**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 141-75-3 |Butyryl Chloride | 98 | 205-498-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Causes burns.Stench.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. Ingestion of large amounts may cause CNS
depression. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Aspiration may lead to pulmonary edema. Vapors may cause dizziness or
suffocation. May cause systemic effects. May cause burning sensation
in the chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Do NOT allow victim to rub eyes or keep eyes
closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. May polymerize explosively when
involved in a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Do NOT use water directly on fire. Use water
spray to cool fire-exposed containers. Water may be ineffective. Do
NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Do not breathe dust, vapor, mist, or gas.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep container tightly closed. Keep away from
heat, sparks and flame. Do not ingest or inhale. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 141-75-3:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles. Wear appropriate
protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection
regulations in 29 CFR 1910.133 or European Standard
EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slightly yellow
Odor: butyl-like
pH: Not available.
Vapor Pressure: 39 hPa @ 20 C
Viscosity: Not available.
Boiling Point: 102 deg C @ 760.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 18 deg C ( 64.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.0260g/cm3
Molecular Formula: C4H7ClO
Molecular Weight: 106.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Alcohols, strong bases, strong oxidizing agents, water.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 141-75-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Butyryl Chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BUTYRYL CHLORIDE
Hazard Class: 3 (8)
UN Number: 2353
Packing Group: II
IMO
Shipping Name: BUTYRYL CHLORIDE
Hazard Class: 3.2 (8)
UN Number: 2353
Packing Group: II
RID/ADR
Shipping Name: BUTYRYL CHLORIDE
Hazard Class: 3
UN Number: 2353
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 36 Wear suitable protective clothing.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 141-75-3: 1
Canada
CAS# 141-75-3 is listed on Canada's DSL List.
CAS# 141-75-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 141-75-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Lutidine, 99%
| 108-48-5 |
|
GIRARD REAGENT D, 98% (TITR.)
| 539-64-0 |
|
4,4'-Azo-Bis-(4-Cyanovaleric Acid), 97%
| 2638-94-0 |
|
4-Hydroxybenzaldehyde, 99%
| 123-08-0 |
|
2-Phenylbenzimidazole, P.A.
| 716-79-0 |
|
Butyryl Chloride, 98%
| 141-75-3 |
|
Iminodiacetic Acid, Disodium Salt Monohydrate, 97%
| 17593-73-6 |
|
Pybop, 99%
| 128625-52-5 |
|
1,6-Diphenyl-1,3,5-Hexatriene, 98%
| 1720-32-7 |
|
2-Methyl-2-propyl-1,3-propanediol,99%
| 78-26-2 |
|
Ammonium sulfobetaine - 2
| |
|
4-Bromophenyl isocyanate
| 2493-02-9 |
|
2-(Methylamino)ethanol, 99%
| 109-83-1 |
|
5-Chloro-2-methylbenzothiazole
| 1006-99-1 |
|
Succinic Acid 2,2-Dimethylhydrazide, 99%
| 1596-84-5 |
|
(s)-(-)-Propylene Oxide, 99%
| 16088-62-3 |
|
2-Methylaminoethanol, 97% (titr.)
| 109-83-1 |
|
Ethyl diethoxyacetate, 99%
| 6065-82-3 |
|
9-BBN, 0.5M solution in THF
| 109-99-9 |
|
9-BBN, 0.5M Solution in Hexane
| 110-54-3 |
|
Rutin, 97.0-102.0% (by Gravimetry on the Dry Substance)
| 153-18-4 |
|
DL-Isoleucine, 99%, Containing up to 10% of DL-Allo-Isoleucine
| 443-79-8 |
|
EPPS, 99%
| 16052-06-5 |
|
2-Butyne-1,4-Diol, 99%
| 110-65-6 |
|
4,4'-Diantipyrylmethane Monohydrate, 97%
| 1251-85-0 |
|
Cis,cis-1,5-cyclooctadiene, 99+%, stab. with 50-200ppm bht
| 111-78-4 |
|
N-Methylaniline, 98%
| 100-61-8 |
|
Ethylamine, solution in water, 70 wt. %
| 75-04-7 |
|
Benzonitrile, 99%
| 100-47-0 |
|
4-Chlorobenzonitrile, 99%
| 623-03-0 |
|
Methyl 4-Formylbenzoate, 99%
| 1571-08-0 |
|
Diphenylacetic Acid, 99+%
| 117-34-0 |
|
Trithiocyanuric acid, 95%
| 638-16-4 |
|
Ammonium nitrate, p.a.
| 6484-52-2 |
|
Potassium borohydride, 98%
| 13762-51-1 |
|
8-Benzyltheophylline, 99%
| 2879-15-4 |
|
Arsenic(III) chloride
| 7784-34-1 |
|
Dowex 50x8-100 Ion-Exchange Resin
| 11119-67-8 |
|
Dowex 50x8-400 Ion-Exchange Resin
| 11119-67-8 |
|
Cyclopropyl Carbinol, 99%
| 2516-33-8 |
|
O-Tolidine, 99% (Titr.)
| 119-93-7 |
|
Diethyl Pimelate, 99%
| 2050-20-6 |
|
11-Bromoundecanoic acid, 99+%
| 2834-05-1 |
|
11-Bromoundecanoic acid, 98% (gc)
| 2834-05-1 |
|
Methyl vinyl ether/maleic acid copolymer, high molecular weight
| 25153-40-6 |
|
Tri-n-octylphosphine oxide, 99%
| 78-50-2 |
|
Theophylline, Anhydrous, 99+% (Titr., on Dry Substance)
| 58-55-9 |
|
DL-Atrolactic Acid Hemihydrate, 98%
| 515-30-0 |
|
2-Octanone, 99+% (GC)
| 111-13-7 |
|
Poly(Ethylene Glycol), Average M.W. 200
| 25322-68-3 |
|
|