**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 35223-80-4 |Propyl Bromoacetate | 98% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). May cause chemical conjunctivitis and corneal damage.
Skin:
Causes skin burns. May cause cyanosis of the extremities. May cause
skin rash (in milder cases), and cold and clammy skin with cyanosis
or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. May cause systemic effects. May cause cardiac
effects such as tachyardia and shock.
Inhalation:
Causes chemical burns to the respiratory tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Aspiration may lead to pulmonary edema. May cause systemic effects.
Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Will burn
if involved in a fire. Use water spray to keep fire-exposed
containers cool. Combustible liquid. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas. Containers may explode when heated. Runoff from fire control
or dilution water may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Keep away from heat, sparks and flame.
Do not ingest or inhale. Use only in a chemical fume hood. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low. Use only under a
chemical fume hood.
Exposure Limits
CAS# 35223-80-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 175 - 176 deg C @ 758mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 82 deg C ( 179.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3990g/cm3
Molecular Formula: C5H9BrO2
Molecular Weight: 180.9658
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 35223-80-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Propyl Bromoacetate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Pseudomonas putida:
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 35223-80-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 35223-80-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 35223-80-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/30/1998 Revision #4 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethyl(2,2-Diethoxypropyl)Phosphonate
| 0-01-1 |
|
Diethyl(2-Propenyl)Phosphonate
| 5954-65-4 |
|
2-Chloromandelic acid, 98%
| 10421-85-9 |
|
Chloroform, Reagent ACS, Spectro Grade
| 67-66-3 |
|
4,4'-Dimethylbiphenyl, 97%
| 613-33-2 |
|
Chloramphenicol, 98.0 - 102.0%
| 56-75-7 |
|
Chlorosulfonic acid, 98%
| 7790-94-5 |
|
Cholesterol, 95+% (gc)
| 57-88-5 |
|
Choline Chloride, P.A.
| 67-48-1 |
|
Propyl Bromoacetate, 98%
| 35223-80-4 |
|
1-(4-Chlorophenyl)-1H-pyrrole, 98%
| 5044-38-2 |
|
4-(2-Furyl)-3-Buten-2-One, 95%
| 623-15-4 |
|
2-Mercapto-5-nitrobenzimidazole, 97%
| 6325-91-3 |
|
(2-Pyrimidylthio)Acetic Acid, 98%
| 88768-45-0 |
|
Chromium(VI) oxide, flakes, 99.9%
| 1333-82-0 |
|
Chromium (III) Chloride Hexahydrate, 98%
| 10060-12-5 |
|
Chromium (III) Nitrate Nonahydrate, 99%
| 7789-02-8 |
|
Methyl 2-(Methylthio)Benzoate
| 3704-28-7 |
|
Cesium carbonate, 99.5%
| 534-17-8 |
|
Chromium(III) Oxide, 99%, Amorphous Powder
| 1308-38-9 |
|
FMOC-L-Alpha-Alanine, 98%
| 35661-39-3 |
|
(4-Chlorophenylthio)Acetic Acid
| 3405-88-7 |
|
Cobalt(II) Nitrate Hexahydrate, P.A.
| 10026-22-9 |
|
Cobalt (II,III) Oxide, - 325 Mesh
| 1308-06-1 |
|
Hematoxylin Hydrate, High Purity Biological Stain
| 1412-19-7 |
|
Cobalt (II) Acetate Tetrahydrate, 97%
| 6147-53-1 |
|
Cobalt(II) chloride hexahydrate, 99.999%
| 7791-13-1 |
|
Cobalt(II) sulfate heptahydrate, 99+%
| 10026-24-1 |
|
2-Naphthalenethiol, 99%
| 91-60-1 |
|
Collodion, Flexible
| 60-29-7 |
|
Strontium Fluoride, 99.99%
| 7783-48-4 |
|
4,4'-Azoxydiphenetole
| 4792-83-0 |
|
2,6,6-Trimethyl-2-cyclohexene-1,4-dione, 98%
| 1125-21-9 |
|
Tetraheptylammonium chloride
| 10247-90-2 |
|
2,3,4,5-Tetrafluorobenzoyl chloride, 99%
| 94695-48-4 |
|
2,3,4,5-Tetrafluorobenzotrifluoride, 99%
| 654-53-5 |
|
Copper Shot, 1-10 mm, 99.9%
| 7440-50-8 |
|
Cupferron, Reagent ACS
| 135-20-6 |
|
Methyl Phenylpropiolate, 98%
| 4891-38-7 |
|
Sodium Caprylate, 98%
| 1984-06-1 |
|
Agar
| 9002-18-0 |
|
Agarose
| 9012-36-6 |
|
Copper (II) Carbonate, Basic, 54-56% Copper
| 12069-69-1 |
|
Muscimol hydrate, 98+%
| 2763-96-4 |
|
Trans, Trans-1,3-Bis(4-Methoxybenzylidene)Acetone, 98%
| 2051-07-2 |
|
(S)-3-Hydroxy-gamma-butyrolactone, 97%
| 7331-52-4 |
|
Copper (II) Oxide, 98%
| 1317-38-0 |
|
Copper(II) sulfate, reagent, anhydrous, 98%
| 7758-98-7 |
|
Copper(II) sulfate pentahydrate, 98%
| 7758-98-7 |
|
Acetylcholine Bromide, 98%
| 66-23-9 |
|
|