**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-99-6 |3-Picoline | 99+% | 203-636-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful if swallowed. Irritating to eyes, respiratory
system and skin.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes severe skin irritation. May be harmful if absorbed through
the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Intoxication may include weight loss, diarrhea, weakness, ataxia
(failure of muscular coordination), and unconsciousness.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Vapors may cause dizziness or suffocation. Exposure may give rise to
flushing of face, skin rash, an increase in heart and respiration
rates, headaches, giddiness, nausea, and vomiting.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Containers may explode
in the heat of a fire. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. May be ignited by heat, sparks, and flame.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. For large fires,
use water spray, fog or regular foam. For small fires, use dry
chemical, carbon dioxide, water spray or regular foam. Cool
containers with flooding quantities of water until well after fire is
out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Do not ingest
or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind,
or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 108-99-6:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear amber
Odor: sweetish odor
pH: Not available.
Vapor Pressure: 6.05 mm Hg @25C
Viscosity: Not available.
Boiling Point: 143.0 - 144.0 deg C @ 760.00m
Freezing/Melting Point: 18.3 deg C
Autoignition Temperature: Not available.
Flash Point: 40 deg C ( 104.00 deg F)
Explosion Limits, lower: 1.30 vol %
Explosion Limits, upper: 8.70 vol %
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: .96
Molecular Formula: C6H7N
Molecular Weight: 93.13
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Acid chlorides, acids, chloroformates, oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-99-6: TJ5000000
LD50/LC50:
CAS# 108-99-6: Dermal, guinea pig: LD50 = 1 gm/kg; Draize test,
rabbit, eye: 100 uL/24H Severe; Draize test, rabbit, skin: 200
uL/24H Severe; Oral, rat: LD50 = 400 mg/kg.
Carcinogenicity:
3-Picoline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PICOLINES
Hazard Class: 3
UN Number: 2313
Packing Group: III
IMO
Shipping Name: PICOLINES
Hazard Class: 3.3 (8)
UN Number: 2313
Packing Group: III
RID/ADR
Shipping Name: PICOLINES
Hazard Class: 3
UN Number: 2313
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
WGK (Water Danger/Protection)
CAS# 108-99-6: 2
Canada
CAS# 108-99-6 is listed on Canada's DSL List.
CAS# 108-99-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-99-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/21/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N-Propyl Acetate, 99+%
| 109-60-4 |
|
Rhodizonic acid dipotassium salt, 95% (uv-vis)
| 13021-40-4 |
|
delta-Valerolactone, 99%
| 542-28-9 |
|
Octaethylporphine
| 2683-82-1 |
|
(2r,4r)-(-)-pentanediol, 99%
| 42075-32-1 |
|
3'-Chloropropiophenone, 98%
| 34841-35-5 |
|
16-Doxyl-Stearic Acid, Free Radical
| 53034-38-1 |
|
(Trifluoromethoxy)benzene, 99+%
| 456-55-3 |
|
N-Butyramide 99%
| 541-35-5 |
|
O-Acetylmandelic acid chloride, 95%
| 1638-63-7 |
|
2-Ethylhexyl cyanoacetate, 98+%
| 13361-34-7 |
|
Pyruvic aldehyde dimethyl acetal, 98%
| 6342-56-9 |
|
1,1'-Diethyl-2,2'-Cyanine Iodide, 99% (UV-Vis)
| 977-96-8 |
|
Isophthaloyl dichloride, 98%
| 99-63-8 |
|
Dibutyltin diacetate, pract.
| 1067-33-0 |
|
Methyl cinnamate, 98%
| 103-26-4 |
|
L-Cystine Dimethyl Ester Dihydrochloride
| 32854-09-4 |
|
Corn Oil, U.S.P./N.F.
| 8001-30-7 |
|
3-Iodobenzylamine hydrochloride, 97%
| 3718-88-5 |
|
4-Phenoxyphenol, 99%
| 831-82-3 |
|
1,10-Phenanthroline monohydrochloride monohydrate, 97%
| 3829-86-5 |
|
Ethyl 3-N-Ethyl-Aminoacrylate
| 55330-56-8 |
|
Phenetole, 99%
| 103-73-1 |
|
Nickel atomic absorption standard solution, 1 mg/ml Ni in 2% HNO3
| 7440-02-0 |
|
Ethyl Glycolate, 95% (GC)
| 623-50-7 |
|
Magnesium Fluoride, 98+%
| 7783-40-6 |
|
Homovanillic Acid, 98%
| 306-08-1 |
|
(R,R)-(-)-1,2-Dicyclohexyl-1,2-Ethanediol, 99%
| 120850-92-2 |
|
Methyl nicotinate, 99%
| 93-60-7 |
|
D-(+)-Talose, 99%
| 2595-98-4 |
|
1,3-Phenylenediacetic acid, 97%
| 19806-17-8 |
|
Ethyl 4-bromocrotonate, tech., 75%
| 37746-78-4 |
|
(s)-(-)-alpha-(1-Naphtyl)ethylamine, 99+%,
| 10420-89-0 |
|
Homophthalic acid, 99%
| 89-51-0 |
|
p-Xylene-alpha,alpha,alpha,alpha',alpha',alpha'-d6, 99+ atom % D
| 106-42-3 |
|
Coumestrol, 99% (UV-Vis)
| 479-13-0 |
|
2-Amino-5-nitropyridine, 99%
| 4214-76-0 |
|
2-Amino-5-Chlorobenzoxazole, 97%
| 61-80-3 |
|
alpha-Naphtholphthalein, indicator
| 596-01-0 |
|
3-Picoline, 99.5+%
| 108-99-6 |
|
Chromium(vi) oxide pyridine complex
| 20492-50-6 |
|
N-Butylcarbamate, 97%
| 592-35-8 |
|
6-Bromo-7-Nitroquinoxaline, 95%
| 113269-09-3 |
|
n-2-Acetylguanine, 99+%
| 19962-37-9 |
|
1,2:5,6-Di-O-Isopropylidene-Alpha-D-Allofuranose, 98%
| 2595-05-3 |
|
N-Cyanoimido Dimethyl Carbonate, 95% (on Dry Substance)
| 0-00-1 |
|
l-(-)-Glyceraldehyde 90 wt% aqueous solution
| 497-09-6 |
|
5-Aminoisophthalic Acid, 98+%(Titr.; Dry Substance)
| 99-31-0 |
|
Flufenamic Acid, 97%
| 530-78-9 |
|
Lipase AY30, according to amano's specification
| 9001-62-1 |
|
|