**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 51429-74-4 |Phosphomolybdic acid hydrate | 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.Oxidizer.
Potential Health Effects
Eye:
Causes eye burns. May cause permanent corneal opacification. May
cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. May cause systemic effects. May cause nausea, vomiting, and
diarrhea, possibly with blood.
Inhalation:
Causes chemical burns to the respiratory tract. May cause systemic
effects. May cause burning sensation, coughing, wheezing, laryngitis,
shortness of breath, headache, nausea, and vomiting. May cause acute
pulmonary edema, asphyxia, chemical pneumonitis, and upper airway
obstruction caused by edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
with caution and in flooding amounts. Oxidizer. Greatly increases the
burning rate of combustible materials.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Remove all sources of ignition.
Provide ventilation. In case of spill, sweep up solid or absorb
liquid with inert material, then place into a biohazard container.
Wear protective equipment.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Keep container tightly closed. Avoid contact
with clothing and other combustible materials. Do not ingest or
inhale. Discard contaminated shoes. Do not breathe dust or fumes.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry, well-ventilated area
away from incompatible substances. Keep refrigerated. (Store below
4C/39F.) Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 12026-57-2:
United Kingdom, WEL - TWA: (listed as molybdenum soluble compound
5 mg/m3 TWA (as Mo)
United Kingdom, WEL - STEL: (listed as molybdenum soluble compoun
10 mg/m3 STEL (as Mo)
United States OSHA: 5 mg/m3 TWA (as Mo) (listed under Molybdenum
soluble compounds).
Belgium - TWA: (listed as molybdenum soluble compounds): 5 mg/m3
(as Mo)
France - VME: (listed as molybdenum soluble compounds): 5 mg/m3 V
(as Mo)
France - VLE: (listed as molybdenum soluble compounds): 10 mg/m3
(as Mo)
Germany: (listed as molybdenum soluble compounds): 5 mg/m3 VME (a
Mo)
Malaysia: (listed as molybdenum soluble compounds): 5 mg/m3 TWA (
Mo)
Netherlands: (listed as molybdenum soluble compounds): 5 mg/m3 MA
(as Mo)
Russia: (listed as molybdenum soluble compounds): 2 mg/m3 TWA (as
Spain: (listed as molybdenum soluble compounds): 5 mg/m3 VLA-ED (
Mo)
CAS# 51429-74-4:
United Kingdom, WEL - TWA: (listed as molybdenum soluble compound
5 mg/m3 TWA (as Mo)
United Kingdom, WEL - STEL: (listed as molybdenum soluble compoun
10 mg/m3 STEL (as Mo)
United States OSHA: 5 mg/m3 TWA (as Mo) (listed under Molybdenum
soluble compounds).
Belgium - TWA: (listed as molybdenum soluble compounds): 5 mg/m3
(as Mo)
France - VME: (listed as molybdenum soluble compounds): 5 mg/m3 V
(as Mo)
France - VLE: (listed as molybdenum soluble compounds): 10 mg/m3
(as Mo)
Germany: (listed as molybdenum soluble compounds): 5 mg/m3 VME (a
Mo)
Malaysia: (listed as molybdenum soluble compounds): 5 mg/m3 TWA (
Mo)
Netherlands: (listed as molybdenum soluble compounds): 5 mg/m3 MA
(as Mo)
Russia: (listed as molybdenum soluble compounds): 2 mg/m3 TWA (as
Spain: (listed as molybdenum soluble compounds): 5 mg/m3 VLA-ED (
Mo)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to
prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: yellow
Odor: none reported
pH: Not available.
Vapor Pressure: 4.0 mm Hg @ 17.8 deg C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: practical insoluble: 0.01% max
Specific Gravity/Density: Not available.
Molecular Formula: Mo20O65P2
Molecular Weight: 3020.71
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, dust generation, combustible materials, organic
materials, reducing agents, finely powdered metals.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Nature of decomposition products unknown..
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12026-57-2 unlisted.
CAS# 51429-74-4 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Phosphomolybdic acid, anhydrous -
Not listed by ACGIH, IARC, or NTP.
Phosphomolybdic acid hydrate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3260
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 12026-57-2: No information available.
CAS# 51429-74-4: No information available.
Canada
CAS# 12026-57-2 is listed on Canada's DSL List.
CAS# 12026-57-2 is not listed on Canada's Ingredient Disclosure List.
CAS# 51429-74-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12026-57-2 is listed on the TSCA inventory.
CAS# 51429-74-4 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 8/24/1997 Revision #5 Date: 11/14/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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