**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3462-97-3 |(4-Methoxybenzyl)triphenylphosphonium | | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Do NOT use water directly on fire. Use foam, dry chemical, or carbon
dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Vacuum or sweep up material and
place into a suitable disposal container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3462-97-3:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C26H24BrOP
Molecular Weight: 463.35
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Moisture sensitive.
Conditions to Avoid:
Incompatible materials, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of phosphorus, carbon dioxide, hydrogen
bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3462-97-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(4-Methoxybenzyl)triphenylphosphonium bromide -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 3462-97-3: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 3462-97-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3462-97-3 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
| NAME | CAS |
4-Isothiocyanatobenzoic acid, 98%
| 2131-62-6 |
p-Tolyl chlorothionoformate, 98%
| 937-63-3 |
Nordihydroguaiaretic acid, 95%
| 500-38-9 |
tert-Butyl vinyl ether, stabilized, 98%
| 926-02-3 |
2,4-Dimethylquinoline, 97%
| 1198-37-4 |
1-Propanephosphonic acid cyclic anhydride, solution in ethyl acetate
| 141-78-6 |
1-Propanephosphonic acid cyclic anhydride, solution in
| 68-12-2 |
Dess-Martin-periodinane
| 87413-09-0 |
Tris(tert-butylimido)osmium oxide
| 63174-16-3 |
Bis(tert-butylimido)osmium dioxide
| 63174-13-0 |
(tert-Butylimido)osmium trioxide
| 50381-48-1 |
2-Naphthoyl chloride
| 2243-83-6 |
(4-Methoxybenzyl)triphenylphosphonium bromide
| 3462-97-3 |
Dl-3-amino butyric acid, 97%
| 2835-82-7 |
meso-1,2-Bis(4-chlorophenyl)ethylenediamine
| 74641-30-8 |
Meso-1,2-bis(4-fluorophenyl)ethylenediamine, 98%
| 50648-93-6 |
Meso-1,2-bis(p-tolyl)ethylenediamine, 98%
| 50764-59-5 |
Meso-1,2-bis(4-methoxyphenyl)ethylenediamine, 98%
| 58520-45-9 |
Meso-1,2-bis(1-naphthyl)ethylenediamine, 99%
| 117106-39-5 |
Triethanolamine triacetate, 95%
| 3002-18-4 |
2,6-Difluorophenylacetone
| 101712-20-3 |
2-Fluoroethanol
| 371-62-0 |
Bismuth oxychloride, 99.99%
| 7787-59-9 |
Iron (III) Chloride Anhydrous
| 7705-08-0 |
Aluminium isopropoxide
| 555-31-7 |
p-Morpholinoaniline, 98+%
| 2524-67-6 |
Iodine pentoxide
| 12029-98-0 |
Cobalt(II) oxide
| 1307-96-6 |
Lithium hydroxide anhydrous, 98%
| 1310-65-2 |
N-BOC-(1,4'-bipiperidine)-4'-carboxamide
| 0-01-1 |
Methyl 3,4-Dimethoxybenzoate, 98+%
| 2150-38-1 |
bis(1,5-Cyclooctadiene)rhodium(i) tetrafluoroborate
| 35138-22-8 |
bis(Pentafluorophenyl) carbonate, 98%
| 59483-84-0 |
(r)-(1-Aminopropyl)phosphonic acid
| 98049-00-4 |
(s)-(1-aminopropyl)phosphonic acid
| 98048-99-8 |
Iron(III) chloride hexahydrate
| 7705-08-0 |
(1R)-(+)-(1-Amino-2-methylpropyl)phosphonic acid
| 66254-56-6 |
(1S)-(-)-(1-Amino-2-methylpropyl)phosphonic acid
| 66254-55-5 |
Tris(2,5-dimethylphenyl)phosphine
| 115034-38-3 |
Tris(3,5-dimethylphenyl)phosphine
| 69227-47-0 |
l-Tryptophan ethyl ester hydrochloride, 99%
| 2899-28-7 |
L-Tryptophan methyl ester hydrochloride, 98%
| 7524-52-9 |
L-Aspartic acid dimethyl ester hydrochloride, 99%
| 32213-95-9 |
Iron Oxide
| 1317-61-9 |
l-Threonine methyl ester hydrochloride
| 39994-75-7 |
l-Arginine methyl ester dihydrochloride, 98%
| 26340-89-6 |
n-Acetyl-l-proline, 99%
| 68-95-1 |
tert-Butyl peroxybenzoate, 98%
| 614-45-9 |
1,1'-Sulfonyldiimidazole
| 7189-69-7 |
2,3-Dichloropyrazine
| 4858-85-9 |
|
|