**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 459-22-3 |Benzeneacetonitrile, 4-fluoro- | 95 | 207-286-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Metabolism may release cyanide, which may result in headache,
dizziness, weakness, collapse, unconsciousness and possible death.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. May be
metabolized to cyanide which in turns act by inhibiting cytochrome
oxidase impairing cellular respiration.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 459-22-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 119.0 - 120.0 deg C @ 18.00mm
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 108 deg C ( 226.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.1260g/cm3
Molecular Formula: C8H6FN
Molecular Weight: 135.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 459-22-3: AM0210000
LD50/LC50:
Not available.
Carcinogenicity:
Benzeneacetonitrile, 4-fluoro- -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 459-22-3: No information available.
Canada
CAS# 459-22-3 is listed on Canada's NDSL List.
CAS# 459-22-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 459-22-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl 2-Thiofuroate, 97%
| 13679-61-3 |
|
(+)-Chloromethyl menthyl ether, 95%, 97% e.e.
| 96662-07-6 |
|
2,5-Difluorobenzonitrile, 99%
| 64248-64-2 |
|
2-Methylbenzothiazole, 96% (gc)
| 120-75-2 |
|
4-Methylmorpholine N-oxide monohydrate, 97% (titr.)
| 7529-22-8 |
|
Sulfonazo iii,tetrasodium salt, p.a.
| 68504-35-8 |
|
3,4-Dimethylbenzoic Acid, 98%
| 619-04-5 |
|
5-Methyltryptamine hydrochloride, 98%
| 55795-89-6 |
|
2,5-Dimethylbenzyl alcohol, 98%
| 53957-33-8 |
|
1,3-Diphenylacetone, 99%
| 102-04-5 |
|
N-Phenyl-o-phenylenediamine, 97%
| 534-85-0 |
|
Phosphorous Acid, Crystalline
| 10294-56-1 |
|
N,N-Dimethylformamide dicyclohexyl acetal, 99%
| 2016-05-9 |
|
3-Bromo-4-methoxybenzaldehyde, 98%
| 34841-06-0 |
|
2-Amino-6-Methylbenzoic Acid, 98%
| 4389-50-8 |
|
2,2,5,5-Tetramethyl-4-Phenyl-3-Imidazoline -1-Oxyl, Free Radical
| 39753-69-0 |
|
2,7-Dimethoxynaphthalene, 98%
| 3469-26-9 |
|
Fast yellow GC salt
| 14263-92-4 |
|
2-Ethylbutyric acid, 99%
| 88-09-5 |
|
(s)-(-)-sec-Phenethyl alcohol, 99%
| 1445-91-6 |
|
DOUBLE-TIPPED NEEDLE, 18 GAUGE STAINLESS, STEEL, 2 FEET
| |
|
Chlorazol Black E, certfied
| 1937-37-7 |
|
4-Fluorophenylacetonitrile, 95%
| 459-22-3 |
|
1-Hexadecylpyridinium bromide
| 140-72-7 |
|
Bromoacetonitrile, 97%
| 590-17-0 |
|
Octane
| 111-65-9 |
|
4-Methylsulphonylaniline Hydrochloride , 95+%
| 5470-49-5 |
|
Dichloroacetic Acid, 99+%
| 79-43-6 |
|
1-Octanol
| 111-87-5 |
|
Cyclohexane-D12, 99.5 Atom % D
| 1735-17-7 |
|
4-Isopropoxybenzoic acid, 98%
| 13205-46-4 |
|
n-Undecylamine, 98%
| 7307-55-3 |
|
(1R,2S)-1-Amino-2-indanol, 98%, (99% e.e.)
| 136030-00-7 |
|
Copper(II)-Ethylenediamine Complex for Viscosity Determination of
| 14552-35-3 |
|
Tris-(Triphenylphosphine)-Rhodium(I)Chloride, 99.99%
| 14694-95-2 |
|
Tetrabutylammonium iodide, 98%
| 311-28-4 |
|
2,2-Dimethyl-3-Pentanol, 97%
| 3970-62-5 |
|
2-Aminophenol (pract), 97% (titr.)
| 95-55-6 |
|
Orcinol Monohydrate
| 6153-39-5 |
|
Olive oil
| 8001-25-0 |
|
Nickel (II) Bromide Hydrate, 98%
| 7789-49-3 |
|
1-(2,4-Dimethylphenyl)Piperazine
| 1013-76-9 |
|
Osmic Acid Anhydride
| 20816-12-0 |
|
Ethyl undecanoate, 97%
| 627-90-7 |
|
8-Hydroxy-1,1,7,7-tetramethyljulolidine-9- carboxaldehyde
| 115662-09-4 |
|
Ethyl isonicotinate, 99+%
| 1570-45-2 |
|
8-Hydroxy-5-Quinesulfonic Acid, Mono- Hydrate, 94% (UV-VIS)
| 84-88-8 |
|
Oxalic acid dihydrate
| 144-62-7 |
|
4-(1H)-Pyridone (Pract), 97% (UV-VIS)
| 108-96-3 |
|
Vanadyl(IV)-sulfate hydrate, 17-23% Vanadium
| 12439-96-2 |
|
|