**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7758-99-8 |Copper(II) sulfate pentahydrate | 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN
Risk Phrases: 22 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes and skin.Air
sensitive.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Exposure to particulates or solution may cause conjunctivitis,
ulceration, and corneal abnormalities. Causes eye irritation and
possible burns.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. Causes skin irritation
and possible burns. May cause itching eczema.
Ingestion:
Harmful if swallowed. May cause severe gastrointestinal tract
irritation with nausea, vomiting and possible burns. Ingestion of
large amounts of copper salts may cause bloody stools and vomit, low
blood pressure, jaundice and coma. Ingestion of copper compounds may
produce systemic toxic effects to the kidney and liver and central
nervous excitation followed by depression.
Inhalation:
May cause ulceration and perforation of the nasal septum if inhaled
in excessive quantities. Causes respiratory tract irritation with
possible burns.
Chronic:
Prolonged or repeated eye contact may cause conjunctivitis. May
cause liver and kidney damage. May cause anemia and other blood cell
abnormalities. Individuals with Wilson's disease are unable to
metabolize copper. Thus, copper accumulates in various tissues and
may result in liver, kidney, and brain damage. Laboratory
experiments have resulted in mutagenic effects. May cause allergic
skin reaction in some individuals. Chronic copper poisoning in man is
recognized in the form of Wilson's disease.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Individuals with Wilson's disease are more susceptible to chronic
copper poisoning.
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is noncombustible. This material in sufficient quantity and reduced
particle size is capable of creating a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Place under an inert atmosphere.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Do not ingest or inhale. Handle under an inert
atmosphere. Store protected from air.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Do not expose
to air. Store protected from moisture. Store under an inert
atmosphere.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7758-98-7:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: 0.5 mg/m3 TWA
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
CAS# 7758-99-8:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: (listed as copper): 1 mg/m3 TWA (dust)
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: blue
Odor: Odorless
pH: Not available.
Vapor Pressure: 7.3 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 150 deg C (dec)
Freezing/Melting Point: 110 deg C (dec)
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density: 2.2840g/cm3
Molecular Formula: CuO4S.5H2O
Molecular Weight: 249.68
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Air sensitive.
Conditions to Avoid:
High temperatures, incompatible materials, dust generation, exposure
to air, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, air, steel, finely powdered metals, hydroxylamine,
magnesium, hydrazine, nitromethane.
Hazardous Decomposition Products:
Oxides of sulfur, irritating and toxic fumes and gases, oxides of
copper, copper fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7758-98-7: GL8800000
CAS# 7758-99-8: GL8900000
LD50/LC50:
CAS# 7758-98-7: Oral, mouse: LD50 = 369 mg/kg; Oral, mouse: LD50 =
87 mg/kg; Oral, rat: LD50 = 300 mg/kg; Oral, rat: LD50 = 960 mg/kg.
CAS# 7758-99-8: Oral, mouse: LD50 = 43 mg/kg; Oral, rat: LD50 = 300
mg/kg; Skin, rat: LD50 = >2 gm/kg.
Carcinogenicity:
Cupric sulfate anhydrous -
Not listed by ACGIH, IARC, or NTP.
Copper(II) sulfate pentahydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 0.1-2.5 mg/L; 96 Hr; UnspecifiedFish:
Harlequin fish: LC50 =0.1-2.5 mg/L; 96 Hr; UnspecifiedFish: Goldfish:
LC50 = 0.1-2.5 mg/L; 96 Hr; UnspecifiedWater flea Daphnia: EC50 =
0.24 mg/L; 48 Hr; UnspecifiedIn soil, copper sulfate is partly washed
down to lower levels, partly bound by soil components, and partly
oxidatively transformed. Copper has a strong affinity for hydrous
iron and manganese oxides, clays, carbonate minerals, and organic
matter. Sorption to these materials ... suspended in the water column
& in the bed sediments, results in relative enrichment of the solid
phase and reduction in dissolved levels.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7758-98-7: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 7758-98-7: 2
CAS# 7758-99-8: 2
Canada
CAS# 7758-98-7 is listed on Canada's DSL List.
CAS# 7758-98-7 is listed on Canada's Ingredient Disclosure List.
CAS# 7758-99-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7758-98-7 is listed on the TSCA inventory.
CAS# 7758-99-8 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 7/09/1999 Revision #3 Date: 9/22/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Diethyl(2,2-Diethoxypropyl)Phosphonate
| 0-01-1 |
|
Diethyl(2-Propenyl)Phosphonate
| 5954-65-4 |
|
2-Chloromandelic acid, 98%
| 10421-85-9 |
|
Chloroform, Reagent ACS, Spectro Grade
| 67-66-3 |
|
4,4'-Dimethylbiphenyl, 97%
| 613-33-2 |
|
Chloramphenicol, 98.0 - 102.0%
| 56-75-7 |
|
Chlorosulfonic acid, 98%
| 7790-94-5 |
|
Cholesterol, 95+% (gc)
| 57-88-5 |
|
Choline Chloride, P.A.
| 67-48-1 |
|
Propyl Bromoacetate, 98%
| 35223-80-4 |
|
1-(4-Chlorophenyl)-1H-pyrrole, 98%
| 5044-38-2 |
|
4-(2-Furyl)-3-Buten-2-One, 95%
| 623-15-4 |
|
2-Mercapto-5-nitrobenzimidazole, 97%
| 6325-91-3 |
|
(2-Pyrimidylthio)Acetic Acid, 98%
| 88768-45-0 |
|
Chromium(VI) oxide, flakes, 99.9%
| 1333-82-0 |
|
Chromium (III) Chloride Hexahydrate, 98%
| 10060-12-5 |
|
Chromium (III) Nitrate Nonahydrate, 99%
| 7789-02-8 |
|
Methyl 2-(Methylthio)Benzoate
| 3704-28-7 |
|
Cesium carbonate, 99.5%
| 534-17-8 |
|
Chromium(III) Oxide, 99%, Amorphous Powder
| 1308-38-9 |
|
FMOC-L-Alpha-Alanine, 98%
| 35661-39-3 |
|
(4-Chlorophenylthio)Acetic Acid
| 3405-88-7 |
|
Cobalt(II) Nitrate Hexahydrate, P.A.
| 10026-22-9 |
|
Cobalt (II,III) Oxide, - 325 Mesh
| 1308-06-1 |
|
Hematoxylin Hydrate, High Purity Biological Stain
| 1412-19-7 |
|
Cobalt (II) Acetate Tetrahydrate, 97%
| 6147-53-1 |
|
Cobalt(II) chloride hexahydrate, 99.999%
| 7791-13-1 |
|
Cobalt(II) sulfate heptahydrate, 99+%
| 10026-24-1 |
|
2-Naphthalenethiol, 99%
| 91-60-1 |
|
Collodion, Flexible
| 60-29-7 |
|
Strontium Fluoride, 99.99%
| 7783-48-4 |
|
4,4'-Azoxydiphenetole
| 4792-83-0 |
|
2,6,6-Trimethyl-2-cyclohexene-1,4-dione, 98%
| 1125-21-9 |
|
Tetraheptylammonium chloride
| 10247-90-2 |
|
2,3,4,5-Tetrafluorobenzoyl chloride, 99%
| 94695-48-4 |
|
2,3,4,5-Tetrafluorobenzotrifluoride, 99%
| 654-53-5 |
|
Copper Shot, 1-10 mm, 99.9%
| 7440-50-8 |
|
Cupferron, Reagent ACS
| 135-20-6 |
|
Methyl Phenylpropiolate, 98%
| 4891-38-7 |
|
Sodium Caprylate, 98%
| 1984-06-1 |
|
Agar
| 9002-18-0 |
|
Agarose
| 9012-36-6 |
|
Copper (II) Carbonate, Basic, 54-56% Copper
| 12069-69-1 |
|
Muscimol hydrate, 98+%
| 2763-96-4 |
|
Trans, Trans-1,3-Bis(4-Methoxybenzylidene)Acetone, 98%
| 2051-07-2 |
|
(S)-3-Hydroxy-gamma-butyrolactone, 97%
| 7331-52-4 |
|
Copper (II) Oxide, 98%
| 1317-38-0 |
|
Copper(II) sulfate, reagent, anhydrous, 98%
| 7758-98-7 |
|
Copper(II) sulfate pentahydrate, 98%
| 7758-98-7 |
|
Acetylcholine Bromide, 98%
| 66-23-9 |
|
|