**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1118-84-9 |Allylacetoacetate | 98 | 214-269-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and respiratory system.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. Can produce delayed pulmonary edema. Inhalation at
high concentrations may cause CNS depression and asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Use
with adequate ventilation. Wash clothing before reuse. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1118-84-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear very slight yellow
Odor: acetic odor
pH: Not available.
Vapor Pressure: 0.2 mbar @ 20 C
Viscosity: 1.62 mPas 20 deg C
Boiling Point: 194 - 195 deg C @ 737.00mm Hg
Freezing/Melting Point: -70 deg C
Autoignition Temperature: 300 deg C ( 572.00 deg F)
Flash Point: 75 deg C ( 167.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 50.5 g/l (20 c)
Specific Gravity/Density: 1.0370g/cm3
Molecular Formula: C7H10O3
Molecular Weight: 142.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1118-84-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Allylacetoacetate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37 Irritating to eyes and respiratory system.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 27 Take off immediately all contaminated clothing.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
WGK (Water Danger/Protection)
CAS# 1118-84-9: 2
Canada
CAS# 1118-84-9 is listed on Canada's DSL List.
CAS# 1118-84-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1118-84-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Mercury (II) Bromide
| 7789-47-1 |
|
2,3-Naphthalenedicarbonitrile, 98%
| 22856-30-0 |
|
6-Nitro-2-phenyl-4-quinolinol
| 56983-10-9 |
|
Mercury(II) chloride
| 7487-94-7 |
|
Mercury (II) Iodide
| 7774-29-0 |
|
Di-p-toluenesulfimide potassium salt
| 97888-41-0 |
|
Mercury(II) nitrate monohydrate
| 7783-34-8 |
|
2-Amino-6,7-Dimethyl-4-Hydroxy-5,6,7,8-Tetrahydropteridine
| 945-43-7 |
|
D-Maltose
| 69-79-4 |
|
Mercury (II) Oxide
| 21908-53-2 |
|
2,4-Difluorotoluene, 98%
| 452-76-6 |
|
2-(3-Thienyl)ethanol, 99%
| 13781-67-4 |
|
1,4-Diaminocyclohexane
| 2615-25-0 |
|
Mercury (II) Sulfate
| 7783-35-9 |
|
Diethylstilbestrol, 99%
| 56-53-1 |
|
Sodium Biphenyl, Reagent, 20 % w/w Solution in Diethylene Glycol
| 112-36-7 |
|
3-Fluorobenzylamine, 97%
| 100-82-3 |
|
Furan, stabilized with 0.025-0.04% BHT
| 110-00-9 |
|
trans-2-Dodecenal, 90-96% (gc)
| 4826-62-4 |
|
2-Chloro-2-methylbutane, 95% (gc)
| 594-36-5 |
|
2-Oxazolidone, 98%
| 497-25-6 |
|
Boron Trifluoride (12% in methanol)
| 67-56-1 |
|
Decyl Aldehyde, 95%
| 112-31-2 |
|
2-Aminobenzotrifluoride, 99% (GC)
| 88-17-5 |
|
N-Vinylpyrrolidone/Styrene Copolymer, 40 wt% Aqueous Emulsion
| 25086-29-7 |
|
1,1'-Bis(chloromercuri)ferrocene, tech.
| 12145-90-3 |
|
Triallyl-s-triazine-2,4,6(1H,3H,5H)-trione 99%, stabilized with 100
| 128-37-0 |
|
Cyclopropyl 2-thienyl ketone
| 6193-47-1 |
|
Mercury
| 7439-97-6 |
|
Decafluorobiphenyl, 98+%
| 434-90-2 |
|
n-Octyl-monooxyethylene
| 10020-43-6 |
|
N-Tert.-Butyl-Alpha-Phenylnitrone,98%
| 3376-24-7 |
|
4-Dimethylaminocinnamonitrile (Mixture of Cis and Trans)
| 32444-63-6 |
|
2-Pyrazinecarboxylic acid, 99%
| 98-97-5 |
|
5-Benzyloxyindole, CHR
| 1215-59-4 |
|
4-Bromobutyric acid, 98%
| 2623-87-2 |
|
Mercury thiocyanatocobaltate(ii), 99%
| 27685-51-4 |
|
Pbd, Scintillation Grade
| 852-38-0 |
|
4-Ethenyl-1,3-Dioxolan-2-One
| 4427-96-7 |
|
2,2,6-Trimethylcyclohexanone, 98.5+% (GC)
| 2408-37-9 |
|
DL-4-Chlorophenylalanine ethyl ester hydrochloride
| 52031-05-7 |
|
p-Methoxyphenylacetone, 98+%
| 122-84-9 |
|
1-Hexen-3-ol, 98%
| 4798-44-1 |
|
4-Fluorothiophenol, 97%
| 371-42-6 |
|
3',5'-Diacetylthymidine, 99+%
| 6979-97-1 |
|
Oxanilide, 99% (UV-Vis)
| 620-81-5 |
|
4-Methoxysalicylic acid, 99%
| 2237-36-7 |
|
Ethyl 3-mercaptopropionate, 99%
| 5466-06-8 |
|
Methyl acetate
| 79-20-9 |
|
Allylacetoacetate, 98%
| 1118-84-9 |
|
|