**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-63-0 |Isopropyl alcohol | 50 | 200-661-7 |
|----------------|--------------------------------------|----------|-----------|
| 108-88-3 |Toluene | 50 | 203-625-9 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN F
Risk Phrases: 11 36/37 20 63 67
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes and respiratory system. Harmful
by inhalation. Possible risk of harm to the unborn child. Vapours may
cause drowsiness and dizziness.
Potential Health Effects
Eye:
May result in corneal injury. Produces irritation, characterized
by a burning sensation, redness, tearing, inflammation, and possible
corneal injury.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Prolonged and/or repeated
contact may cause defatting of the skin and dermatitis. May cause
irritation with pain and stinging, especially if the skin is abraded.
Ingestion:
Aspiration hazard. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause systemic toxicity with
acidosis. May cause liver and kidney damage. May cause central
nervous system depression, characterized by excitement, followed by
headache, dizziness, drowsiness, and nausea. Advanced stages may
cause collapse, unconsciousness, coma and possible death due to
respiratory failure. Aspiration of material into the lungs may cause
chemical pneumonitis, which may be fatal.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. May cause liver and
kidney damage. May cause cardiac sensitization and possible failure.
May cause heart disturbances, possibly leading to cardiac arrest and
death. May cause drowsiness, unconsciousness, and central nervous
system depression.
Chronic:
May cause cardiac sensitization and severe heart abnormalities. May
cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Causes cardiac sensitization to endogenous catelcholamines which may
lead to cardiac arrhythmias. Do NOT use adrenergic agents such as
epinephrine or pseudoepinephrine.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Containers may explode in the heat of a fire. Flammable liquid and
vapor. May form explosive peroxides. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. May be ignited by heat, sparks, and flame. Containers may
explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. A vapor suppressing foam
may be used to reduce vapors. Water spray may reduce vapor but may
not prevent ignition in closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Keep from contact with oxidizing materials. Store in a
cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 67-63-0:
United Kingdom, WEL - TWA: 400 ppm TWA; 999 mg/m3 TWA
United Kingdom, WEL - STEL: 500 ppm STEL; 1250 mg/m3 STEL
United States OSHA: 400 ppm TWA; 980 mg/m3 TWA
Belgium - TWA: 400 ppm VLE; 997 mg/m3 VLE
Belgium - STEL: 500 ppm VLE; 1248 mg/m3 VLE
France - VLE: 400 ppm VLE; 980 mg/m3 VLE
Germany: 200 ppm TWA; 500 mg/m3 TWA
Japan: 400 ppm Ceiling; 980 mg/m3 Ceiling
Malaysia: 400 ppm TWA; 983 mg/m3 TWA
Netherlands: 250 ppm MAC; 650 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 400 ppm VLA-ED; 998 mg/m3 VLA-ED
Spain: 500 ppm VLA-EC; 1250 mg/m3 VLA-EC
CAS# 108-88-3:
United Kingdom, WEL - TWA: 50 ppm TWA; 191 mg/m3 TWA
United Kingdom, WEL - STEL: 150 ppm STEL; 574 mg/m3 STEL
United States OSHA: 200 ppm TWA; 300 ppm Ceiling
Belgium - TWA: 50 ppm VLE; 191 mg/m3 VLE
France - VME: 100 ppm VME; 375 mg/m3 VME
France - VLE: 150 ppm VLE; 550 mg/m3 VLE
Germany: 50 ppm TWA; 190 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 188 mg/m3 OEL
Malaysia: 50 ppm TWA; 188 mg/m3 TWA
Netherlands: 40 ppm MAC; 150 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 50 ppm VLA-ED; 191 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: toluene-like odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: 810 deg F ( 432.22 deg C)
Flash Point: 40 deg F ( 4.44 deg C)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water.
Specific Gravity/Density: 0.82
Molecular Formula: Mixture
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. This material may be
sensitive to peroxide formation.
Conditions to Avoid:
This material may be sensitive to peroxide formation., incompatible
materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing,
e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid),
acids (organic, e.g. acetic acid, benzoic acid, formic acid,
methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g.
dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g.
methyl isocyanate), metals (alkali and alkaline, e.g. cesium,
potassium, sodium), nitrides (e.g. potassium nitride, sodium
nitride), peroxides and hydroperoxides (organic, e.g. acetyl
peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone
peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents
(strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide,
potassium nitrate), reducing agents (strong, e.g. aluminum carbide,
chlorosilane, hydrogen phosphide, lithium hydride), water reactive
substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium
carbide, ethyl dichlorosilane), Isopropanol is susceptible to
autoxidation and therefore should be classified as peroxidizable..
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-63-0: NT8050000
CAS# 108-88-3: XS5250000
LD50/LC50:
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H
Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, mouse:
LC50 = 53000 mg/m3; Inhalation, rat: LC50 = 16000 ppm/8H; Inhalation,
rat: LC50 = 72600 mg/m3; Oral, mouse: LD50 = 3600 mg/kg; Oral, mouse:
LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 =
5045 mg/kg; Oral, rat: LD50 = 5000 mg/kg; Skin, rabbit: LD50 = 12800
mg/kg.
CAS# 108-88-3: Draize test, rabbit, eye: 870 ug Mild; Draize test,
rabbit, eye: 2 mg/24H Severe; Draize test, rabbit, skin: 435 mg Mild;
Draize test, rabbit, skin: 500 mg Moderate; Draize test, rabbit,
skin: 20 mg/24H Moderate; Inhalation, mouse: LC50 = 400 ppm/24H;
Inhalation, mouse: LC50 = 30000 mg/m3/2H; Inhalation, mouse: LC50 =
19900 mg/m3/7H; Inhalation, mouse: LC50 = 10000 mg/m3; Inhalation,
rat: LC50 = 49 gm/m3/4H; Oral, rat: LD50 = 636 mg/kg; Skin, rabbit:
LD50 = 14100 uL/kg.
Carcinogenicity:
Isopropyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Toluene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
2-Propanol:Acute aquatic effects
Fathead minnow: LC50 =1000 mg/L/96
Hr.
Golden orfe: LC50 = 8970 mg/L/48 Hr.
Goldfish: LC50 = GT5000
mg/L/24 Hr.
LC50 (96Hr.) Fathead Minnow = 94900-10400 mg/L;
Flow-through condition
LC50 (96 Hr.) Fathead Minnow = 61200-65500
mg/L;Flow-through condition.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (TOLUENE, ISOPROPANOL)
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (TOLUENE, ISOPROPANOL)
Hazard Class: 3
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUIDS, N.O.S. (TOLUENE, ISOPROPANOL)
Hazard Class: 3
UN Number: 1993
Packing group: II
USA RQ: CAS# 108-88-3: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 36/37 Irritating to eyes and respiratory system.
R 63 Possible risk of harm to the unborn child.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 108-88-3: 2
Canada
CAS# 67-63-0 is listed on Canada's DSL List.
CAS# 108-88-3 is listed on Canada's DSL List.
CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List.
CAS# 108-88-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 108-88-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 36 Irritating to eyes.
R 20 Harmful by inhalation.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 10/19/2001 Revision #2 Date: 7/07/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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