**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-13-7 |2-Octanone | 98 | 203-837-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 21
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful in contact with skin.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Adverse reproductive effects have been reported in animals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid if irritation or symptoms
occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
Water may be ineffective. Use water spray, dry chemical, carbon
dioxide, or chemical foam. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation. Use with adequate
ventilation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 111-13-7:
Russia: 200 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Clear - colorless
Odor: fresh green odor - floral-like
pH: Not available.
Vapor Pressure: .75 mm Hg @20 C
Viscosity: Not available.
Boiling Point: 173 deg C @ 760.00mmHg
Freezing/Melting Point: -16 deg C
Autoignition Temperature: Not available.
Flash Point: 62 deg C ( 143.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: .8190g/cm3
Molecular Formula: C8H16O
Molecular Weight: 128.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-13-7: RH1484000
LD50/LC50:
CAS# 111-13-7: Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, mouse: LC50 = 102000 mg/m3; Inhalation, rat: LC50 = >2132
ppm/6H; Oral, mouse: LD50 = 3100 mg/kg; Oral, rat: LD50 = 3089 mg/kg;
Skin, rabbit: LD50 = 1337 mg/kg.
Oral, Rat:LD50 = 3089 mg/kg
hour
Carcinogenicity:
2-Octanone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 36 mg/L; 96 hour; Hard WaterBacteria:
Gold orfe: EC50 = 11.7 ppm; 5 minutes; Microtox Test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 21 Harmful in contact with skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 111-13-7: 1
Canada
CAS# 111-13-7 is listed on Canada's DSL List.
CAS# 111-13-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-13-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/26/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Lutidine, 99%
| 108-48-5 |
|
GIRARD REAGENT D, 98% (TITR.)
| 539-64-0 |
|
4,4'-Azo-Bis-(4-Cyanovaleric Acid), 97%
| 2638-94-0 |
|
4-Hydroxybenzaldehyde, 99%
| 123-08-0 |
|
2-Phenylbenzimidazole, P.A.
| 716-79-0 |
|
Butyryl Chloride, 98%
| 141-75-3 |
|
Iminodiacetic Acid, Disodium Salt Monohydrate, 97%
| 17593-73-6 |
|
Pybop, 99%
| 128625-52-5 |
|
1,6-Diphenyl-1,3,5-Hexatriene, 98%
| 1720-32-7 |
|
2-Methyl-2-propyl-1,3-propanediol,99%
| 78-26-2 |
|
Ammonium sulfobetaine - 2
| |
|
4-Bromophenyl isocyanate
| 2493-02-9 |
|
2-(Methylamino)ethanol, 99%
| 109-83-1 |
|
5-Chloro-2-methylbenzothiazole
| 1006-99-1 |
|
Succinic Acid 2,2-Dimethylhydrazide, 99%
| 1596-84-5 |
|
(s)-(-)-Propylene Oxide, 99%
| 16088-62-3 |
|
2-Methylaminoethanol, 97% (titr.)
| 109-83-1 |
|
Ethyl diethoxyacetate, 99%
| 6065-82-3 |
|
9-BBN, 0.5M solution in THF
| 109-99-9 |
|
9-BBN, 0.5M Solution in Hexane
| 110-54-3 |
|
Rutin, 97.0-102.0% (by Gravimetry on the Dry Substance)
| 153-18-4 |
|
DL-Isoleucine, 99%, Containing up to 10% of DL-Allo-Isoleucine
| 443-79-8 |
|
EPPS, 99%
| 16052-06-5 |
|
2-Butyne-1,4-Diol, 99%
| 110-65-6 |
|
4,4'-Diantipyrylmethane Monohydrate, 97%
| 1251-85-0 |
|
Cis,cis-1,5-cyclooctadiene, 99+%, stab. with 50-200ppm bht
| 111-78-4 |
|
N-Methylaniline, 98%
| 100-61-8 |
|
Ethylamine, solution in water, 70 wt. %
| 75-04-7 |
|
Benzonitrile, 99%
| 100-47-0 |
|
4-Chlorobenzonitrile, 99%
| 623-03-0 |
|
Methyl 4-Formylbenzoate, 99%
| 1571-08-0 |
|
Diphenylacetic Acid, 99+%
| 117-34-0 |
|
Trithiocyanuric acid, 95%
| 638-16-4 |
|
Ammonium nitrate, p.a.
| 6484-52-2 |
|
Potassium borohydride, 98%
| 13762-51-1 |
|
8-Benzyltheophylline, 99%
| 2879-15-4 |
|
Arsenic(III) chloride
| 7784-34-1 |
|
Dowex 50x8-100 Ion-Exchange Resin
| 11119-67-8 |
|
Dowex 50x8-400 Ion-Exchange Resin
| 11119-67-8 |
|
Cyclopropyl Carbinol, 99%
| 2516-33-8 |
|
O-Tolidine, 99% (Titr.)
| 119-93-7 |
|
Diethyl Pimelate, 99%
| 2050-20-6 |
|
11-Bromoundecanoic acid, 99+%
| 2834-05-1 |
|
11-Bromoundecanoic acid, 98% (gc)
| 2834-05-1 |
|
Methyl vinyl ether/maleic acid copolymer, high molecular weight
| 25153-40-6 |
|
Tri-n-octylphosphine oxide, 99%
| 78-50-2 |
|
Theophylline, Anhydrous, 99+% (Titr., on Dry Substance)
| 58-55-9 |
|
DL-Atrolactic Acid Hemihydrate, 98%
| 515-30-0 |
|
2-Octanone, 99+% (GC)
| 111-13-7 |
|
Poly(Ethylene Glycol), Average M.W. 200
| 25322-68-3 |
|
|