**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 623-50-7 |Acetic acid, hydroxy-, ethyl ester | 95 | 210-798-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Absorption into the body may cause cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood).
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood).
Inhalation:
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). Causes respiratory tract irritation.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively. If cyanosis is severe,
intravenous injection of Methylene Blue, 1mg/kg of body weight may be
of value.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases may
be generated by thermal decomposition or combustion. Use water spray
to keep fire-exposed containers cool. Vapors may be heavier than
air. They can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with
flooding quantities of water until well after fire is out. Use water
spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Avoid contact with skin and eyes.
Keep container tightly closed. Avoid ingestion and inhalation. Wash
clothing before reuse.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 623-50-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 160 deg C
Freezing/Melting Point: 0 deg C
Autoignition Temperature: Not available.
Flash Point: 143 deg F ( 61.67 deg C)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble in ether or alcohol
Specific Gravity/Density: 1.0800g/cm3
Molecular Formula: C4H8O3
Molecular Weight: 104.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 623-50-7: MC5410000
LD50/LC50:
Not available.
Carcinogenicity:
Acetic acid, hydroxy-, ethyl ester -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 623-50-7: No information available.
Canada
CAS# 623-50-7 is listed on Canada's DSL List.
CAS# 623-50-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 623-50-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/22/1998 Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
N-Propyl Acetate, 99+%
| 109-60-4 |
|
Rhodizonic acid dipotassium salt, 95% (uv-vis)
| 13021-40-4 |
|
delta-Valerolactone, 99%
| 542-28-9 |
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Octaethylporphine
| 2683-82-1 |
|
(2r,4r)-(-)-pentanediol, 99%
| 42075-32-1 |
|
3'-Chloropropiophenone, 98%
| 34841-35-5 |
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16-Doxyl-Stearic Acid, Free Radical
| 53034-38-1 |
|
(Trifluoromethoxy)benzene, 99+%
| 456-55-3 |
|
N-Butyramide 99%
| 541-35-5 |
|
O-Acetylmandelic acid chloride, 95%
| 1638-63-7 |
|
2-Ethylhexyl cyanoacetate, 98+%
| 13361-34-7 |
|
Pyruvic aldehyde dimethyl acetal, 98%
| 6342-56-9 |
|
1,1'-Diethyl-2,2'-Cyanine Iodide, 99% (UV-Vis)
| 977-96-8 |
|
Isophthaloyl dichloride, 98%
| 99-63-8 |
|
Dibutyltin diacetate, pract.
| 1067-33-0 |
|
Methyl cinnamate, 98%
| 103-26-4 |
|
L-Cystine Dimethyl Ester Dihydrochloride
| 32854-09-4 |
|
Corn Oil, U.S.P./N.F.
| 8001-30-7 |
|
3-Iodobenzylamine hydrochloride, 97%
| 3718-88-5 |
|
4-Phenoxyphenol, 99%
| 831-82-3 |
|
1,10-Phenanthroline monohydrochloride monohydrate, 97%
| 3829-86-5 |
|
Ethyl 3-N-Ethyl-Aminoacrylate
| 55330-56-8 |
|
Phenetole, 99%
| 103-73-1 |
|
Nickel atomic absorption standard solution, 1 mg/ml Ni in 2% HNO3
| 7440-02-0 |
|
Ethyl Glycolate, 95% (GC)
| 623-50-7 |
|
Magnesium Fluoride, 98+%
| 7783-40-6 |
|
Homovanillic Acid, 98%
| 306-08-1 |
|
(R,R)-(-)-1,2-Dicyclohexyl-1,2-Ethanediol, 99%
| 120850-92-2 |
|
Methyl nicotinate, 99%
| 93-60-7 |
|
D-(+)-Talose, 99%
| 2595-98-4 |
|
1,3-Phenylenediacetic acid, 97%
| 19806-17-8 |
|
Ethyl 4-bromocrotonate, tech., 75%
| 37746-78-4 |
|
(s)-(-)-alpha-(1-Naphtyl)ethylamine, 99+%,
| 10420-89-0 |
|
Homophthalic acid, 99%
| 89-51-0 |
|
p-Xylene-alpha,alpha,alpha,alpha',alpha',alpha'-d6, 99+ atom % D
| 106-42-3 |
|
Coumestrol, 99% (UV-Vis)
| 479-13-0 |
|
2-Amino-5-nitropyridine, 99%
| 4214-76-0 |
|
2-Amino-5-Chlorobenzoxazole, 97%
| 61-80-3 |
|
alpha-Naphtholphthalein, indicator
| 596-01-0 |
|
3-Picoline, 99.5+%
| 108-99-6 |
|
Chromium(vi) oxide pyridine complex
| 20492-50-6 |
|
N-Butylcarbamate, 97%
| 592-35-8 |
|
6-Bromo-7-Nitroquinoxaline, 95%
| 113269-09-3 |
|
n-2-Acetylguanine, 99+%
| 19962-37-9 |
|
1,2:5,6-Di-O-Isopropylidene-Alpha-D-Allofuranose, 98%
| 2595-05-3 |
|
N-Cyanoimido Dimethyl Carbonate, 95% (on Dry Substance)
| 0-00-1 |
|
l-(-)-Glyceraldehyde 90 wt% aqueous solution
| 497-09-6 |
|
5-Aminoisophthalic Acid, 98+%(Titr.; Dry Substance)
| 99-31-0 |
|
Flufenamic Acid, 97%
| 530-78-9 |
|
Lipase AY30, according to amano's specification
| 9001-62-1 |
|
|