**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7440-21-3 |Silicon | >99 | 231-130-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.Moisture sensitive.
Potential Health Effects
Eye:
May cause chemical conjunctivitis and corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Ingestion of large amounts may cause CNS depression.
Inhalation:
Aspiration may lead to pulmonary edema. Contains crystalline silica
which may lead to respiratory abnormalities and silicosis.
Inhalation of dusts cause severe irritation of the upper respiratory
tract, gastrointestinal disturbances, albuminuria, gradual loss of
weight, and increasing weakness. May cause burning sensation in the
chest.
Chronic:
Chronic inhalation of dust may lead to silicosis. May cause
silicosis-disabling pulmonary fibrosis characterized by fibrotic
changes and miliary nodules in the lungs, dry cough, shortness of
breath, emphysema, decreased chest expansion and increased
susceptibility to tuberculosis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Use water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. May be ignited by friction, heat,
sparks, or flame. May react violently or explosively on contact with
water. May re-ignite after fire is extinguished.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use dry sand,
Met-L-X powder, or G-1 graphite powder. Do NOT get water inside
containers. DO NOT USE WATER, CO2, OR FOAM DIRECTLY ON FIRE ITSELF.
Use dry sand, graphite powder, dry sodium chloride-based
extinguishers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Very fine particles can cause a fire or explosion. Eliminate all
ignition sources. Clean up spills immediately, observing precautions
in the Protective Equipment section. Sweep up, then place into a
suitable container for disposal. Avoid generating dusty conditions.
Use a spark-proof tool. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Use with
adequate ventilation. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not allow contact with water. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Keep from contact
with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 7440-21-3:
United Kingdom, WEL - TWA: (listed as silica, amorphous): 6 mg/m3
(inhalable dust); 2.4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: 30 ppm STEL (inhalable dust); 12 mg/m
STEL (respirable dust)
United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA
(respirable fraction)
Belgium - TWA: 10 mg/m3 VLE
France - VME: 10 mg/m3 VME
Netherlands: 10 mg/m3 MAC
Russia: (listed as silica, amorphous): 1 mg/m3 TWA
Spain: 10 mg/m3 VLA-ED (inhalable fraction); 4 mg/m3 VLA-ED
(respirable fraction)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white crystalline powder
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 2355 deg C @ 760.00mm Hg
Freezing/Melting Point: 1410 deg C
Autoignition Temperature: > 150 deg C (> 302.00 deg F)
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble in nitric acid and hydrochlori
Specific Gravity/Density: 2.3300g/cm3
Molecular Formula: Si
Molecular Weight: 28.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, moisture,
excess heat, strong oxidants.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, oxides of silicon.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7440-21-3: VW0400000
LD50/LC50:
CAS# 7440-21-3: Draize test, rabbit, eye: 3 mg Mild; Oral, rat: LD50
= 3160 mg/kg.
Carcinogenicity:
Silicon -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: SILICON POWDER, AMORPHOUS
Hazard Class: 4.1
UN Number: 1346
Packing Group: III
IMO
Shipping Name: SILICON POWDER, AMORPHOUS
Hazard Class: 4.1
UN Number: 1346
Packing Group: III
RID/ADR
Shipping Name: SILICON POWDER, AMORPHOUS
Hazard Class: 4.1
UN Number: 1346
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7440-21-3: No information available.
Canada
CAS# 7440-21-3 is listed on Canada's DSL List.
CAS# 7440-21-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7440-21-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Ethyl chloroacetate
| 105-39-5 |
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1,2:3,4-Di-O-isopropylidene-D-galactopyranose, 97%
| 4064-06-6 |
|
4-Nitrophenylhydrazine, 98%
| 100-16-3 |
|
1,1,4,4-Tetraphenyl-1,3-Butadiene, 99%
| 1450-63-1 |
|
2-Mercaptopyridine-n-oxide, sodium salt, monohydrate,98%
| 3811-73-2 |
|
1,3-Propane sultone, 97%
| 1120-71-4 |
|
Poly(ethylene glycol methyl ether), average M.W. 350
| 9004-74-4 |
|
Poly(ethylene glycol methyl ether), average mw. 750
| 9004-74-4 |
|
Azetidine, 99+%
| 503-29-7 |
|
Methyl Violet 2B High Purity Biological Stain
| 8004-87-3 |
|
Methyl Violet 2B (Cert)
| 8004-87-3 |
|
4,7-Diphenyl-1,10-Phenanthroline, 99%
| 1662-01-7 |
|
1',3',3'-Trimethyl-6-hydroxyspiro (2h-1-benzopyran-2,2'-indoline)
| 23001-29-8 |
|
Diethyl Carbonate, 99%
| 105-58-8 |
|
1,2,4-1h-triazole, 99+%, flakes
| 288-88-0 |
|
Hydroquinone Bis(2-Hydroxyethyl)ether, 99+%
| 104-38-1 |
|
Silicon, Pieces, 99.9999%
| 7440-21-3 |
|
Silicon, Powder, -60 Mesh, 99.999%
| 7440-21-3 |
|
Phenanthrenequinone, tech. 80%
| 84-11-7 |
|
3-Aminofluoranthene
| 2693-46-1 |
|
Phenanthrenequinone, 98% (uv-vis)
| 84-11-7 |
|
4-(4-Chlorophenyl)-4-hydroxypiperidine, 99%(titr.)
| 39512-49-7 |
|
4-Methyl-3-nitrobenzyl alcohol, 99%
| 40870-59-5 |
|
Amberlite ira-410 ion-exchange resin
| 9002-26-0 |
|
Isoprene, 99+%, stabilized with 100 ppm 4-tert-butylcatechol
| 78-79-5 |
|
Poly(isoprene), cis, average M.W. 800,000
| 9003-31-0 |
|
Isopropenyl Acetate, 99%
| 108-22-5 |
|
N,N,N',N'-Tetramethyl-p-phenylenediamine dihydrochloride, 96%
| 637-01-4 |
|
Ethyl-Vinyl Ether, 99%, stabilized with 0.1% Potassium Hydroxide
| 109-92-2 |
|
1,1,1-Trichloro-2-methyl-2-propanol hemihydrate
| 57-15-8 |
|
n-Butyric Anhydride, 98%
| 106-31-0 |
|
2,2',4'-Trichloroacetophenone,tech.
| 4252-78-2 |
|
Benz(a)anthracene-7,12-dione, 99%
| 2498-66-0 |
|
(+)-Limonene, 97%, stabilized with 0.03% Tocopherol
| 5989-27-5 |
|
(+)-Limonene, tech., 95%, stabilized with 0.03% Tocopherol
| 5989-27-5 |
|
2,4-Dichlorophenoxyacetic acid, 99+%
| 94-75-7 |
|
??-nicotinamide adenine dinucleotide, disodium salt,reduced form, 98%
| 606-68-8 |
|
4-Bromobenzaldehyde, 99%
| 1122-91-4 |
|
Benzyl cyanide, 99+%
| 140-29-4 |
|
5-Bromosalicylaldehyde, 99%
| 1761-61-1 |
|
Silica Gel, 60-200 Mesh
| 7631-86-9 |
|
Poly(acrylic acid), sec. stand., aver. M.W. 1,080,000, aver. M.N.
| 9003-01-4 |
|
Poly(acrylic acid), 50 wt. % solution in water
| 7732-18-5 |
|
(R)-(+)-1-Benzylglycerol, 97%
| 56552-80-8 |
|
Poly(acrylic acid), 25 wt% solution in water
| 7732-18-5 |
|
Poly(acrylic acid), 52-56% aqueous solution
| 7732-18-5 |
|
Potassium nitrosodisulfonate, 50-75%, remainder water and methanol
| 14293-70-0 |
|
Zinc, Powder, -200 Mesh, 99.9999%
| 7440-66-6 |
|
2-Dimethylaminoisopropyl chloride hydrochloride, 98.5% (titr.)
| 4584-49-0 |
|
Zinc, Mossy, 99+%
| 7440-66-6 |
|
|