**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 364-74-9 |2,5-Difluoronitrobenzene | 99 | 206-663-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustible liquid.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Keep away from heat,
sparks and flame. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 364-74-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: yellow-green
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 207 deg C @ 760.00mmHg
Freezing/Melting Point: -11.7 deg C
Autoignition Temperature: Not available.
Flash Point: 90 deg C ( 194.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.4670g/cm3
Molecular Formula: C6H3F2NO2
Molecular Weight: 159.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat, electrical sparks.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 364-74-9: CZ5715000
LD50/LC50:
Not available.
Carcinogenicity:
2,5-Difluoronitrobenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 364-74-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 364-74-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 364-74-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/17/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2-Bromoethylamine Hydrobromide, 98+ %
| 2576-47-8 |
|
5-Methyl-S-Triazolo(1,5-a)Pyrimidin-7-Ol 98%
| 2503-56-2 |
|
2-Amino-1-Propene-1,1,3-Tricarbonitrile, 97%
| 868-54-2 |
|
6-Ethoxy-1,2,3,4-Tetrahydro-2,2,4-Tri-Methylquinoline, 97%
| 16489-90-0 |
|
Tetramethylpyrazine, 98%
| 1124-11-4 |
|
Methyl 4-(chloroformyl)-butyrate 98 %
| 1501-26-4 |
|
o-Nitrophenyl-beta-D-thiogalactopyranoside
| 1158-17-4 |
|
Dichloromethylsilane, 97%
| 75-54-7 |
|
Quinidine anhydrous, ca.95%, remainder dihydroquinidine
| 56-54-2 |
|
Coumarin 152, Laser Grade
| 53518-14-2 |
|
o-Nitrophenol (pract), 95% (uv-vis)
| 88-75-5 |
|
5-Nitroso-8-quinolinol
| 3565-26-2 |
|
2,4,6-Tri-Tert-Butylnitrosobenzene, 99%
| 24973-59-9 |
|
Calix(5)arene
| |
|
Triphenylcarbenium tetrafluoroborate
| 341-02-6 |
|
3-Exo-Aminobicyclo??2.2.1??Heptane-2-Exo-Carboxylic Acid, 98%
| 88330-32-9 |
|
6-Nitroquinoline, 98%
| 613-50-3 |
|
2,2-Dichloropentanal, 92%
| 41718-50-7 |
|
1-Ethoxynaphthalene, 97%
| 5328-01-8 |
|
2,5-Difluoronitrobenzene, 99%
| 364-74-9 |
|
1,4-Cyclohexanedimethanol 99%, (Mixture of Cis and Trans)
| 105-08-8 |
|
(S,S)-(-)-1,2-Diphenyl-1,2-Ethanediol, 98+%
| 2325-10-2 |
|
3-Bromotoluene, 99%
| 591-17-3 |
|
3-Carboxypropyl disulfide, 97%
| 2906-60-7 |
|
Orange (II) (Cert)
| 633-96-5 |
|
Glycylglycylglycylglycine, 97%
| 637-84-3 |
|
1,5-Hexadien-3-Ol, 95%
| 924-41-4 |
|
Lactic acid lithium salt, 99% (titr.)
| 867-55-0 |
|
Stearoyl chloride, tech.
| 112-67-4 |
|
Pentyl Ether, 99% (GC)
| 693-65-2 |
|
10-Methyl-9(10H)-acridone, 98%
| 719-54-0 |
|
4-Methyl-1-pentanol, 99%
| 626-89-1 |
|
2,3-Dimethyl-2-Butene, 98%
| 563-79-1 |
|
Ethyl 4-Hydroxybenzoate, 99%
| 120-47-8 |
|
2-Cyclohexen-1-One, 97%
| 930-68-7 |
|
2-Methylhippuric acid, 98%
| 42013-20-7 |
|
4-(Trifluoromethoxy)aniline, 99+% (titr.)
| 461-82-5 |
|
(1S,2S)-(-)-1,2-Diphenyl-1,2-Ethanediamine, 99% (99% e.e.)
| 35132-20-8 |
|
D-(-)-Arabinose, P.A.
| 28697-53-2 |
|
Hoechst 33342
| 23491-52-3 |
|
Sucrose Octaacetate, 98.0-100.5% (on Dry Substance)
| 126-14-7 |
|
1-(2-Pyridyl)piperazine, 98%
| 34803-66-2 |
|
(1R)-(+)-Isomenthol, 99%
| 23283-97-8 |
|
1,2,4,5-Tetrachlorobenzene, 98%
| 95-94-3 |
|
R-(-)1,1'-Binaphthyl-2,2'-Diyl Hydrogen Phosphate, 99%
| 39648-67-4 |
|
(+)-(2-Methylbutyl)benzene, 99% (GC)
| 40560-30-3 |
|
3,4,5-Trimethoxybenzyl alcohol, 97%
| 3840-31-1 |
|
4-Tert.-amylcyclohexanol, 99+%, mixture of cis and trans
| 5349-51-9 |
|
4-(4-Chlorophenylmethyl)-6,7-dimethoxy- isoquinoline methanesulfonate
| 61189-88-6 |
|
Drierite, 4 mesh, without indicator
| 7778-18-9 |
|
|