**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 555-31-7 |Aluminium isopropoxide | >98% | 209-090-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Flammable solid.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Remove all sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 555-31-7:
United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2
mg/m3 TWA
United Kingdom, WEL - STEL: (listed as aluminum, soluble salts):
mg/m3 STEL
Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE (
Al)
France - VME: (listed as aluminum, soluble salts): 2 mg/m3 VME
Germany: (listed as aluminum, soluble salts): 2 mg/m3 VME
Malaysia: (listed as aluminum, soluble salts): 2 mg/m3 TWA (as Al
Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: alcohol-like
pH: Not available.
Vapor Pressure: 0.13hPa @21 deg C
Viscosity: Not available.
Boiling Point: 125 - 130 deg C @38mmHg
Freezing/Melting Point: 129 - 136 deg C
Autoignition Temperature: Not available.
Flash Point: 46 deg C ( 114.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density:
Molecular Formula: C9H21AlO3
Molecular Weight: 204.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Moisture sensitive.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, halogens.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, aluminum oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 555-31-7: BD0975000
LD50/LC50:
CAS# 555-31-7: Oral, rat: LD50 = 11300 mg/kg.
Carcinogenicity:
Aluminium isopropoxide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S
.*
Hazard Class: 4.1
UN Number: 3181
Packing Group: II
IMO
Shipping Name: METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S
.
Hazard Class: 4.1
UN Number: 3181
Packing Group: II
RID/ADR
Shipping Name: METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S
.
Hazard Class: 4.1
UN Number: 3181
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 8 Keep container dry.
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 555-31-7: 1
Canada
CAS# 555-31-7 is listed on Canada's DSL List.
CAS# 555-31-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 555-31-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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| 2131-62-6 |
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| 937-63-3 |
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Nordihydroguaiaretic acid, 95%
| 500-38-9 |
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| 926-02-3 |
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2,4-Dimethylquinoline, 97%
| 1198-37-4 |
|
1-Propanephosphonic acid cyclic anhydride, solution in ethyl acetate
| 141-78-6 |
|
1-Propanephosphonic acid cyclic anhydride, solution in
| 68-12-2 |
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Dess-Martin-periodinane
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Tris(tert-butylimido)osmium oxide
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|
Bis(tert-butylimido)osmium dioxide
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|
(tert-Butylimido)osmium trioxide
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|
2-Naphthoyl chloride
| 2243-83-6 |
|
(4-Methoxybenzyl)triphenylphosphonium bromide
| 3462-97-3 |
|
Dl-3-amino butyric acid, 97%
| 2835-82-7 |
|
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| 74641-30-8 |
|
Meso-1,2-bis(4-fluorophenyl)ethylenediamine, 98%
| 50648-93-6 |
|
Meso-1,2-bis(p-tolyl)ethylenediamine, 98%
| 50764-59-5 |
|
Meso-1,2-bis(4-methoxyphenyl)ethylenediamine, 98%
| 58520-45-9 |
|
Meso-1,2-bis(1-naphthyl)ethylenediamine, 99%
| 117106-39-5 |
|
Triethanolamine triacetate, 95%
| 3002-18-4 |
|
2,6-Difluorophenylacetone
| 101712-20-3 |
|
2-Fluoroethanol
| 371-62-0 |
|
Bismuth oxychloride, 99.99%
| 7787-59-9 |
|
Iron (III) Chloride Anhydrous
| 7705-08-0 |
|
Aluminium isopropoxide
| 555-31-7 |
|
p-Morpholinoaniline, 98+%
| 2524-67-6 |
|
Iodine pentoxide
| 12029-98-0 |
|
Cobalt(II) oxide
| 1307-96-6 |
|
Lithium hydroxide anhydrous, 98%
| 1310-65-2 |
|
N-BOC-(1,4'-bipiperidine)-4'-carboxamide
| 0-01-1 |
|
Methyl 3,4-Dimethoxybenzoate, 98+%
| 2150-38-1 |
|
bis(1,5-Cyclooctadiene)rhodium(i) tetrafluoroborate
| 35138-22-8 |
|
bis(Pentafluorophenyl) carbonate, 98%
| 59483-84-0 |
|
(r)-(1-Aminopropyl)phosphonic acid
| 98049-00-4 |
|
(s)-(1-aminopropyl)phosphonic acid
| 98048-99-8 |
|
Iron(III) chloride hexahydrate
| 7705-08-0 |
|
(1R)-(+)-(1-Amino-2-methylpropyl)phosphonic acid
| 66254-56-6 |
|
(1S)-(-)-(1-Amino-2-methylpropyl)phosphonic acid
| 66254-55-5 |
|
Tris(2,5-dimethylphenyl)phosphine
| 115034-38-3 |
|
Tris(3,5-dimethylphenyl)phosphine
| 69227-47-0 |
|
l-Tryptophan ethyl ester hydrochloride, 99%
| 2899-28-7 |
|
L-Tryptophan methyl ester hydrochloride, 98%
| 7524-52-9 |
|
L-Aspartic acid dimethyl ester hydrochloride, 99%
| 32213-95-9 |
|
Iron Oxide
| 1317-61-9 |
|
l-Threonine methyl ester hydrochloride
| 39994-75-7 |
|
l-Arginine methyl ester dihydrochloride, 98%
| 26340-89-6 |
|
n-Acetyl-l-proline, 99%
| 68-95-1 |
|
tert-Butyl peroxybenzoate, 98%
| 614-45-9 |
|
1,1'-Sulfonyldiimidazole
| 7189-69-7 |
|
2,3-Dichloropyrazine
| 4858-85-9 |
|
|