**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 76903-88-3 |3,4-Difluorobenzoylchloride | 98 | 278-570-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.Corrosive.Lachrymator (substance
which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract. May cause systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause
systemic effects. May cause burning sensation, coughing, wheezing,
laryngitis, shortness of breath, headache, nausea, and vomiting.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Do NOT get water inside containers.
In case of fire, use carbon dioxide, dry chemical powder or
appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Do not ingest or inhale. Do not allow
contact with water. Use only in a chemical fume hood. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames. Keep from contact with moist air and steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 76903-88-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 61.0 - 63.0 deg C @ 15.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 78 deg C ( 172.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: May decompose.
Specific Gravity/Density: 1.4120g/cm3
Molecular Formula: C7H3ClF2O
Molecular Weight: 176.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose on
exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, moisture, water.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 76903-88-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3,4-Difluorobenzoylchloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
WGK (Water Danger/Protection)
CAS# 76903-88-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 76903-88-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 76903-88-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
4-Dimethylaminoantipyrine, 97%
| 58-15-1 |
|
(R)-(-)-1-Phenyl-1,2-Ethanediol, 99+%
| 16355-00-3 |
|
Triethylphenylammonium Hydroxide (10% in Water)
| 7620-71-5 |
|
4-Aminophenol Hydrochloride, 98% (UV-Vis)
| 51-78-5 |
|
N-Butylaniline,99%
| 1126-78-9 |
|
4-Chlorobutyryl chloride, 98%
| 4635-59-0 |
|
2-Ethyl-2-Hydroxybutyric Acid, 99%
| 3639-21-2 |
|
Methyl phenyl disulfide, 97+%
| 14173-25-2 |
|
1-Nitropyrene, 99%
| 5522-43-0 |
|
1-Hexadecanesulfonyl chloride, 98%
| 38775-38-1 |
|
M-Phenylene Dibenzoate
| 94-01-9 |
|
5-Methyl-1H-benzotriazole(1,2,3), 98%
| 136-85-6 |
|
1,4-Cyclohexanediol (Pract)
| 556-48-9 |
|
3-Nitrobenzamidine hydrochloride, 97%
| 56406-50-9 |
|
Tris-(3-(Heptafluoropropylhydroxymethylene )-D-Camphorato), Eu (III)
| 34788-82-4 |
|
2,3-Diphenylquinoxaline, 99+% (titr.)
| 1684-14-6 |
|
2-Isopropyl-3-Methoxypyrazine, 97%
| 25773-40-4 |
|
Cadmium fluoride, 99.99+%
| 7790-79-6 |
|
2,2,4-Trichlorobutanal, 97%
| 0-01-1 |
|
2-Fluorenecarboxaldehyde, 99%
| 30084-90-3 |
|
Calcein blue, indicator grade
| 54375-47-2 |
|
Tetraester 4-Tert-Butylcalix(4)Arene, 95% (TLC)
| 0-01-1 |
|
4-Fluorobenzotrifluoride, 97%
| 402-44-8 |
|
1-Oxo-Octyl-Beta-D-Glucoside, 99+%
| 0-01-1 |
|
Arecoline Hydrobromide, 99+%
| 300-08-3 |
|
Dl-2-amino-3-methyl-1-butanol, 95% (gc)
| 16369-05-4 |
|
4-Fluorobenzenesulfonyl Chloride, 98%
| 349-88-2 |
|
Telluroxanthone, 99+%
| 72294-67-8 |
|
Triethanolamine borate, 95+% (ex nitrogen)
| 15277-97-1 |
|
Acetyl-Beta-Methylcholine Bromide, 99%
| 333-31-3 |
|
2,4-Dimethylimidazole, Tech.,90%
| 930-62-1 |
|
Dl-3-methylcyclopentanone, 99%
| 1757-42-2 |
|
Cadmium atomic absorption standard solution, 1 mg/ml Cd in 0.5N HNO3
| 7440-43-9 |
|
3,3'-Diethyloxadicarbocyanine Iodide, 98% (UV-Vis)
| 14806-50-9 |
|
2-(2-(2-Methoxyethoxy)ethoxy)-1,3-Dioxola-ne, 97%
| 74733-99-6 |
|
3,4-Difluorobenzoyl chloride, 98%
| 76903-88-3 |
|
4-Methylsulphonyl Benzaldehyde, 95+%
| 5398-77-6 |
|
N,N'-Bis(3-Aminopropyl)Ethylenediamine, 96.5+% (GC)
| 10563-26-5 |
|
4-Amino-Alpha-Diethylamino-Ortho-Cresol Dihydrochloride, 97%
| 6297-14-9 |
|
Polyvinylpyrrolidone-iodine complex
| 25655-41-8 |
|
2,3,3-Trimethyl-1-butene, 99+%
| 594-56-9 |
|
N-Cyclohexyl-2-pyrrolidone, 99%
| 6837-24-7 |
|
Fluorobenzene-d5, 98+ atom % D
| 1423-10-5 |
|
DL-alpha-Tocopheryl acetate, 98%
| 7695-91-2 |
|
Methyl-d3 alcohol-d, 99.5 atom % D
| 67-56-1 |
|
Didodecylamine (Pract)
| 3007-31-6 |
|
3-Hexylthiophene, 99+%
| 1693-86-3 |
|
N-Methylbenzamide, 99+%
| 613-93-4 |
|
4,4'-Difluorobenzophenone, 99%
| 345-92-6 |
|
1-Fluoronaphthalene, 98%
| 321-38-0 |
|
|