**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 1310-73-2 |Sodium hydroxide | .04-0.4 | 215-185-5 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | >99.6 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Use water with caution
and in flooding amounts. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Contact
with metals may evolve flammable hydrogen gas. Containers may explode
when heated. Non-combustible, substance itself does not burn but may
decompose upon heating to produce irritating, corrosive and/or toxic
fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Do not ingest or
inhale. Discard contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from strong acids. Keep away from metals. Keep away from flammable
liquids. Keep away from organic halogens.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1310-73-2:
United Kingdom, WEL - STEL: 2 mg/m3 STEL
United States OSHA: 2 mg/m3 TWA
Belgium - TWA: 2 mg/m3 VLE
France - VME: 2 mg/m3 VME
Germany: 2 mg/m3 TWA (inhalable fraction)
Japan: 2 mg/m3 Ceiling
Malaysia: 2 mg/m3 Ceiling
Spain: 2 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: practically odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: > 100 deg C
Freezing/Melting Point: > 0 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: >1.0
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Prolonged exposure to air.
Incompatibilities with Other Materials:
Metals, acids.
Hazardous Decomposition Products:
Toxic fumes of sodium oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1310-73-2: WB4900000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 1310-73-2: Draize test, rabbit, eye: 400 ug Mild; Draize test,
rabbit, eye: 1% Severe; Draize test, rabbit, eye: 50 ug/24H Severe;
Draize test, rabbit, eye: 1 mg/24H Severe; Draize test, rabbit,
skin: 500 mg/24H Severe.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Sodium hydroxide -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Carp: 180ppm (LC100); 24H
Other
For more information, see "HANDBOOK OF ENVIRONMENTAL FATE AND
EXPOSURE DATA."
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class: 8
UN Number:
Packing group: II
USA RQ: CAS# 1310-73-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1310-73-2: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 1310-73-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 1310-73-2 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1310-73-2 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 35 Causes severe burns.
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
FMOC-L-Tryptophan, 99%
| 35737-15-6 |
|
5-Acetylamido-2-chloroaniline, 98%
| 51867-83-5 |
|
3'-Aminoacetanilide, 98%
| 102-28-3 |
|
Cellulose Acetate, Average M.W. 52000
| 9004-35-7 |
|
FMOC-L-Methionine, 98%
| 71989-28-1 |
|
Methyl iodide
| 74-88-4 |
|
Polyvinylpyrrolidone Average M.W. 360.000
| 9003-39-8 |
|
Phenolphthalin
| 81-90-3 |
|
1H-Indole-3-Acetic Acid,99+%
| 87-51-4 |
|
Boc-L-Aspartic Acid 4-Benzylester, 99+%
| 7536-58-5 |
|
Phenosafranin
| 81-93-6 |
|
Bromotriethylgermane
| 1067-10-3 |
|
4,5-Dimethyl-2-Nitroaniline, 97%
| 6972-71-0 |
|
3-Methacryloyloxypropyltris(Trimethylsilyloxy)Silane, 98%
| 17096-07-0 |
|
Ammonium nitrate, reagent ACS, crystals
| 6484-52-2 |
|
Boc-L-Tryptophane, 97%
| 13139-14-5 |
|
3,4,5,6-Tetrabromo-o-cresol, 98%
| 576-55-6 |
|
Sodium Hydroxide Solution 2-4%
| 1310-73-2 |
|
3-(4-Bromobenzoyl)Propionic Acid
| 6340-79-0 |
|
Copper(II) nitrate, trihydrate, p.a.
| 3251-23-8 |
|
Sodium Molybdate (VI) Dihydrate, 99+%
| 7631-95-0 |
|
Glutaric Dialdehyde, 25% Solution in Water E.M. Grade, Purified
| 111-30-8 |
|
Glutaric Dialdehyde (50% in water)
| 111-30-8 |
|
Sulfuric acid, 1N standard solution
| 7664-93-9 |
|
Ethyl Eosin
| 21514-87-4 |
|
Sodium Hydroxide Solution 0.4 - 0.04%
| 1310-73-2 |
|
BOC-L-Proline, 99+%
| 15761-39-4 |
|
5-Fluorouridine, 99+%
| 316-46-1 |
|
Boc-L-Glutamine, 99+%
| 13726-85-7 |
|
(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4- methanol, 98%
| 22323-82-6 |
|
Heptadecafluorononanoic Acid, 97%
| 375-95-1 |
|
2-(p-Chlorobenzyl)benzimidazole
| 5468-66-6 |
|
Lithium, Granular, Dry
| 7439-93-2 |
|
2-Amino-4,6-dimethylpyrimidine, 98%
| 767-15-7 |
|
trans-3-(3-Pyridyl)acrylic acid
| 19337-97-4 |
|
Pyronin B, certified
| 2150-48-3 |
|
Methyl 2-cyclopentanonecarboxylate
| 10472-24-9 |
|
8-Amino-2-naphthol, 98%
| 118-46-7 |
|
2,5-Dimethyl-1,5-hexadiene
| 627-58-7 |
|
Tetramethyltetraselenafulvalene
| 55259-49-9 |
|
Gallium(III) perchlorate, 50% solution in water
| 7732-18-5 |
|
1-Naphthyl phosphate calcium salt trihydrate
| 17805-69-5 |
|
4-Nitrobenzyl chloroformate, 97%
| 4457-32-3 |
|
(S)-3-Acetoxy-gamma-Butyrolactone, 95%
| 191403-65-3 |
|
4-Methoxyphenyl isocyanate, 99%
| 5416-93-3 |
|
N-Pivaloyl-o-toluidine
| 61495-04-3 |
|
N-Pivaloyl-o-Benzylaniline, 99%
| 85864-33-1 |
|
trans-4-Aminocyclohexanol, 97%
| 27489-62-9 |
|
D-(-)-Phenylglycinamide, 99%
| 0-01-1 |
|
2,6-Dichlorobenzylchloride, 97%
| 2014-83-7 |
|
|