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MSDS 
:
 Chromium(III) Oxide, 99%, Amorphous Powder
CAS 
:
 1308-38-9
SYNONYMS 
:
 Chrome Oxide; Green Chrome Oxide
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1308-38-9 |Chromimium (III) Oxide | 100 | 215-160-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Cancer suspect agent.Hygroscopic.Oxidizer.

Potential Health Effects
Eye:
May cause mild eye irritation.
Skin:
May cause mild skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. Repeated
inhalation may cause chronic bronchitis. May cause cancer according
to animal studies.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. Get medical aid if
cough or other symptoms appear.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible. Oxidizer. Greatly
increases the burning rate of combustible materials.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage:
Do not store near combustible materials. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Appearance: green
Odor: Odorless.
pH: Not available.
Vapor Pressure: Not applicable.
Viscosity: Not available.
Boiling Point: 4000 deg C @ 760.00mmHg
Freezing/Melting Point: 2435 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 5.2100g/cm3
Molecular Formula: Cr2O3
Molecular Weight: 151.99

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Combustible materials.
Incompatibilities with Other Materials:
Chlorine trifluoride, glycerol, lithium, rubidium acetylide, and
oxygen difluoride.
Hazardous Decomposition Products:
None.
Hazardous Polymerization: Has not been reported.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 1308-38-9: GB6475000
LD50/LC50:
Not available.
Carcinogenicity:
Chromimium (III) Oxide -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as **
IARC: Group 3 carcinogen (listed as ** undefined **).
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Dangerous Goods Code:
UN Number:

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 1308-38-9: 1
United Kingdom Occupational Exposure Limits
CAS# 1308-38-9: OES-United Kingdom, TWA (listed as ** undefined
**): 0.5 mg/m3 TWA

Canada
CAS# 1308-38-9 is listed on Canada's DSL List.
CAS# 1308-38-9 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 1308-38-9 (listed as ** undefined **): OEL-ARAB Republic of Egypt
:TWA 0.05 mg/m3
OEL-AUSTRALIA:TWA 0.05 mg/m3
OEL-BELGIUM:TWA 0.5 mg/m3
OEL-DENMARK:TWA 0.5 mg/m3
OEL-FINLAND:TWA 0.01 mg/m3
OEL-FRANCE:TWA 0.5 mg/m3
OEL-JAPAN:TWA 0.5 mg/m3
OEL-THE NETHERLANDS:TWA 0.5 mg/m3
OEL-THE PHILIPPINES:TWA 1 mg/m3
OEL-SWEDEN:TWA 0.5 mg/m3
OEL-UNITED KINGDOM:TWA 0.5 mg/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 1308-38-9 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 11/21/1997 Revision #2 Date: 8/02/2000

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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