**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 497-19-8 |Sodium carbonate anhydrous | < 40 | 207-838-8 |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 6834-92-0 |Sodium metasilicate | < 20 | 229-912-9 |
|----------------|--------------------------------------|----------|-----------|
| 7757-82-6 |Sodium sulfate anhydrous | 10 | 231-820-9 |
|----------------|--------------------------------------|----------|-----------|
| 7758-29-4 |Sodium tripolyphosphate | 36 | 231-838-7 |
|----------------|--------------------------------------|----------|-----------|
| 51580-86-0 |Sodium dichloroisocyanurate, dihydrate| < 10 | unlisted |
| | | | |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: O C N
Risk Phrases: 31 34 8 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with acids liberates toxic gas. Causes burns. Contact with
combustible material may cause fire. Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
Contact with skin causes irritation and possible burns, especially
if the skin is wet or moist.
Ingestion:
May cause severe digestive tract irritation with abdominal pain,
nausea, vomiting and diarrhea.
Inhalation:
May cause severe irritation of the upper respiratory tract with
pain, burns, and inflammation.
Chronic:
Prolonged or repeated contact with concentrated solutions causes
tissue damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
Get medical aid immediately. In case of contact, immediately wipe
away excess material with a dry cloth while removing contaminated
clothing and shoes. Under safety shower, wash affected areas
thoroughly with large amounts of water, and soap if available, for at
least 15 minutes. Discard or decontaminate clothing and shoes.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Oxidizer. Greatly increases the burning rate of
combustible materials. Aqueous solutions at 10% or greater of sodium
metasilicate are corrosive to skin and to aluminum.
Extinguishing Media:
Water is a suitable extinguishing media. Do not use dry chemical
extinguisher containing ammonia compounds.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Do not get in eyes, on skin, or on
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Keep from contact with clothing and other combustible
materials. Do not use Sparkleen 2 for cleaning of rubber,
silverware, aluminum, tinned metal, galvanized metal, brass, or
other materials harmed by alkaline chlorine solutions.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from flammable liquids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 497-19-8:
Russia: 5 mg/m3 TWA
CAS# 2893-78-9:
CAS# 6834-92-0:
CAS# 7757-82-6:
Russia: 10 mg/m3 TWA
CAS# 7758-29-4:
CAS# 51580-86-0:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Granules
Color: white
Odor: chlorine-like
pH: 12.1 (0.5% soln)
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Approx. 10% in water @ 25C
Specific Gravity/Density: Not available.
Molecular Formula: Mixture
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong reducing agents, acids, aluminum, organic matter.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, nitrogen oxides, carbon monoxide, carbon
dioxide, toxic fumes of sodium oxide, nitrogen trichloride.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 497-19-8: VZ4050000
CAS# 2893-78-9: XZ1900000
CAS# 6834-92-0: VV9275000
CAS# 7757-82-6: WE1650000
CAS# 7758-29-4: YK4570000
CAS# 51580-86-0: XZ1910000
LD50/LC50:
CAS# 497-19-8: Draize test, rabbit, eye: 100 mg/24H Moderate; Draize
test, rabbit, eye: 50 mg Severe; Draize test, rabbit, skin: 500
mg/24H Mild; Inhalation, mouse: LC50 = 1200 mg/m3/2H; Inhalation,
rat: LC50 = 2300 mg/m3/2H; Oral, mouse: LD50 = 6600 mg/kg; Oral,
mouse: LD50 = 6600 mg/kg; Oral, rat: LD50 = 4090 mg/kg.
CAS# 2893-78-9: Draize test, rabbit, eye: 100 mg/24H Mild; Draize
test, rabbit, skin: 500 mg/24H Mild; Draize test, rabbit, skin: 500
mg Severe; Oral, rat: LD50 = 1420 mg/kg.
CAS# 6834-92-0: Draize test, rabbit, skin: 250 mg/24H Severe; Oral,
mouse: LD50 = 770 mg/kg; Oral, rat: LD50 = 1153 mg/kg.
CAS# 7757-82-6: Oral, mouse: LD50 = 5989 mg/kg.
CAS# 7758-29-4: Draize test, rabbit, skin: 500 mg/24H Moderate;
Oral, mouse: LD50 = 3100 mg/kg; Oral, rat: LD50 = 3120 mg/kg; Skin,
rabbit: LD50 = >4640 mg/kg.
CAS# 51580-86-0.
Carcinogenicity:
Sodium carbonate anhydrous -
Not listed by ACGIH, IARC, or NTP.
Dichloroisocyanuric acid, sodium salt, anhydrous -
Not listed by ACGIH, IARC, or NTP.
Sodium metasilicate -
Not listed by ACGIH, IARC, or NTP.
Sodium sulfate anhydrous -
Not listed by ACGIH, IARC, or NTP.
Sodium tripolyphosphate -
Not listed by ACGIH, IARC, or NTP.
Sodium dichloroisocyanurate, dihydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Aquatic toxicity data for Sodium dichloroisocyanurate dihydrate:
96
hr LC50 rainbow trout: 0.22 mg/l
96 hr LC50 bluegill sunfish: 0.28
mg/l
48 hr LC50 (Daphnia magna): 0.2 mg/l.
Other
When too many nutrients such as phosphorus are in the water, algae
grows maniacally. Algae blooms are followed by a die-off, and as
material decays, it consumes oxygen like a forest fire. No fish,
plants or insects can live in oxygen-free zones.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing Group: III
IMO
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing Group: III
RID/ADR
Shipping Name: OXIDIZING SOLID, CORROSIVE, N.O.S.
Hazard Class: 5.1
UN Number: 3085
Packing group: III
USA RQ: CAS# 7758-29-4: 5000 lb final RQ (Listed under Sodium phosphate, tribasi
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C N
Risk Phrases:
R 31 Contact with acids liberates toxic gas.
R 34 Causes burns.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 8 Keep container dry.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 41 In case of fire and/or explosion do not breathe
fumes.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 497-19-8: 1
CAS# 2893-78-9: 2
CAS# 6834-92-0: 1
CAS# 7757-82-6: 0
CAS# 7758-29-4: 1
CAS# 51580-86-0: No information available.
Canada
CAS# 497-19-8 is listed on Canada's DSL List.
CAS# 2893-78-9 is listed on Canada's DSL List.
CAS# 6834-92-0 is listed on Canada's DSL List.
CAS# 7757-82-6 is listed on Canada's DSL List.
CAS# 7758-29-4 is listed on Canada's DSL List.
CAS# 497-19-8 is listed on Canada's Ingredient Disclosure List.
CAS# 2893-78-9 is listed on Canada's Ingredient Disclosure List.
CAS# 6834-92-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7757-82-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 7758-29-4 is not listed on Canada's Ingredient Disclosure List.
CAS# 51580-86-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 497-19-8 is listed on the TSCA inventory.
CAS# 2893-78-9 is listed on the TSCA inventory.
CAS# 6834-92-0 is listed on the TSCA inventory.
CAS# 7757-82-6 is listed on the TSCA inventory.
CAS# 7758-29-4 is listed on the TSCA inventory.
CAS# 51580-86-0 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 7/12/1999 Revision #5 Date: 7/14/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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