**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 139-59-3 |4-Phenoxyaniline | 97% | 205-367-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 22 40 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Limited evidence of a carcinogenic effect. May
cause sensitization by skin contact. Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Possible risk of irreversible effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not allow water to get into the
container because of violent reaction. Avoid breathing dust, vapor,
mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 139-59-3:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: brown - green
Odor: weak odor
pH: Not available.
Vapor Pressure: 13.3 hPa @180 deg C
Viscosity: Not available.
Boiling Point: 140 deg C @3hPa
Freezing/Melting Point: 82-86 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 385 deg C
Solubility in water: <1g/l in water (20C)
Specific Gravity/Density:
Molecular Formula: C12H11NO
Molecular Weight: 185.22
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, acid anhydrides, chlorides.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 139-59-3: BY7930000
LD50/LC50:
CAS# 139-59-3: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Mild.
Carcinogenicity:
4-Phenoxyaniline -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 24 Avoid contact with skin.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 139-59-3: No information available.
Canada
CAS# 139-59-3 is listed on Canada's NDSL List.
CAS# 139-59-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 139-59-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/06/2000 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Hexadecyltrimethylammonium hydroxide (25% in methanol)
| 67-56-1 |
|
d-(-)-alpha-Phenylglycine, 98%
| 875-74-1 |
|
1,2-Ethanedithiol, 99+% (GC)
| 540-63-6 |
|
Guaiazulene, 99%
| 489-84-9 |
|
Triethylsilane, 99%
| 617-86-7 |
|
5-Chloro-2-Methylindole, 95%
| 1075-35-0 |
|
Uridine 5'-diphosphate, trisodium salt hydrate
| 19817-91-5 |
|
Coumarin 337, Laser Grade, 99% (UV-Vis)
| 55804-68-7 |
|
5,7-Dimethyl-4-Hydroxypyrido(2,3-D)-Pyrimidine, 98%
| 0-00-1 |
|
beta-Naphthoflavone, 99+%
| 6051-87-2 |
|
1,4-Thioxane-1,1-Dioxide, 99+%
| 107-61-9 |
|
o-Toluic acid, 98+%
| 118-90-1 |
|
1-Bromo-2-iodobenzene, 99%, stabilized with copper
| 583-55-1 |
|
2-Methylheptane, 99%
| 592-27-8 |
|
Pyrrolidone Hydrotribromide, 97%
| 52215-12-0 |
|
Benzyl Methyl Ether, 99%
| 538-86-3 |
|
Pyrazinamide, 99%
| 98-96-4 |
|
3,6-exo-oxo-1,2,3,6-tetrahydrophthalic anhydride
| 5426-09-5 |
|
4-Chlorobenzoyl chloride
| 122-01-0 |
|
Bis-(2-Chloroethyl)-Amine Hydrochloride, 98%
| 821-48-7 |
|
1-Chloro-2-methylpropane, 98%
| 513-36-0 |
|
D(+)-Malic acid, 98%
| 636-61-3 |
|
N-Hydroxyphthalimide, 99% (Titr., Dry Subst., Remainder 10-15%
| 524-38-9 |
|
Ethylamine hydrochloride, 99%
| 557-66-4 |
|
1,2,4-Trifluorobenzene, 97+%
| 367-23-7 |
|
4-Pentyloxyaniline, 99%
| 39905-50-5 |
|
p-Methoxycinnamic acid, 99% (titr.)
| 830-09-1 |
|
3-(Methylthio)-1-Propanol, 98%
| 505-10-2 |
|
Pararosaniline Base
| 25620-78-4 |
|
4-Amino-1,8-naphthalimide, 98%
| 1742-95-6 |
|
P-Toluic Hydrazide, 98%
| 3619-22-5 |
|
Methylhydroquinone, 99%
| 95-71-6 |
|
1,4-Diaminobutane, 99%
| 110-60-1 |
|
Acid Red 88
| 1658-56-6 |
|
Azodicarbonamide, 97%
| 123-77-3 |
|
4-Phenoxyaniline, 97%
| 139-59-3 |
|
(R)-(+)-sec-Phenethyl alcohol, 99%
| 1517-69-7 |
|
(S)-(-)-N-Benzyl-Alpha-Methylbenzylamine, 98%
| 17480-69-2 |
|
4-Pentylbenzoyl Chloride, 99%
| 49763-65-7 |
|
L-(+)-Norvaline, 99%
| 6600-40-4 |
|
Cortexolone, 99%
| 152-58-9 |
|
1-Nonene, 99%
| 124-11-8 |
|
2-Amino-5-Ethyl-1,3,4-Thiadiazole, 98+%
| 14068-53-2 |
|
2,3,7-Trimethylindole
| 27505-78-8 |
|
5-[(4,6-Dichlorotriazin-2-yl)amino] fluorescein hydrochloride, 99%
| 21799-87-1 |
|
3-(2-Isothiocyanatoethyl-carbamoyl)-PROXYL, free radical
| 100929-92-8 |
|
1-Dodecanol, 98%
| 112-53-8 |
|
(3-Mercaptopropyl)trimethoxysilane tech. 85%
| 67-56-1 |
|
Sparkleen 2
| 497-19-8 |
|
N-(2-Hydroxyethyl)Piperazine, 98%
| 103-76-4 |
|
|