**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 590-17-0 |BROMOACETONITRILE | 97% | 209-672-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. Toxic in contact with skin.
Ingestion:
Poison by ingestion. May cause headache. May cause nausea and
vomiting.
Inhalation:
Causes respiratory tract irritation. Inhalation may be fatal as a
result of spasm, inflammation, edema of the larynx and bronchi,
chemical pneumonitis and pulmonary edema. Toxic if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Do not breathe dust, vapor,
mist, or gas. Do not get in eyes, on skin, or on clothing. Use only
in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 590-17-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow to brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 150 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.7220g/cm3
Molecular Formula: C2H2BrN
Molecular Weight: 119.95
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong acids - strong bases - strong oxidizing agents - strong
reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 590-17-0: AL7970000
LD50/LC50:
Not available.
Carcinogenicity:
BROMOACETONITRILE -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: NITRILES, LIQUID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: II
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: II
RID/ADR
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 590-17-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 590-17-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 590-17-0 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl 2-Thiofuroate, 97%
| 13679-61-3 |
|
(+)-Chloromethyl menthyl ether, 95%, 97% e.e.
| 96662-07-6 |
|
2,5-Difluorobenzonitrile, 99%
| 64248-64-2 |
|
2-Methylbenzothiazole, 96% (gc)
| 120-75-2 |
|
4-Methylmorpholine N-oxide monohydrate, 97% (titr.)
| 7529-22-8 |
|
Sulfonazo iii,tetrasodium salt, p.a.
| 68504-35-8 |
|
3,4-Dimethylbenzoic Acid, 98%
| 619-04-5 |
|
5-Methyltryptamine hydrochloride, 98%
| 55795-89-6 |
|
2,5-Dimethylbenzyl alcohol, 98%
| 53957-33-8 |
|
1,3-Diphenylacetone, 99%
| 102-04-5 |
|
N-Phenyl-o-phenylenediamine, 97%
| 534-85-0 |
|
Phosphorous Acid, Crystalline
| 10294-56-1 |
|
N,N-Dimethylformamide dicyclohexyl acetal, 99%
| 2016-05-9 |
|
3-Bromo-4-methoxybenzaldehyde, 98%
| 34841-06-0 |
|
2-Amino-6-Methylbenzoic Acid, 98%
| 4389-50-8 |
|
2,2,5,5-Tetramethyl-4-Phenyl-3-Imidazoline -1-Oxyl, Free Radical
| 39753-69-0 |
|
2,7-Dimethoxynaphthalene, 98%
| 3469-26-9 |
|
Fast yellow GC salt
| 14263-92-4 |
|
2-Ethylbutyric acid, 99%
| 88-09-5 |
|
(s)-(-)-sec-Phenethyl alcohol, 99%
| 1445-91-6 |
|
DOUBLE-TIPPED NEEDLE, 18 GAUGE STAINLESS, STEEL, 2 FEET
| |
|
Chlorazol Black E, certfied
| 1937-37-7 |
|
4-Fluorophenylacetonitrile, 95%
| 459-22-3 |
|
1-Hexadecylpyridinium bromide
| 140-72-7 |
|
Bromoacetonitrile, 97%
| 590-17-0 |
|
Octane
| 111-65-9 |
|
4-Methylsulphonylaniline Hydrochloride , 95+%
| 5470-49-5 |
|
Dichloroacetic Acid, 99+%
| 79-43-6 |
|
1-Octanol
| 111-87-5 |
|
Cyclohexane-D12, 99.5 Atom % D
| 1735-17-7 |
|
4-Isopropoxybenzoic acid, 98%
| 13205-46-4 |
|
n-Undecylamine, 98%
| 7307-55-3 |
|
(1R,2S)-1-Amino-2-indanol, 98%, (99% e.e.)
| 136030-00-7 |
|
Copper(II)-Ethylenediamine Complex for Viscosity Determination of
| 14552-35-3 |
|
Tris-(Triphenylphosphine)-Rhodium(I)Chloride, 99.99%
| 14694-95-2 |
|
Tetrabutylammonium iodide, 98%
| 311-28-4 |
|
2,2-Dimethyl-3-Pentanol, 97%
| 3970-62-5 |
|
2-Aminophenol (pract), 97% (titr.)
| 95-55-6 |
|
Orcinol Monohydrate
| 6153-39-5 |
|
Olive oil
| 8001-25-0 |
|
Nickel (II) Bromide Hydrate, 98%
| 7789-49-3 |
|
1-(2,4-Dimethylphenyl)Piperazine
| 1013-76-9 |
|
Osmic Acid Anhydride
| 20816-12-0 |
|
Ethyl undecanoate, 97%
| 627-90-7 |
|
8-Hydroxy-1,1,7,7-tetramethyljulolidine-9- carboxaldehyde
| 115662-09-4 |
|
Ethyl isonicotinate, 99+%
| 1570-45-2 |
|
8-Hydroxy-5-Quinesulfonic Acid, Mono- Hydrate, 94% (UV-VIS)
| 84-88-8 |
|
Oxalic acid dihydrate
| 144-62-7 |
|
4-(1H)-Pyridone (Pract), 97% (UV-VIS)
| 108-96-3 |
|
Vanadyl(IV)-sulfate hydrate, 17-23% Vanadium
| 12439-96-2 |
|
|