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MSDS 
:
 Mercury
CAS 
:
 7439-97-6
SYNONYMS 
:
 Colloidal mercury; Hydrargyrum; Metallic mercury; Quick silver;     Liquid silver.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7439-97-6 |Mercury | 100 | 231-106-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23 33 50/53

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Toxic by inhalation. Danger of cumulative effects. Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.Corrosive.

Potential Health Effects
Eye:
Exposure to mercury or mercury compounds can cause discoloration on
the front surface of the lens, which does not interfere with vision.
Causes eye irritation and possible burns. Contact with mercury or
mercury compounds can cause ulceration of the conjunctiva and
cornea.
Skin:
May be absorbed through the skin in harmful amounts. May cause skin
sensitization, an allergic reaction, which becomes evident upon
re-exposure to this material. Causes skin irritation and possible
burns. May cause skin rash (in milder cases), and cold and clammy
skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. May
cause perforation of the digestive tract. May cause effects similar
to those for inhalation exposure. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation of fumes
may cause metal fume fever, which is characterized by flu-like
symptoms with metallic taste, fever, chills, cough, weakness, chest
pain, muscle pain and increased white blood cell count. May cause
central nervous system effects including vertigo, anxiety,
depression, muscle incoordination, and emotional instability.
Aspiration may lead to pulmonary edema. May cause systemic effects.
May cause respiratory sensitization.
Chronic:
May cause liver and kidney damage. May cause reproductive and fetal
effects. Effects may be delayed. Chronic exposure to mercury may
cause permanent central nervous system damage, fatigue, weight loss,
tremors, personality changes. Chronic ingestion may cause
accumulation of mercury in body tissues. Prolonged or repeated
exposure may cause inflammation of the mouth and gums, excessive
salivation, and loosening of the teeth.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Wash mouth out with
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
The concentration of mercury in whole blood is a reasonable measure
of the body-burden of mercury and thus is used for monitoring
purposes. Treat symptomatically and supportively. Persons with
kidney disease, chronic respiratory disease, liver disease, or skin
disease may be at increased risk from exposure to this substance.
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel. The use of Dimercaprol or BAL
(British Anti-Lewisite) as a chelating agent should be determined by
qualified medical personnel.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion.
Extinguishing Media:
Substance is nonflammable; use agent most appropriate to extinguish
surrounding fire. Use water spray, dry chemical, carbon dioxide, or
appropriate foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Keep
container tightly closed. Do not get on skin or in eyes. Do not
ingest or inhale. Use only in a chemical fume hood. Discard
contaminated shoes. Do not breathe vapor.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep away from metals. Store protected from
azides.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 7439-97-6:
United States OSHA: ; 0.1 mg/m3 Ceiling (vapor)
Belgium - TWA: (listed as mercury, aryl and inorganic compounds):
mg/m3 VLE (as Hg)
France - VME: 0.05 mg/m3 VME (vapor)
Germany: 0.1 mg/m3 TWA
Japan: 0.025 mg/m3 OEL (vapor)
Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1
mg/m3 TWA (as Hg)
Netherlands: 0.5 mg/m3 STEL
Netherlands: 0.05 mg/m3 MAC
Russia: 0.01 mg/m3 TWA
Russia: 0.005 mg/m3 STEL
Spain: 0.025 mg/m3 VLA-ED

Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: silver
Odor: odorless
pH: Not available.
Vapor Pressure: 0.002 mm Hg @ 25C
Viscosity: 15.5 mP @ 25 deg C
Boiling Point: 356.72 deg C
Freezing/Melting Point: -38.87 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 13.59 (water=1)
Molecular Formula: Hg
Molecular Weight: 200.59

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials.
Incompatibilities with Other Materials:
Oxygen, sulfur, acetylene, ammonia, chlorine dioxide, azides,
chlorates, nitrates, sulfuric acid, halogens, rubidium, calcium,
3-bromopropyne, ethylene oxide, lithium, methylsilane + oxygen,
peroxyformic acid, tetracarbonylnickel + oxygen, copper, copper
alloys, boron diiodophosphide, metals, nitromethane, sodium carbide,
aluminum, lead, iron, metal oxides.
Hazardous Decomposition Products:
Mercury/mercury oxides.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 7439-97-6: OV4550000
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Mercury -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.16-0.90 mg/L; 96 Hr; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 0.16-0.90 mg/L; 96 Hr; UnspecifiedFish:
Channel catfish: LC50 = 0.35 mg/L; 96 Hr; UnspecifiedWater flea
Daphnia: EC50 = 0.01 mg/L; 48 Hr; UnspecifiedIn aquatic systems,
mercury appears to bind to dissolved matter
or fine particulates,
while the transport of mercury bound to dust particles in the
atmosphere or bed sediment particles in rivers and lakes is
generally less substantial. The conversion, in aquatic environments,
of inorganic mercury cmpd to methyl mercury implies that recycling of
mercury from sediment to water to air and back could be a rapid
Other
Harmful to aquatic life in very low concentrations.

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: MERCURY
Hazard Class: 8
UN Number: 2809
Packing Group: III
IMO
Shipping Name: MERCURY
Hazard Class: 8
UN Number: 2809
Packing Group: III
RID/ADR
Shipping Name: MERCURY
Hazard Class: 8
UN Number: 2809
Packing group: III
USA RQ: CAS# 7439-97-6: 1 lb final RQ; 0.454 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23 Toxic by inhalation.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 1/2 Keep locked up and out of reach of children.
S 7 Keep container tightly closed.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7439-97-6: 3
Canada
CAS# 7439-97-6 is listed on Canada's DSL List.
CAS# 7439-97-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7439-97-6 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 6/15/1999 Revision #7 Date: 1/20/2005

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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2-(3-Thienyl)ethanol, 99% 13781-67-4
1,4-Diaminocyclohexane 2615-25-0
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trans-2-Dodecenal, 90-96% (gc) 4826-62-4
2-Chloro-2-methylbutane, 95% (gc) 594-36-5
2-Oxazolidone, 98% 497-25-6
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Decyl Aldehyde, 95% 112-31-2
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DL-4-Chlorophenylalanine ethyl ester hydrochloride 52031-05-7
p-Methoxyphenylacetone, 98+% 122-84-9
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3',5'-Diacetylthymidine, 99+% 6979-97-1
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4-Methoxysalicylic acid, 99% 2237-36-7
Ethyl 3-mercaptopropionate, 99% 5466-06-8
Methyl acetate 79-20-9
Allylacetoacetate, 98% 1118-84-9

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