**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 124-02-7 |Diallylamine | 97 | 204-671-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T F
Risk Phrases: 11 22 24 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. Toxic in contact with skin.
Irritating to eyes, respiratory system and skin.Highly
flammable.Lachrymator (substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes severe eye irritation. Lachrymator (substance which
increases the flow of tears).
Skin:
May cause skin irritation. Harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Vapors may cause dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Remove contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. If breathing has ceased
apply artificial respiration using oxygen and a suitable mechanical
device such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and
flash back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Water may be ineffective. Material
is lighter than water and a fire may be spread by the use of water.
Flammable liquid and vapor. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas. Will be
easily ignited by heat, sparks or flame. Containers may explode if
exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. In case of fire, use water, dry chemical,
chemical foam, or alcohol-resistant foam. Water may be ineffective.
Water may spread fire. If water is the only media available, use in
flooding amounts. Use agent most appropriate to extinguish fire. For
large fires, use water spray, fog or alcohol-resistant foam. Do NOT
use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Do not get in
eyes, on skin, or on clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep away from
heat, sparks and flame. Do not ingest or inhale. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 124-02-7:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Colorless - Light Yellow Liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 111 - 112 deg C @ 760.00mm Hg
Freezing/Melting Point: -88 deg C
Autoignition Temperature: Not available.
Flash Point: 7 deg C ( 44.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 90 g/l (20 c)
Specific Gravity/Density: .7870g/cm3
Molecular Formula: C6H11N
Molecular Weight: 97.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, excess
heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, carbon dioxide, acid anhydrides, acid
chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 124-02-7: UC6650000
LD50/LC50:
CAS# 124-02-7: Inhalation, rat: LC50 = 795 ppm/8H; Oral, mouse: LD50
= 355 mg/kg; Oral, rat: LD50 = 578 mg/kg; Skin, rabbit: LD50 = 280
uL/kg.
Inhalation, human (man): TCLo = 5ppm/5M (Pulmonary system effects,
Eye effects)
mammal: LC50 = 2100 mg
Carcinogenicity:
Diallylamine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIALLYLAMINE
Hazard Class: 3 (6.1)
UN Number: 2359
Packing Group: II
IMO
Shipping Name: DIALLYLAMINE
Hazard Class: 3.2 (6.1)
UN Number: 2359
Packing Group: II
RID/ADR
Shipping Name: DIALLYLAMINE
Hazard Class: 3
UN Number: 2359
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 29 Do not empty into drains.
WGK (Water Danger/Protection)
CAS# 124-02-7: No information available.
Canada
CAS# 124-02-7 is listed on Canada's DSL List.
CAS# 124-02-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 124-02-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/24/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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2-(2-Chloroethoxy)-ethanol, 99%
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| 617-27-6 |
|
3-Amino-1,2,4-Triazine, 97%
| 1120-99-6 |
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2-Cyanophenol, 99%
| 611-20-1 |
|
2-Phenylpropyl isobutyrate, 98%
| 65813-53-8 |
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1-Methyl-2-pyrrolidineethanol, 98%
| 67004-64-2 |
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O-Tolunitrile, 98%
| 529-19-1 |
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Ammonium Iodide, P.A.
| 12027-06-4 |
|
4-Ethyl-1,3-Dioxolan-2-one
| 4437-51-8 |
|
(-)-2,3-O-Benzylidene-(L)-Threitol, 98%
| 35572-34-0 |
|
1,12-Diaminododecane, 98%
| 2783-17-7 |
|
1,1,2-Trichloro-1,2,2-trifluoroethane
| 76-13-1 |
|
1,1,2-Trichloroethane
| 79-00-5 |
|
Bordeaux R
| 5858-33-3 |
|
Exo-2-Chloro-Syn-7-Hydroxymethyl-5-Oxo-Bicyclo??2.2.1??Heptane, 98%
| 0-00-1 |
|
9-Hydroxyfluorene, 97+%
| 1689-64-1 |
|
Boron tribromide
| 10035-10-6 |
|
6-Hydroxytropinone
| 5932-53-6 |
|
4-Chlorobenzenesulfonic acid (techn), 90% (titr.)
| 98-66-8 |
|
(+)-cis-2(r),3(s)-2,3-dihydroxy-2,3- dihydrobenzonitrile, 98+% (nmr)
| 138769-96- |
|
Copper chromite, barium promoted
| 12053-18-8 |
|
2,5-Dimethyl-P-Anisaldehyde, 97%
| 6745-75-1 |
|
2,4,5-Trichlorotoluene, 98%
| 6639-30-1 |
|
Meta-Anisoyl Chloride, 99%
| 1711-05-3 |
|
bis(2-Hydroxyethyl)dimethylammonium chloride, 99%
| 38402-02-7 |
|
4-Bromo-2,5-difluoroanisole, 99%
| |
|
3,5-Dimethoxycinnamic Acid, 99+% Predominantly Trans Isomer
| 16909-11-8 |
|
2-(2-nitro-4-benzoic acid)malondialdehyde
| |
|
2,6-Difluorobenzoic Acid, 98%
| 385-00-2 |
|
Coumarin 314T, Laser Grade
| 113869-06-0 |
|
2-Methylheptanoic Acid, 98%
| 1188-02-9 |
|
Diethyl phosphite, 98%
| 64-17-5 |
|
3-Aminophenylacetylene, 99% (GC)
| 54060-30-9 |
|
7,12-Dimethylbenz(a)anthracene, 99%(uv-vis)
| 57-97-6 |
|
Bromoxylenol blue, indicator grade
| 40070-59-5 |
|
3-Nitrobenzoic acid, 99%
| 121-92-6 |
|
Neodymium(III)Nitrate Hexahydrate, 99.99%
| 16454-60-7 |
|
4,5-Dichlorophthalic Acid, 99%
| 56962-08-4 |
|
6-Mercaptopurine-9-d-riboside, 99+%
| 574-25-4 |
|
1,8-Dihydroxyanthraquinone, 90-95%
| 117-10-2 |
|
Dl-tyrosine, 99%
| 556-03-6 |
|
Gallocyanine
| 1562-85-2 |
|
5-Bromo-4-chloro-3-indolyl-beta-D-glucoside (X-Glucoside)
| 15548-60-4 |
|
Cyclopentanone Oxime
| 1192-28-5 |
|
Diallylamine, 97%
| 124-02-7 |
|
|