**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 76-13-1 |1,1,2-Trichlorotrifluoroethane | 99 | 200-936-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: N
Risk Phrases: 59
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Dangerous for the ozone layer.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Skin:
May cause mild skin irritation. Prolonged or repeated contact may
dry/defat the skin and cause irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Expected to be a low ingestion hazard.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Vapor reduces oxygen available for breathing. May cause
heart disturbances, possibly leading to cardiac arrest and death. May
cause narcotic effects in high concentration.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Causes cardiac sensitization to endogenous catelcholamines which may
lead to cardiac arrhythmias. Do NOT use adrenergic agents such as
epinephrine or pseudoepinephrine.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Substance is
noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. U.S. regulations require reporting spills and releases
to soil, water and air in excess of reportable quantities.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid ingestion and inhalation. Do not
vent to the atmosphere. To comply with provisions of the U.S. Clean
Air Act, any residual must be recovered.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 76-13-1:
United States OSHA: 1000 ppm TWA; 7600 mg/m3 TWA
Belgium - TWA: 1000 ppm VLE; 7781 mg/m3 VLE
Belgium - STEL: 1250 ppm VLE; 9729 mg/m3 VLE
France - VME: 1000 ppm VME; 7600 mg/m3 VME
France - VLE: 1250 ppm VLE; 9500 mg/m3 VLE
Germany: 500 ppm TWA; 3900 mg/m3 TWA
Japan: 500 ppm OEL; 3800 mg/m3 OEL
Malaysia: 1000 ppm TWA; 7670 mg/m3 TWA
Netherlands: 150 ppm MAC; 1170 mg/m3 MAC
Russia: 5000 mg/m3 TWA
Spain: 1000 ppm VLA-ED; 7795 mg/m3 VLA-ED
Spain: 1250 ppm VLA-EC; 9745 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: ethereal odor - weak odor - sweetish odor
pH: Not available.
Vapor Pressure: 273 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 47-48 deg C
Freezing/Melting Point: -36 deg C
Autoignition Temperature: 770 deg C ( 1,418.00 deg F)
Flash Point: None.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 1.5635 @ 25C
Molecular Formula: C2Cl3F3
Molecular Weight: 187.38
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, powdered
aluminum.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic
fumes and gases, carbon dioxide, hydrogen fluoride gas, carbonyl
fluoride.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 76-13-1: KJ4000000
LD50/LC50:
CAS# 76-13-1: Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, mouse: LC50 = 260 gm/m3/2H; Inhalation, mouse: LC50 =
467000 mg/m3/2H; Inhalation, rabbit: LC50 = 59500 ppm/2H;
Inhalation, rabbit: LC50 = 59.5 ppm/2H; Inhalation, rat: LC50 =
38500 ppm/4H; Inhalation, rat: LC50 = 53.3 ppm/4H; Inhalation, rat:
LC50 = 38.5 ppm/4H; Inhalation, rat: LC50 = 52.5 ppm/4H; Oral, rat:
LD50 = 43 gm/kg; Oral, rat: LD50 = 43 gm/kg.
Carcinogenicity:
1,1,2-Trichlorotrifluoroethane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: N
Risk Phrases:
R 59 Dangerous for the ozone layer.
Safety Phrases:
S 59 Refer to manufacturer/supplier for information
on recovery/recycling.
WGK (Water Danger/Protection)
CAS# 76-13-1: 2
Canada
CAS# 76-13-1 is listed on Canada's DSL List.
CAS# 76-13-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 76-13-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/12/1997 Revision #6 Date: 4/04/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
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| 79-00-5 |
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| 1689-64-1 |
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| 138769-96- |
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| 1711-05-3 |
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| |
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| 16909-11-8 |
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2-(2-nitro-4-benzoic acid)malondialdehyde
| |
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2,6-Difluorobenzoic Acid, 98%
| 385-00-2 |
|
Coumarin 314T, Laser Grade
| 113869-06-0 |
|
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|
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| 64-17-5 |
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3-Aminophenylacetylene, 99% (GC)
| 54060-30-9 |
|
7,12-Dimethylbenz(a)anthracene, 99%(uv-vis)
| 57-97-6 |
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| 40070-59-5 |
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| 121-92-6 |
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| 16454-60-7 |
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