopropylidene-D-galactopyranose, 97%
| 4064-06-6 |
|
4-Nitrophenylhydrazine, 98%
| 100-16-3 |
|
1,1,4,4-Tetraphenyl-1,3-Butadiene, 99%
| 1450-63-1 |
|
2-Mercaptopyridine-n-oxide, sodium salt, monohydrate,98%
| 3811-73-2 |
|
1,3-Propane sultone, 97%
| 1120-71-4 |
|
Poly(ethylene glycol methyl ether), average M.W. 350
| 9004-74-4 |
|
Poly(ethylene glycol methyl ether), average mw. 750
| 9004-74-4 |
|
Azetidine, 99+%
| 503-29-7 |
|
Methyl Violet 2B High Purity Biological Stain
| 8004-87-3 |
|
Methyl Violet 2B (Cert)
| 8004-87-3 |
|
4,7-Diphenyl-1,10-Phenanthroline, 99%
| 1662-01-7 |
|
1',3',3'-Trimethyl-6-hydroxyspiro (2h-1-benzopyran-2,2'-indoline)
| 23001-29-8 |
|
Diethyl Carbonate, 99%
| 105-58-8 |
|
1,2,4-1h-triazole, 99+%, flakes
| 288-88-0 |
|
Hydroquinone Bis(2-Hydroxyethyl)ether, 99+%
| 104-38-1 |
|
Silicon, Pieces, 99.9999%
| 7440-21-3 |
|
Silicon, Powder, -60 Mesh, 99.999%
| 7440-21-3 |
|
Phenanthrenequinone, tech. 80%
| 84-11-7 |
|
3-Aminofluoranthene
| 2693-46-1 |
|
Phenanthrenequinone, 98% (uv-vis)
| 84-11-7 |
|
4-(4-Chlorophenyl)-4-hydroxypiperidine, 99%(titr.)
| 39512-49-7 |
|
4-Methyl-3-nitrobenzyl alcohol, 99%
| 40870-59-5 |
|
Amberlite ira-410 ion-exchange resin
| 9002-26-0 |
|
Isoprene, 99+%, stabilized with 100 ppm 4-tert-butylcatechol
| 78-79-5 |
|
Poly(isoprene), cis, average M.W. 800,000
| 9003-31-0 |
|
Isopropenyl Acetate, 99%
| 108-22-5 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride, 96%
| 637-01-4 |
|
Ethyl-Vinyl Ether, 99%, stabilized with 0.1% Potassium Hydroxide
| 109-92-2 |
|
1,1,1-Trichloro-2-methyl-2-propanol hemihydrate
| 57-15-8 |
|
n-Butyric Anhydride, 98%
| 106-31-0 |
|
2,2',4'-Trichloroacetophenone,tech.
| 4252-78-2 |
|
Benz(a)anthracene-7,12-dione, 99%
| 2498-66-0 |
|
(+)-Limonene, 97%, stabilized with 0.03% Tocopherol
| 5989-27-5 |
|
(+)-Limonene, tech., 95%, stabilized with 0.03% Tocopherol
| 5989-27-5 |
|
2,4-Dichlorophenoxyacetic acid, 99+%
| 94-75-7 |
|
??-nicotinamide adenine dinucleotide, disodium salt,reduced form, 98%
| 606-68-8 |
|
4-Bromobenzaldehyde, 99%
| 1122-91-4 |
|
Benzyl cyanide, 99+%
| 140-29-4 |
|
5-Bromosalicylaldehyde, 99%
| 1761-61-1 |
|
Silica Gel, 60-200 Mesh
| 7631-86-9 |
|
Poly(acrylic acid), sec. stand., aver. M.W. 1,080,000, aver. M.N.
| 9003-01-4 |
|
Poly(acrylic acid), 50 wt. % solution in water
| 7732-18-5 |
|
(R)-(+)-1-Benzylglycerol, 97%
| 56552-80-8 |
|
Poly(acrylic acid), 25 wt% solution in water
| 7732-18-5 |
|
Poly(acrylic acid), 52-56% aqueous solution
| 7732-18-5 |
|
Potassium nitrosodisulfonate, 50-75%, remainder water and methanol
| 14293-70-0 |
|
Zinc, Powder, -200 Mesh, 99.9999%
| 7440-66-6 |
|
2-Dimethylaminoisopropyl chloride hydrochloride, 98.5% (titr.)
| 4584-49-0 |
|
Zinc, Mossy, 99+%
| 7440-66-6 |
|
|