**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7758-98-7 |Copper(II) sulfate | 98 | 231-847-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 22 36/38 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin. Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Exposure to particulates or solution may cause conjunctivitis,
ulceration, and corneal abnormalities. Causes eye irritation and
possible burns.
Skin:
Causes skin irritation and possible burns.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns. Ingestion of
large amounts of copper salts may cause bloody stools and vomit, low
blood pressure, jaundice and coma. Ingestion of copper compounds may
produce systemic toxic effects to the kidney and liver and central
nervous excitation followed by depression.
Inhalation:
May cause ulceration and perforation of the nasal septum if inhaled
in excessive quantities. Causes respiratory tract irritation with
possible burns.
Chronic:
May cause liver and kidney damage. May cause anemia and other blood
cell abnormalities. Individuals with Wilson's disease are unable to
metabolize copper. Thus, copper accumulates in various tissues and
may result in liver, kidney, and brain damage. Adverse reproductive
effects have been reported in animals. Laboratory experiments have
resulted in mutagenic effects. Chronic copper poisoning in man is
recognized in the form of Wilson's disease.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Individuals with Wilson's disease are more susceptible to chronic
copper poisoning.
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is noncombustible.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. U.S. regulations require reporting spills and
releases to soil, water and air in excess of reportable quantities.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid breathing dust.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7758-98-7:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: 0.5 mg/m3 TWA
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: light gray
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 200 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 560 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 3.6
Molecular Formula: CuO4S
Molecular Weight: 159.61
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
High temperatures, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Aqueous solution of copper(2+) sulfate is an acid. Incompatible with
strong bases, hydroxylamine, magnesium..
Hazardous Decomposition Products:
Oxides of sulfur, copper fumes.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7758-98-7: GL8800000
LD50/LC50:
CAS# 7758-98-7: Oral, mouse: LD50 = 369 mg/kg; Oral, mouse: LD50 =
87 mg/kg; Oral, rat: LD50 = 300 mg/kg; Oral, rat: LD50 = 960 mg/kg.
Carcinogenicity:
Copper(II) sulfate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.1-2.5 mg/L; 96 Hr; UnspecifiedFish:
Bluegill/Sunfish: LC50 = 0.6 mg/L; 48 Hr; 15 mg/L CaCO3Fish:
Bluegill/Sunfish: LC50 = 8.0 mg/L; 48 Hr; 68 mg/L CaCO3Fish:
Bluegill/Sunfish: LC50 = 10.0 mg/L; 48 Hr; 100 mg/L CaCO3Fish:
Bluegill/Sunfish: LC50 = 45.0 mg/L; 48 Hr; 132 mg/L CaCO3In soil,
copper sulfate is partly washed down to lower levels, partly bound
by soil components, and partly oxidatively transformed. Copper has a
strong affinity for hydrous iron and manganese oxides, clays,
carbonate minerals, and organic matter. Sorption to these materials
... suspended in the water column & in the bed sediments, results in
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Hazard Class: 9
UN Number: 3077
Packing Group: III
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 7758-98-7: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7758-98-7: 2
Canada
CAS# 7758-98-7 is listed on Canada's DSL List.
CAS# 7758-98-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7758-98-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/09/1999 Revision #4 Date: 4/22/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethyl(2,2-Diethoxypropyl)Phosphonate
| 0-01-1 |
|
Diethyl(2-Propenyl)Phosphonate
| 5954-65-4 |
|
2-Chloromandelic acid, 98%
| 10421-85-9 |
|
Chloroform, Reagent ACS, Spectro Grade
| 67-66-3 |
|
4,4'-Dimethylbiphenyl, 97%
| 613-33-2 |
|
Chloramphenicol, 98.0 - 102.0%
| 56-75-7 |
|
Chlorosulfonic acid, 98%
| 7790-94-5 |
|
Cholesterol, 95+% (gc)
| 57-88-5 |
|
Choline Chloride, P.A.
| 67-48-1 |
|
Propyl Bromoacetate, 98%
| 35223-80-4 |
|
1-(4-Chlorophenyl)-1H-pyrrole, 98%
| 5044-38-2 |
|
4-(2-Furyl)-3-Buten-2-One, 95%
| 623-15-4 |
|
2-Mercapto-5-nitrobenzimidazole, 97%
| 6325-91-3 |
|
(2-Pyrimidylthio)Acetic Acid, 98%
| 88768-45-0 |
|
Chromium(VI) oxide, flakes, 99.9%
| 1333-82-0 |
|
Chromium (III) Chloride Hexahydrate, 98%
| 10060-12-5 |
|
Chromium (III) Nitrate Nonahydrate, 99%
| 7789-02-8 |
|
Methyl 2-(Methylthio)Benzoate
| 3704-28-7 |
|
Cesium carbonate, 99.5%
| 534-17-8 |
|
Chromium(III) Oxide, 99%, Amorphous Powder
| 1308-38-9 |
|
FMOC-L-Alpha-Alanine, 98%
| 35661-39-3 |
|
(4-Chlorophenylthio)Acetic Acid
| 3405-88-7 |
|
Cobalt(II) Nitrate Hexahydrate, P.A.
| 10026-22-9 |
|
Cobalt (II,III) Oxide, - 325 Mesh
| 1308-06-1 |
|
Hematoxylin Hydrate, High Purity Biological Stain
| 1412-19-7 |
|
Cobalt (II) Acetate Tetrahydrate, 97%
| 6147-53-1 |
|
Cobalt(II) chloride hexahydrate, 99.999%
| 7791-13-1 |
|
Cobalt(II) sulfate heptahydrate, 99+%
| 10026-24-1 |
|
2-Naphthalenethiol, 99%
| 91-60-1 |
|
Collodion, Flexible
| 60-29-7 |
|
Strontium Fluoride, 99.99%
| 7783-48-4 |
|
4,4'-Azoxydiphenetole
| 4792-83-0 |
|
2,6,6-Trimethyl-2-cyclohexene-1,4-dione, 98%
| 1125-21-9 |
|
Tetraheptylammonium chloride
| 10247-90-2 |
|
2,3,4,5-Tetrafluorobenzoyl chloride, 99%
| 94695-48-4 |
|
2,3,4,5-Tetrafluorobenzotrifluoride, 99%
| 654-53-5 |
|
Copper Shot, 1-10 mm, 99.9%
| 7440-50-8 |
|
Cupferron, Reagent ACS
| 135-20-6 |
|
Methyl Phenylpropiolate, 98%
| 4891-38-7 |
|
Sodium Caprylate, 98%
| 1984-06-1 |
|
Agar
| 9002-18-0 |
|
Agarose
| 9012-36-6 |
|
Copper (II) Carbonate, Basic, 54-56% Copper
| 12069-69-1 |
|
Muscimol hydrate, 98+%
| 2763-96-4 |
|
Trans, Trans-1,3-Bis(4-Methoxybenzylidene)Acetone, 98%
| 2051-07-2 |
|
(S)-3-Hydroxy-gamma-butyrolactone, 97%
| 7331-52-4 |
|
Copper (II) Oxide, 98%
| 1317-38-0 |
|
Copper(II) sulfate, reagent, anhydrous, 98%
| 7758-98-7 |
|
Copper(II) sulfate pentahydrate, 98%
| 7758-98-7 |
|
Acetylcholine Bromide, 98%
| 66-23-9 |
|
|