**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 111-30-8 |Glutaric Dialdehyde | 50.0 | 203-856-5 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 50.0 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T N
Risk Phrases: 23/25 34 42/43 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation and if swallowed. Causes burns. May cause
sensitization by inhalation and skin contact. Very toxic to aquatic
organisms.Toxic.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury. Causes
severe burning pain and redness of the conjunctiva. May cause
permanent visual impairment.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Produces harmless yellow stains on the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns. Ingestion
may produce shock, collapse, and convulsions.
Inhalation:
Harmful if inhaled. Causes chemical burns to the respiratory tract.
May cause lung damage. In rare instances, exposure may cause
sensitization, resulting in inflammation of the mucous membranes and
in eczematous eruptions.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated or
prolonged exposure may cause allergic reactions in sensitive
individuals. Chronic exposure may cause effects similar to those of
acute exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Containers can build up pressure if exposed to heat and/or fire. As
in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases may
be generated by thermal decomposition or combustion. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas. Non-combustible, substance itself does not
burn but may decompose upon heating to produce irritating, corrosive
and/or toxic fumes.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam. Cool
containers with flooding quantities of water until well after fire is
out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Absorb spill using an absorbent, non-combustible
material such as earth, sand, or vermiculite. Do not use combustible
materials such as sawdust. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Do not ingest or inhale. Use only in a chemical fume
hood. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 111-30-8:
United Kingdom, WEL - TWA: 0.05 ppm TWA; 0.2 mg/m3 TWA
United Kingdom, WEL - STEL: 0.05 ppm STEL; 0.2 mg/m3 STEL
Belgium - TWA: 0.2 ppm VLE; 0.83 mg/m3 VLE
France - VME: 0.1 ppm VME; 0.4 mg/m3 VME
France - VLE: 0.2 ppm VLE; 0.8 mg/m3 VLE
Germany: 0.1 ppm TWA; 0.42 mg/m3 TWA
Malaysia: 0.05 ppm Ceiling; 0.21 mg/m3 Ceiling
Russia: 5 mg/m3 TWA
Spain: 0.05 ppm VLA-EC; 0.2 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: pungent odor
pH: 3.2-4.2
Vapor Pressure: 15 mm Hg @ 20 C
Viscosity: Not available.
Boiling Point: > 100 deg C
Freezing/Melting Point: -15 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 1.1310g/cm3
Molecular Formula: C5H8O2
Molecular Weight: 100.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Exposure to air, excess heat, temperatures above 50C (122F).
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, caustics (e.g. ammonia,
ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium
hydroxide), ammonia, amines, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-30-8: MA2450000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 111-30-8: Draize test, rabbit, eye: 1 mg Severe; Draize test,
rabbit, eye: 250 ug/24H Severe; Draize test, rabbit, skin: 2 mg/24H
Severe; Inhalation, rat: LC50 = 480 mg/m3/4H; Oral, mouse: LD50 = 100
mg/kg; Oral, mouse: LD50 = 231 mg/kg; Oral, rat: LD50 = 134 mg/kg;
Oral, rat: LD50 = 140 mg/kg; Skin, rabbit: LD50 = 560 uL/kg; Skin,
rat: LD50 = >2500 mg/kg.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Glutaric Dialdehyde -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 76.0 mg/L; 5 minutes;
Microtox testFish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.*
Hazard Class: 6.1,8
UN Number: 2927
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 6.1,8
UN Number: 2927
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 6.1,8
UN Number: 2927
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/25 Toxic by inhalation and if swallowed.
R 34 Causes burns.
R 42/43 May cause sensitization by inhalation and
skin contact.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 111-30-8: 2
CAS# 7732-18-5: No information available.
Canada
CAS# 111-30-8 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 111-30-8 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-30-8 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 23/25 Toxic by inhalation and if swallowed.
R 34 Causes burns.
R 42/43 May cause sensitization by inhalation and skin
contact.
R 50 Very toxic to aquatic organisms.
MSDS Creation Date: 6/07/1999 Revision #7 Date: 5/31/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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