**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 112-67-4 |Hexadecanoyl chloride | 40 | 203-996-7 |
|----------------|--------------------------------------|----------|-----------|
| 112-76-5 |Octadecanoyl chloride | 60 | 204-004-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Causes chemical burns to the respiratory tract. May
cause abdominal pain, nausea, vomiting, and inflammation of the gums
and mouth.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Do NOT use water directly on fire. Use carbon dioxide or dry
chemical.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid contact with eyes, skin, and clothing. Do not breathe dust,
vapor, mist, or gas. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep under a nitrogen blanket. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
Exposure Limits
CAS# 112-67-4:
CAS# 112-76-5:
Personal Protective Equipment
Eyes:
Wear chemical goggles and a face shield if splashing
is possible.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: amber
Odor: Not available.
pH: Not available.
Vapor Pressure: .1 mbar @ 100 deg C
Viscosity: Not available.
Boiling Point: 202 deg C @ 6.00mm Hg
Freezing/Melting Point: 18 - 22 deg C
Autoignition Temperature: 230 deg C ( 446.00 deg F)
Flash Point: 165 deg C ( 329.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 120 deg C
Solubility in water: may decompose
Specific Gravity/Density: .9000g/cm3
Molecular Formula: C18H35ClO
Molecular Weight: 302.92
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Water, alcohols, oxidizing agents, strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 112-67-4 unlisted.
CAS# 112-76-5: RG2162000
LD50/LC50:
Not available.
CAS# 112-76-5: Oral, rat: LD50 = 7500 mg/kg.
Carcinogenicity:
Hexadecanoyl chloride -
Not listed by ACGIH, IARC, or NTP.
Octadecanoyl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 112-67-4: 1
CAS# 112-76-5: 1
Canada
CAS# 112-67-4 is listed on Canada's NDSL List.
CAS# 112-76-5 is listed on Canada's DSL List.
CAS# 112-67-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 112-76-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 112-67-4 is listed on the TSCA inventory.
CAS# 112-76-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Bromoethylamine Hydrobromide, 98+ %
| 2576-47-8 |
|
5-Methyl-S-Triazolo(1,5-a)Pyrimidin-7-Ol 98%
| 2503-56-2 |
|
2-Amino-1-Propene-1,1,3-Tricarbonitrile, 97%
| 868-54-2 |
|
6-Ethoxy-1,2,3,4-Tetrahydro-2,2,4-Tri-Methylquinoline, 97%
| 16489-90-0 |
|
Tetramethylpyrazine, 98%
| 1124-11-4 |
|
Methyl 4-(chloroformyl)-butyrate 98 %
| 1501-26-4 |
|
o-Nitrophenyl-beta-D-thiogalactopyranoside
| 1158-17-4 |
|
Dichloromethylsilane, 97%
| 75-54-7 |
|
Quinidine anhydrous, ca.95%, remainder dihydroquinidine
| 56-54-2 |
|
Coumarin 152, Laser Grade
| 53518-14-2 |
|
o-Nitrophenol (pract), 95% (uv-vis)
| 88-75-5 |
|
5-Nitroso-8-quinolinol
| 3565-26-2 |
|
2,4,6-Tri-Tert-Butylnitrosobenzene, 99%
| 24973-59-9 |
|
Calix(5)arene
| |
|
Triphenylcarbenium tetrafluoroborate
| 341-02-6 |
|
3-Exo-Aminobicyclo??2.2.1??Heptane-2-Exo-Carboxylic Acid, 98%
| 88330-32-9 |
|
6-Nitroquinoline, 98%
| 613-50-3 |
|
2,2-Dichloropentanal, 92%
| 41718-50-7 |
|
1-Ethoxynaphthalene, 97%
| 5328-01-8 |
|
2,5-Difluoronitrobenzene, 99%
| 364-74-9 |
|
1,4-Cyclohexanedimethanol 99%, (Mixture of Cis and Trans)
| 105-08-8 |
|
(S,S)-(-)-1,2-Diphenyl-1,2-Ethanediol, 98+%
| 2325-10-2 |
|
3-Bromotoluene, 99%
| 591-17-3 |
|
3-Carboxypropyl disulfide, 97%
| 2906-60-7 |
|
Orange (II) (Cert)
| 633-96-5 |
|
Glycylglycylglycylglycine, 97%
| 637-84-3 |
|
1,5-Hexadien-3-Ol, 95%
| 924-41-4 |
|
Lactic acid lithium salt, 99% (titr.)
| 867-55-0 |
|
Stearoyl chloride, tech.
| 112-67-4 |
|
Pentyl Ether, 99% (GC)
| 693-65-2 |
|
10-Methyl-9(10H)-acridone, 98%
| 719-54-0 |
|
4-Methyl-1-pentanol, 99%
| 626-89-1 |
|
2,3-Dimethyl-2-Butene, 98%
| 563-79-1 |
|
Ethyl 4-Hydroxybenzoate, 99%
| 120-47-8 |
|
2-Cyclohexen-1-One, 97%
| 930-68-7 |
|
2-Methylhippuric acid, 98%
| 42013-20-7 |
|
4-(Trifluoromethoxy)aniline, 99+% (titr.)
| 461-82-5 |
|
(1S,2S)-(-)-1,2-Diphenyl-1,2-Ethanediamine, 99% (99% e.e.)
| 35132-20-8 |
|
D-(-)-Arabinose, P.A.
| 28697-53-2 |
|
Hoechst 33342
| 23491-52-3 |
|
Sucrose Octaacetate, 98.0-100.5% (on Dry Substance)
| 126-14-7 |
|
1-(2-Pyridyl)piperazine, 98%
| 34803-66-2 |
|
(1R)-(+)-Isomenthol, 99%
| 23283-97-8 |
|
1,2,4,5-Tetrachlorobenzene, 98%
| 95-94-3 |
|
R-(-)1,1'-Binaphthyl-2,2'-Diyl Hydrogen Phosphate, 99%
| 39648-67-4 |
|
(+)-(2-Methylbutyl)benzene, 99% (GC)
| 40560-30-3 |
|
3,4,5-Trimethoxybenzyl alcohol, 97%
| 3840-31-1 |
|
4-Tert.-amylcyclohexanol, 99+%, mixture of cis and trans
| 5349-51-9 |
|
4-(4-Chlorophenylmethyl)-6,7-dimethoxy- isoquinoline methanesulfonate
| 61189-88-6 |
|
Drierite, 4 mesh, without indicator
| 7778-18-9 |
|
|