**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 119-93-7 |3,3'-dimethylbenzidine | 99 | 204-358-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 45
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. May cause cancer.Air sensitive.Cancer suspect
agent.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
May cause cancer in humans.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes.
Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. Get medical aid if
cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation. Avoid contact with air and sunlight.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from light and air.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use
process enclosure, local exhaust ventilation, or other engineering
controls to control airborne levels.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions. Follow the OSHA respirator regulations
found in 29CFR 1910.134 or European Standard EN 149.
Always use a NIOSH or European Standard EN 149
approved respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: grey
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 300 deg C
Freezing/Melting Point: 129-131C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density:
Molecular Formula: C14H16N2
Molecular Weight: 212.29
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, exposure to air, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizers
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 119-93-7: DD1225000
LD50/LC50:
Not available.
Carcinogenicity:
3,3'-dimethylbenzidine -
ACGIH: A3 - Animal Carcinogen
California: carcinogen; initial date 1/1/88
NIOSH: occupational carcinogen
NTP: Suspect carcinogen
OSHA: Possible Select carcinogen
IARC: Group 2B carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Dangerous Goods Code: 6.1(25C)
UN Number: 2811
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 45 May cause cancer.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.
WGK (Water Danger/Protection)
CAS# 119-93-7: No information available.
United Kingdom Occupational Exposure Limits
Canada
CAS# 119-93-7 is listed on Canada's DSL List.
CAS# 119-93-7 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 119-93-7: OEL-AUSTRALIA;Skin;Carcinogen
OEL-FINLAND;Carcinogen
OEL-FRANCE;Carcinogen
OEL-GERMANY;Carcinogen
OEL-SWITZERLAND;Carcinogen
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 119-93-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/14/1998 Revision #2 Date: 8/02/2000
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2,6-Lutidine, 99%
| 108-48-5 |
|
GIRARD REAGENT D, 98% (TITR.)
| 539-64-0 |
|
4,4'-Azo-Bis-(4-Cyanovaleric Acid), 97%
| 2638-94-0 |
|
4-Hydroxybenzaldehyde, 99%
| 123-08-0 |
|
2-Phenylbenzimidazole, P.A.
| 716-79-0 |
|
Butyryl Chloride, 98%
| 141-75-3 |
|
Iminodiacetic Acid, Disodium Salt Monohydrate, 97%
| 17593-73-6 |
|
Pybop, 99%
| 128625-52-5 |
|
1,6-Diphenyl-1,3,5-Hexatriene, 98%
| 1720-32-7 |
|
2-Methyl-2-propyl-1,3-propanediol,99%
| 78-26-2 |
|
Ammonium sulfobetaine - 2
| |
|
4-Bromophenyl isocyanate
| 2493-02-9 |
|
2-(Methylamino)ethanol, 99%
| 109-83-1 |
|
5-Chloro-2-methylbenzothiazole
| 1006-99-1 |
|
Succinic Acid 2,2-Dimethylhydrazide, 99%
| 1596-84-5 |
|
(s)-(-)-Propylene Oxide, 99%
| 16088-62-3 |
|
2-Methylaminoethanol, 97% (titr.)
| 109-83-1 |
|
Ethyl diethoxyacetate, 99%
| 6065-82-3 |
|
9-BBN, 0.5M solution in THF
| 109-99-9 |
|
9-BBN, 0.5M Solution in Hexane
| 110-54-3 |
|
Rutin, 97.0-102.0% (by Gravimetry on the Dry Substance)
| 153-18-4 |
|
DL-Isoleucine, 99%, Containing up to 10% of DL-Allo-Isoleucine
| 443-79-8 |
|
EPPS, 99%
| 16052-06-5 |
|
2-Butyne-1,4-Diol, 99%
| 110-65-6 |
|
4,4'-Diantipyrylmethane Monohydrate, 97%
| 1251-85-0 |
|
Cis,cis-1,5-cyclooctadiene, 99+%, stab. with 50-200ppm bht
| 111-78-4 |
|
N-Methylaniline, 98%
| 100-61-8 |
|
Ethylamine, solution in water, 70 wt. %
| 75-04-7 |
|
Benzonitrile, 99%
| 100-47-0 |
|
4-Chlorobenzonitrile, 99%
| 623-03-0 |
|
Methyl 4-Formylbenzoate, 99%
| 1571-08-0 |
|
Diphenylacetic Acid, 99+%
| 117-34-0 |
|
Trithiocyanuric acid, 95%
| 638-16-4 |
|
Ammonium nitrate, p.a.
| 6484-52-2 |
|
Potassium borohydride, 98%
| 13762-51-1 |
|
8-Benzyltheophylline, 99%
| 2879-15-4 |
|
Arsenic(III) chloride
| 7784-34-1 |
|
Dowex 50x8-100 Ion-Exchange Resin
| 11119-67-8 |
|
Dowex 50x8-400 Ion-Exchange Resin
| 11119-67-8 |
|
Cyclopropyl Carbinol, 99%
| 2516-33-8 |
|
O-Tolidine, 99% (Titr.)
| 119-93-7 |
|
Diethyl Pimelate, 99%
| 2050-20-6 |
|
11-Bromoundecanoic acid, 99+%
| 2834-05-1 |
|
11-Bromoundecanoic acid, 98% (gc)
| 2834-05-1 |
|
Methyl vinyl ether/maleic acid copolymer, high molecular weight
| 25153-40-6 |
|
Tri-n-octylphosphine oxide, 99%
| 78-50-2 |
|
Theophylline, Anhydrous, 99+% (Titr., on Dry Substance)
| 58-55-9 |
|
DL-Atrolactic Acid Hemihydrate, 98%
| 515-30-0 |
|
2-Octanone, 99+% (GC)
| 111-13-7 |
|
Poly(Ethylene Glycol), Average M.W. 200
| 25322-68-3 |
|
|