**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1307-96-6 |Cobalt(II) oxide | | 215-154-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 22 40 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic effect. May
cause sensitization by skin contact. Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin. May cause sensitization by skin contact.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Limited evidence of a carcinogenic effect.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 1307-96-6:
United Kingdom, WEL - TWA: (listed as cobalt compounds): 0.1 mg/m
TWA (as Co)
United Kingdom, WEL - STEL: (listed as cobalt compounds): 0.3 mg/
STEL (as Co)
Japan: (listed as cobalt compounds): 0.05 mg/m3 OEL (as Co)
Malaysia: (listed as cobalt, inorganic compounds): 0.02 mg/m3 TWA
Co)
Spain: (listed as cobalt, inorganic compounds): 0.02 mg/m3 VLA-ED
Co)
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: green - brown
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 1785 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: CoO
Molecular Weight: 74.93
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Metallic oxides.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1307-96-6: GG2800000
LD50/LC50:
CAS# 1307-96-6: Oral, rat: LD50 = 202 mg/kg; Oral, rat: LD50 = 202
mg/kg.
Carcinogenicity:
Cobalt(II) oxide -
California: carcinogen, initial date 7/1/92
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
*
Hazard Class: 9
UN Number: 3077
Packing Group: III
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class: 9
UN Number: 3077
Packing Group: III
RID/ADR
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class: 9
UN Number: 3077
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 24 Avoid contact with skin.
S 37 Wear suitable gloves.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1307-96-6: 2
Canada
CAS# 1307-96-6 is listed on Canada's DSL List.
CAS# 1307-96-6 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1307-96-6 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
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| 1198-37-4 |
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| 141-78-6 |
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| 2243-83-6 |
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| 3462-97-3 |
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| 2835-82-7 |
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Meso-1,2-bis(4-fluorophenyl)ethylenediamine, 98%
| 50648-93-6 |
Meso-1,2-bis(p-tolyl)ethylenediamine, 98%
| 50764-59-5 |
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| 58520-45-9 |
Meso-1,2-bis(1-naphthyl)ethylenediamine, 99%
| 117106-39-5 |
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| 3002-18-4 |
2,6-Difluorophenylacetone
| 101712-20-3 |
2-Fluoroethanol
| 371-62-0 |
Bismuth oxychloride, 99.99%
| 7787-59-9 |
Iron (III) Chloride Anhydrous
| 7705-08-0 |
Aluminium isopropoxide
| 555-31-7 |
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| 2524-67-6 |
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| 12029-98-0 |
Cobalt(II) oxide
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| 1310-65-2 |
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| 0-01-1 |
Methyl 3,4-Dimethoxybenzoate, 98+%
| 2150-38-1 |
bis(1,5-Cyclooctadiene)rhodium(i) tetrafluoroborate
| 35138-22-8 |
bis(Pentafluorophenyl) carbonate, 98%
| 59483-84-0 |
(r)-(1-Aminopropyl)phosphonic acid
| 98049-00-4 |
(s)-(1-aminopropyl)phosphonic acid
| 98048-99-8 |
Iron(III) chloride hexahydrate
| 7705-08-0 |
(1R)-(+)-(1-Amino-2-methylpropyl)phosphonic acid
| 66254-56-6 |
(1S)-(-)-(1-Amino-2-methylpropyl)phosphonic acid
| 66254-55-5 |
Tris(2,5-dimethylphenyl)phosphine
| 115034-38-3 |
Tris(3,5-dimethylphenyl)phosphine
| 69227-47-0 |
l-Tryptophan ethyl ester hydrochloride, 99%
| 2899-28-7 |
L-Tryptophan methyl ester hydrochloride, 98%
| 7524-52-9 |
L-Aspartic acid dimethyl ester hydrochloride, 99%
| 32213-95-9 |
Iron Oxide
| 1317-61-9 |
l-Threonine methyl ester hydrochloride
| 39994-75-7 |
l-Arginine methyl ester dihydrochloride, 98%
| 26340-89-6 |
n-Acetyl-l-proline, 99%
| 68-95-1 |
tert-Butyl peroxybenzoate, 98%
| 614-45-9 |
1,1'-Sulfonyldiimidazole
| 7189-69-7 |
2,3-Dichloropyrazine
| 4858-85-9 |
|
|