**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 67004-64-2 |1-Methyl-2-pyrrolidineethanol | 98 | 266-538-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 38 41
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin. Risk of serious damage to
eyes.
Potential Health Effects
Eye:
Causes severe eye irritation and possible injury. May cause
chemical conjunctivitis and corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. Can produce delayed
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use water spray,
dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 67004-64-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow to brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 110 - 112 deg C @ 14.00 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: 240 deg C ( 464.00 deg F)
Flash Point: 84 deg C ( 183.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: 0.9510 g/cm3
Molecular Formula: C7H15NO
Molecular Weight: 129.20
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Stable at room
temperature in closed containers under normal storage and handling
conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and
gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67004-64-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Methyl-2-pyrrolidineethanol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
R 41 Risk of serious damage to eyes.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 67004-64-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 67004-64-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67004-64-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethyleneglycol Monoricinoleate
| 5401-17-2 |
|
Potassium, chunks, in mineral oil
| 7440-09-7 |
|
1-Naphthalenesulfonyl Chloride, 99%
| 85-46-1 |
|
2-(2-Chloroethoxy)-ethanol, 99%
| 628-89-7 |
|
1,2-Benzisoxazol-3-yl-diphenyl phosphate, 97%(TLC)
| 0-01-0 |
|
Aminoguanidine Bicarbonate, 98.5%
| 2582-30-1 |
|
2-Methyl-3-hexanol, 98%
| 617-27-6 |
|
3-Amino-1,2,4-Triazine, 97%
| 1120-99-6 |
|
2-Cyanophenol, 99%
| 611-20-1 |
|
2-Phenylpropyl isobutyrate, 98%
| 65813-53-8 |
|
1-Methyl-2-pyrrolidineethanol, 98%
| 67004-64-2 |
|
O-Tolunitrile, 98%
| 529-19-1 |
|
Ammonium Iodide, P.A.
| 12027-06-4 |
|
4-Ethyl-1,3-Dioxolan-2-one
| 4437-51-8 |
|
(-)-2,3-O-Benzylidene-(L)-Threitol, 98%
| 35572-34-0 |
|
1,12-Diaminododecane, 98%
| 2783-17-7 |
|
1,1,2-Trichloro-1,2,2-trifluoroethane
| 76-13-1 |
|
1,1,2-Trichloroethane
| 79-00-5 |
|
Bordeaux R
| 5858-33-3 |
|
Exo-2-Chloro-Syn-7-Hydroxymethyl-5-Oxo-Bicyclo??2.2.1??Heptane, 98%
| 0-00-1 |
|
9-Hydroxyfluorene, 97+%
| 1689-64-1 |
|
Boron tribromide
| 10035-10-6 |
|
6-Hydroxytropinone
| 5932-53-6 |
|
4-Chlorobenzenesulfonic acid (techn), 90% (titr.)
| 98-66-8 |
|
(+)-cis-2(r),3(s)-2,3-dihydroxy-2,3- dihydrobenzonitrile, 98+% (nmr)
| 138769-96- |
|
Copper chromite, barium promoted
| 12053-18-8 |
|
2,5-Dimethyl-P-Anisaldehyde, 97%
| 6745-75-1 |
|
2,4,5-Trichlorotoluene, 98%
| 6639-30-1 |
|
Meta-Anisoyl Chloride, 99%
| 1711-05-3 |
|
bis(2-Hydroxyethyl)dimethylammonium chloride, 99%
| 38402-02-7 |
|
4-Bromo-2,5-difluoroanisole, 99%
| |
|
3,5-Dimethoxycinnamic Acid, 99+% Predominantly Trans Isomer
| 16909-11-8 |
|
2-(2-nitro-4-benzoic acid)malondialdehyde
| |
|
2,6-Difluorobenzoic Acid, 98%
| 385-00-2 |
|
Coumarin 314T, Laser Grade
| 113869-06-0 |
|
2-Methylheptanoic Acid, 98%
| 1188-02-9 |
|
Diethyl phosphite, 98%
| 64-17-5 |
|
3-Aminophenylacetylene, 99% (GC)
| 54060-30-9 |
|
7,12-Dimethylbenz(a)anthracene, 99%(uv-vis)
| 57-97-6 |
|
Bromoxylenol blue, indicator grade
| 40070-59-5 |
|
3-Nitrobenzoic acid, 99%
| 121-92-6 |
|
Neodymium(III)Nitrate Hexahydrate, 99.99%
| 16454-60-7 |
|
4,5-Dichlorophthalic Acid, 99%
| 56962-08-4 |
|
6-Mercaptopurine-9-d-riboside, 99+%
| 574-25-4 |
|
1,8-Dihydroxyanthraquinone, 90-95%
| 117-10-2 |
|
Dl-tyrosine, 99%
| 556-03-6 |
|
Gallocyanine
| 1562-85-2 |
|
5-Bromo-4-chloro-3-indolyl-beta-D-glucoside (X-Glucoside)
| 15548-60-4 |
|
Cyclopentanone Oxime
| 1192-28-5 |
|
Diallylamine, 97%
| 124-02-7 |
|
|