**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7789-49-3 |Nickel(II) bromide hydrate | 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Causes "nickel itch" which is a dermatitis resulting from
sensitization to nickel, which is characterized by skin eruptions,
followed by discrete ulcers that may discharge and become crusted,
or by eczema.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May cause asthmatic attacks due
to allergic sensitization of the respiratory tract. Can produce
delayed pulmonary edema.
Chronic:
May cause cancer according to animal studies. Effects may be
delayed. Symptoms of overexposure to nickel can cause sensitization,
dermatitis, allergic asthma and pneumonitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7789-49-3:
United States OSHA: 1 mg/m3 TWA (as Ni) (listed under Nickel sol
compounds).
Belgium - TWA: (listed as nickel soluble compounds): 0.1 mg/m3 VL
(as Ni)
Malaysia: (listed as nickel soluble compounds): 0.1 mg/m3 TWA
(inhalable fraction, as Ni)
Netherlands: (listed as nickel soluble compounds): 0.1 mg/m3 MAC
Ni)
Spain: (listed as nickel soluble compounds): 0.1 mg/m3 VLA-ED (as
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder and chunks
Color: orange
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >200 deg C
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: Br2Ni.xH2O
Molecular Weight: 218.53
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7789-49-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nickel(II) bromide hydrate -
California: carcinogen, initial date 5/7/04 (listed as Nickel compound
NTP: Known carcinogen (listed as Nickel compounds).
IARC: Group 1 carcinogen (listed as Nickel compounds).
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, INORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 3288
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 7789-49-3: 3
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7789-49-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7789-49-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl 2-Thiofuroate, 97%
| 13679-61-3 |
|
(+)-Chloromethyl menthyl ether, 95%, 97% e.e.
| 96662-07-6 |
|
2,5-Difluorobenzonitrile, 99%
| 64248-64-2 |
|
2-Methylbenzothiazole, 96% (gc)
| 120-75-2 |
|
4-Methylmorpholine N-oxide monohydrate, 97% (titr.)
| 7529-22-8 |
|
Sulfonazo iii,tetrasodium salt, p.a.
| 68504-35-8 |
|
3,4-Dimethylbenzoic Acid, 98%
| 619-04-5 |
|
5-Methyltryptamine hydrochloride, 98%
| 55795-89-6 |
|
2,5-Dimethylbenzyl alcohol, 98%
| 53957-33-8 |
|
1,3-Diphenylacetone, 99%
| 102-04-5 |
|
N-Phenyl-o-phenylenediamine, 97%
| 534-85-0 |
|
Phosphorous Acid, Crystalline
| 10294-56-1 |
|
N,N-Dimethylformamide dicyclohexyl acetal, 99%
| 2016-05-9 |
|
3-Bromo-4-methoxybenzaldehyde, 98%
| 34841-06-0 |
|
2-Amino-6-Methylbenzoic Acid, 98%
| 4389-50-8 |
|
2,2,5,5-Tetramethyl-4-Phenyl-3-Imidazoline -1-Oxyl, Free Radical
| 39753-69-0 |
|
2,7-Dimethoxynaphthalene, 98%
| 3469-26-9 |
|
Fast yellow GC salt
| 14263-92-4 |
|
2-Ethylbutyric acid, 99%
| 88-09-5 |
|
(s)-(-)-sec-Phenethyl alcohol, 99%
| 1445-91-6 |
|
DOUBLE-TIPPED NEEDLE, 18 GAUGE STAINLESS, STEEL, 2 FEET
| |
|
Chlorazol Black E, certfied
| 1937-37-7 |
|
4-Fluorophenylacetonitrile, 95%
| 459-22-3 |
|
1-Hexadecylpyridinium bromide
| 140-72-7 |
|
Bromoacetonitrile, 97%
| 590-17-0 |
|
Octane
| 111-65-9 |
|
4-Methylsulphonylaniline Hydrochloride , 95+%
| 5470-49-5 |
|
Dichloroacetic Acid, 99+%
| 79-43-6 |
|
1-Octanol
| 111-87-5 |
|
Cyclohexane-D12, 99.5 Atom % D
| 1735-17-7 |
|
4-Isopropoxybenzoic acid, 98%
| 13205-46-4 |
|
n-Undecylamine, 98%
| 7307-55-3 |
|
(1R,2S)-1-Amino-2-indanol, 98%, (99% e.e.)
| 136030-00-7 |
|
Copper(II)-Ethylenediamine Complex for Viscosity Determination of
| 14552-35-3 |
|
Tris-(Triphenylphosphine)-Rhodium(I)Chloride, 99.99%
| 14694-95-2 |
|
Tetrabutylammonium iodide, 98%
| 311-28-4 |
|
2,2-Dimethyl-3-Pentanol, 97%
| 3970-62-5 |
|
2-Aminophenol (pract), 97% (titr.)
| 95-55-6 |
|
Orcinol Monohydrate
| 6153-39-5 |
|
Olive oil
| 8001-25-0 |
|
Nickel (II) Bromide Hydrate, 98%
| 7789-49-3 |
|
1-(2,4-Dimethylphenyl)Piperazine
| 1013-76-9 |
|
Osmic Acid Anhydride
| 20816-12-0 |
|
Ethyl undecanoate, 97%
| 627-90-7 |
|
8-Hydroxy-1,1,7,7-tetramethyljulolidine-9- carboxaldehyde
| 115662-09-4 |
|
Ethyl isonicotinate, 99+%
| 1570-45-2 |
|
8-Hydroxy-5-Quinesulfonic Acid, Mono- Hydrate, 94% (UV-VIS)
| 84-88-8 |
|
Oxalic acid dihydrate
| 144-62-7 |
|
4-(1H)-Pyridone (Pract), 97% (UV-VIS)
| 108-96-3 |
|
Vanadyl(IV)-sulfate hydrate, 17-23% Vanadium
| 12439-96-2 |
|
|