**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1126-78-9 |N-Butylaniline | 99% | 214-425-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. May cause liver and
kidney damage. May cause cardiac disturbances. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death. May be
harmful if swallowed. May cause central nervous system depression.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death. May cause liver and kidney damage. Exposure produces
central nervous system depression. May cause cardiac abnormalities.
Chronic:
May cause liver and kidney damage. May cause methemoglobinemia,
which is characterized by chocolate-brown colored blood, headache,
weakness, dizziness, breath shortness, cyanosis (bluish skin due to
deficient oxygenation of blood), rapid heart rate, unconsciousness
and possible death.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Immediately flush
eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas. Containers may explode when heated. Runoff
from fire control or dilution water may cause pollution.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 1126-78-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 241 deg C @ 760.00mmHg
Freezing/Melting Point: 12 deg C
Autoignition Temperature: Not applicable.
Flash Point: 107 deg C ( 224.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: .9310g/cm3
Molecular Formula: C10H15N
Molecular Weight: 149.23
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1126-78-9: BW9450000
LD50/LC50:
CAS# 1126-78-9: Oral, rat: LD50 = 1620 mg/kg; Skin, rabbit: LD50 =
5990 uL/kg.
Carcinogenicity:
N-Butylaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: N-BUTYLANILINE
Hazard Class: 6.1
UN Number: 2738
Packing Group: II
IMO
Shipping Name: N-normal-BUTYLANILINE
Hazard Class: 6.1
UN Number: 2738
Packing Group: II
RID/ADR
Shipping Name: N-BUTYLANILINE
Hazard Class: 6.1
UN Number: 2738
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1126-78-9: No information available.
Canada
CAS# 1126-78-9 is listed on Canada's NDSL List.
CAS# 1126-78-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1126-78-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Dimethylaminoantipyrine, 97%
| 58-15-1 |
|
(R)-(-)-1-Phenyl-1,2-Ethanediol, 99+%
| 16355-00-3 |
|
Triethylphenylammonium Hydroxide (10% in Water)
| 7620-71-5 |
|
4-Aminophenol Hydrochloride, 98% (UV-Vis)
| 51-78-5 |
|
N-Butylaniline,99%
| 1126-78-9 |
|
4-Chlorobutyryl chloride, 98%
| 4635-59-0 |
|
2-Ethyl-2-Hydroxybutyric Acid, 99%
| 3639-21-2 |
|
Methyl phenyl disulfide, 97+%
| 14173-25-2 |
|
1-Nitropyrene, 99%
| 5522-43-0 |
|
1-Hexadecanesulfonyl chloride, 98%
| 38775-38-1 |
|
M-Phenylene Dibenzoate
| 94-01-9 |
|
5-Methyl-1H-benzotriazole(1,2,3), 98%
| 136-85-6 |
|
1,4-Cyclohexanediol (Pract)
| 556-48-9 |
|
3-Nitrobenzamidine hydrochloride, 97%
| 56406-50-9 |
|
Tris-(3-(Heptafluoropropylhydroxymethylene )-D-Camphorato), Eu (III)
| 34788-82-4 |
|
2,3-Diphenylquinoxaline, 99+% (titr.)
| 1684-14-6 |
|
2-Isopropyl-3-Methoxypyrazine, 97%
| 25773-40-4 |
|
Cadmium fluoride, 99.99+%
| 7790-79-6 |
|
2,2,4-Trichlorobutanal, 97%
| 0-01-1 |
|
2-Fluorenecarboxaldehyde, 99%
| 30084-90-3 |
|
Calcein blue, indicator grade
| 54375-47-2 |
|
Tetraester 4-Tert-Butylcalix(4)Arene, 95% (TLC)
| 0-01-1 |
|
4-Fluorobenzotrifluoride, 97%
| 402-44-8 |
|
1-Oxo-Octyl-Beta-D-Glucoside, 99+%
| 0-01-1 |
|
Arecoline Hydrobromide, 99+%
| 300-08-3 |
|
Dl-2-amino-3-methyl-1-butanol, 95% (gc)
| 16369-05-4 |
|
4-Fluorobenzenesulfonyl Chloride, 98%
| 349-88-2 |
|
Telluroxanthone, 99+%
| 72294-67-8 |
|
Triethanolamine borate, 95+% (ex nitrogen)
| 15277-97-1 |
|
Acetyl-Beta-Methylcholine Bromide, 99%
| 333-31-3 |
|
2,4-Dimethylimidazole, Tech.,90%
| 930-62-1 |
|
Dl-3-methylcyclopentanone, 99%
| 1757-42-2 |
|
Cadmium atomic absorption standard solution, 1 mg/ml Cd in 0.5N HNO3
| 7440-43-9 |
|
3,3'-Diethyloxadicarbocyanine Iodide, 98% (UV-Vis)
| 14806-50-9 |
|
2-(2-(2-Methoxyethoxy)ethoxy)-1,3-Dioxola-ne, 97%
| 74733-99-6 |
|
3,4-Difluorobenzoyl chloride, 98%
| 76903-88-3 |
|
4-Methylsulphonyl Benzaldehyde, 95+%
| 5398-77-6 |
|
N,N'-Bis(3-Aminopropyl)Ethylenediamine, 96.5+% (GC)
| 10563-26-5 |
|
4-Amino-Alpha-Diethylamino-Ortho-Cresol Dihydrochloride, 97%
| 6297-14-9 |
|
Polyvinylpyrrolidone-iodine complex
| 25655-41-8 |
|
2,3,3-Trimethyl-1-butene, 99+%
| 594-56-9 |
|
N-Cyclohexyl-2-pyrrolidone, 99%
| 6837-24-7 |
|
Fluorobenzene-d5, 98+ atom % D
| 1423-10-5 |
|
DL-alpha-Tocopheryl acetate, 98%
| 7695-91-2 |
|
Methyl-d3 alcohol-d, 99.5 atom % D
| 67-56-1 |
|
Didodecylamine (Pract)
| 3007-31-6 |
|
3-Hexylthiophene, 99+%
| 1693-86-3 |
|
N-Methylbenzamide, 99+%
| 613-93-4 |
|
4,4'-Difluorobenzophenone, 99%
| 345-92-6 |
|
1-Fluoronaphthalene, 98%
| 321-38-0 |
|
|