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MSDS 
:
 1-Octanol
CAS 
:
 111-87-5
SYNONYMS 
:
 Capryl alcohol; n-Octanol; n-Octyl alcohol; n-Caprylic alcohol; Octyl     alcohol; Octan-1-ol.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-87-5 |1-Octanol | > 98 | 203-917-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/38

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Irritating to eyes and skin.

Potential Health Effects
Eye:
Causes eye irritation. May cause transient corneal injury.
Skin:
May cause mild skin irritation. May be absorbed through the skin.
Prolonged or repeated contact may dry/defat the skin and cause
irritation.
Ingestion:
May cause digestive tract disturbances.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustible liquid and vapor. Vapors are heavier
than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined
areas. This liquid floats on water and may travel to a source of
ignition and spread fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Use only with adequate ventilation. Keep
away from heat and flame. Avoid breathing vapor or mist.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 111-87-5:

Russia: 10 mg/m3 TWA

Personal Protective Equipment

Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: clear, colorless
Odor: penetrating odor - sweetish odor
pH: Not available.
Vapor Pressure: 0.08 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 195 deg C
Freezing/Melting Point: -16 deg C
Autoignition Temperature: 273 deg C ( 523.40 deg F)
Flash Point: 81 deg C ( 177.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 0.8240
Molecular Formula: C8H18O
Molecular Weight: 130.23

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 111-87-5: RH6550000
LD50/LC50:
CAS# 111-87-5: Dermal, guinea pig: LD50 = >1 gm/kg; Draize test,
rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 1790 mg/kg; Oral,
mouse: LD50 = 15000 mg/kg; Oral, rat: LD50 = >3200 mg/kg; Oral, rat:
LD50 = 20000 mg/kg.
Carcinogenicity:
1-Octanol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish: Fathead Minnow: LC50 = 13.5 mg/L; 96 Hr.; Flow-through
ConditionFish: Rainbow trout: LC50 = 18.0 mg/L; 96 Hr.;
UnspecifiedWater flea Daphnia: EC50 = 23.0 mg/L; 96 Hr.;
UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 3.7-7.3 mg/L;
30 minutes; Microtox test
Other
If spilled into U.S. waters, it may be reportable under 33 CFR Part
153 if it produces a sheen.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 111-87-5: 1
Canada
CAS# 111-87-5 is listed on Canada's DSL List.
CAS# 111-87-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-87-5 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 6/08/1999 Revision #6 Date: 1/04/2005

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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