**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 109-86-4 |2-Methoxyethanol | 52.25 | 203-713-7 |
|----------------|--------------------------------------|----------|-----------|
| 110-86-1 |Pyridine | 25.40 | 203-809-9 |
|----------------|--------------------------------------|----------|-----------|
| 7446-09-5 |Sulfur dioxide | 7.80 | 231-195-2 |
|----------------|--------------------------------------|----------|-----------|
| 7553-56-2 |Iodine | 14.55 | 231-442-4 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 10 23/24/25 60 61
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Toxic by inhalation, in contact with skin and if
swallowed. May impair fertility. May cause harm to the unborn
child.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause blindness. May cause permanent
corneal opacification. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin burns. May be absorbed through the skin in harmful
amounts. May cause skin irritation and possible burns. May cause
irritation and dermatitis. May cause cyanosis of the extremities.
Ingestion:
Causes gastrointestinal tract burns. May cause kidney damage. May
cause liver damage. Ingestion of large amounts may cause CNS
depression. May cause nausea, vomiting, and diarrhea, possibly with
blood.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. May cause central nervous system effects including
vertigo, anxiety, depression, muscle incoordination, and emotional
instability. Exposure produces central nervous system depression.
Aspiration may lead to pulmonary edema. Vapors may cause dizziness or
suffocation. May cause burning sensation in the chest. May cause
acute pulmonary edema, asphyxia, chemical pneumonitis, and upper
airway obstruction caused by edema.
Chronic:
Chronic exposure to organic solvents has been associated with
various neurotoxic effects including permanent brain and nervous
system damage. Prolonged or repeated skin contact may cause
sensitization dermatitis and possible destruction and/or ulceration.
May cause liver and kidney damage. May cause fetal effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Vaporizes
easily at normal temperatures. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Water may be
ineffective. Material is lighter than water and a fire may be spread
by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. May form explosive peroxides. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Isolate area and deny
entry. Place under an inert atmosphere. A vapor suppressing foam may
be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Ground and
bond containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with skin and eyes. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Take precautionary measures against static discharges.
Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Use only in a chemical fume hood. If peroxide formation
is suspected, do not open or move container. Avoid contact with air
and sunlight. Keep away from flames and other sources of high
temperatures that may cause material to form vapors. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Unused chemicals should
not be returned to the container. Do not distill since this removes
peroxide-inhibitors.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry place. Do not store in direct
sunlight. Store in a tightly closed container. Flammables-area.
Regularly check inhibitor levels to maintain peroxide levels below
1%. Keep containers tightly closed. Do not break the seal on the
container until it is needed. Label the container with the date it
was first opened. Long-term storage is not recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 109-86-4:
United Kingdom, WEL - TWA: 5 ppm TWA; 16 mg/m3 TWA
United Kingdom, WEL - STEL: 15 ppm STEL; 48 mg/m3 STEL
United States OSHA: 25 ppm TWA; 80 mg/m3 TWA
Belgium - TWA: 5 ppm VLE; 16 mg/m3 VLE
France - VME: 5 ppm VME; 16 mg/m3 VME
Germany: 5 ppm TWA; 16 mg/m3 TWA
Germany: Skin absorber
Japan: 5 ppm OEL; 16 mg/m3 OEL
Malaysia: 5 ppm TWA; 16 mg/m3 TWA
Netherlands: 0.3 ppm MAC; 1 mg/m3 MAC
Spain: 5 ppm VLA-ED; 16 mg/m3 VLA-ED
CAS# 110-86-1:
United Kingdom, WEL - TWA: 5 ppm TWA; 16 mg/m3 TWA
United Kingdom, WEL - STEL: 10 ppm STEL; 33 mg/m3 STEL
United States OSHA: 5 ppm TWA; 15 mg/m3 TWA
Belgium - TWA: 5 ppm VLE; 16 mg/m3 VLE
France - VME: 5 ppm VME; 15 mg/m3 VME
France - VLE: 10 ppm VLE; 30 mg/m3 VLE
Germany: 5 ppm TWA; 16 mg/m3 TWA
Germany: Skin absorber
Malaysia: 5 ppm TWA; 16 mg/m3 TWA
Netherlands: 0.3 ppm MAC; 0.9 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 15 mg/m3 VLA-ED
CAS# 7446-09-5:
United States OSHA: 5 ppm TWA; 13 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 5.3 mg/m3 VLE
Belgium - STEL: 5 ppm VLE; 13 mg/m3 VLE
France - VME: 2 ppm VME; 5 mg/m3 VME
France - VLE: 5 ppm VLE; 10 mg/m3 VLE
Germany: 1 ppm TWA (paper production, chemical and pharmaceutical
industries); 2.5 mg/m3
Malaysia: 2 ppm TWA; 5.2 mg/m3 TWA
Netherlands: 2 ppm MAC; 5 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 2 ppm VLA-ED; 5.3 mg/m3 VLA-ED
Spain: 5 ppm VLA-EC; 13 mg/m3 VLA-EC
CAS# 7553-56-2:
United Kingdom, WEL - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL
United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling
Belgium - TWA: 0.1 ppm VLE; 1 mg/m3 VLE
France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE
Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA
Germany: Skin absorber
Japan: 0.1 ppm OEL; 1 mg/m3 OEL
Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling
Russia: 1 mg/m3 TWA
Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: dark brown
Odor: disagreeable odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 100 deg F ( 37.78 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 0.93
Molecular Formula: Not applicable.
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. On long term storage, substances with similar functional
groups form explosive peroxides. Explosive peroxides may form on
concentration. Peroxides can be detonated by friction, impact, or
heating. Tends to form explosive peroxides; especially when
anhydrous. Peroxide formation may occur in containers that have been
opened and remain in storage.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources, exposure
to air, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Acid anhydrides, strong acids, strong bases, strong oxidizing agents,
water, metal oxides, metals, oils, halogens, interhalogens.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide,
hydrogen iodide, iodine.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-86-4: KL5775000
CAS# 110-86-1: UR8400000
CAS# 7446-09-5: WS4550000
CAS# 7553-56-2: NN1575000
LD50/LC50:
CAS# 109-86-4: Draize test, rabbit, eye: 97 mg; Draize test, rabbit,
eye: 500 mg/24H Mild; Draize test, rabbit, skin: 483 mg/24H Mild;
Inhalation, mouse: LC50 = 1480 ppm/7H; Inhalation, rat: LC50 = 1500
ppm/7H; Oral, mouse: LD50 = 2560 mg/kg; Oral, mouse: LD50 = 2800
mg/kg; Oral, rabbit: LD50 = 890 mg/kg; Oral, rat: LD50 = 2370 mg/kg;
Oral, rat: LD50 = 2460 mg/kg; Skin, rabbit: LD50 = 1280 mg/kg; Skin,
rabbit: LD50 = 2000 mg/kg.
CAS# 110-86-1: Dermal, guinea pig: LD50 = 1 gm/kg; Draize test,
rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = 28500
mg/m3/1H; Oral, mouse: LD50 = 1500 mg/kg; Oral, rat: LD50 = 891
mg/kg; Skin, rabbit: LD50 = 1121 mg/kg.
CAS# 7446-09-5: Draize test, rabbit, eye: 6 ppm/32D Mild;
Inhalation, mouse: LC50 = 3000 ppm/30M; Inhalation, rat: LC50 = 2520
ppm/1H; Inhalation, rat: LC50 = 2168 mg/m3.
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 =
1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14
gm/kg.
Carcinogenicity:
2-Methoxyethanol -
Not listed by ACGIH, IARC, or NTP.
Pyridine -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 5/17/02
Sulfur dioxide -
Not listed by ACGIH, IARC, or NTP.
Iodine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
No information available.
IMO
No information available.
RID/ADR
No information available.
USA RQ: CAS# 110-86-1: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 61 May cause harm to the unborn child.
R 10 Flammable.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 60 May impair fertility.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 109-86-4: 1
CAS# 110-86-1: 2
CAS# 7446-09-5: 1
CAS# 7553-56-2: 1
Canada
CAS# 109-86-4 is listed on Canada's DSL List.
CAS# 110-86-1 is listed on Canada's DSL List.
CAS# 7446-09-5 is listed on Canada's DSL List.
CAS# 7553-56-2 is listed on Canada's DSL List.
CAS# 109-86-4 is listed on Canada's Ingredient Disclosure List.
CAS# 110-86-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7446-09-5 is listed on Canada's Ingredient Disclosure List.
CAS# 7553-56-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-86-4 is listed on the TSCA inventory.
CAS# 110-86-1 is listed on the TSCA inventory.
CAS# 7446-09-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 20/21/22 Harmful by inhalation, in contact with skin and
if swallowed.
R 60 May impair fertility.
R 61 May cause harm to the unborn child.
MSDS Creation Date: 11/06/2001 Revision #2 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|