**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 14508-49-7 |2-Chloropyrazine | 98% | 238-517-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: 10
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause central nervous
system depression.
Inhalation:
May cause respiratory tract irritation. Aspiration may lead to
pulmonary edema. Vapors may cause dizziness or suffocation. May cause
cardiac abnormalities. Inhalation at high concentrations may cause
CNS depression and asphixiation. May cause burning sensation in the
chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor.
Combustible liquid. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Containers
may explode when heated. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Do NOT use straight streams of water. For large fires,
use water spray, fog or regular foam. For small fires, use dry
chemical, carbon dioxide, water spray or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 14508-49-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless - yellowish
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 153.0 - 154.0 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 57 deg C ( 134.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density: 1.2830g/cm3
Molecular Formula:
Molecular Weight: 114.53
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, light, ignition sources, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, irritating and
toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 14508-49-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Chloropyrazine -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 14508-49-7: No information available.
Canada
CAS# 14508-49-7 is listed on Canada's NDSL List.
CAS# 14508-49-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14508-49-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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(-)-beta-Pinene, 98%
| 18172-67-3 |
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2-Chloro-3-Nitropyridine, 99+%
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|
2,4,6-Tri(2-Pyridyl)-S-Triazine, 99% (titr.)
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1,3-Cyclohexanedione, 97% stabilized with 3% sodium chloride
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2,4,6-Tri-Tert-Butylnitrobenzene, 99%
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Oxalacetic acid, 98% (titr.)
| 328-42-7 |
|
All-Trans-Retinol, 99%+(TLC)
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2-Bromo-4-Chlorophenol, 99+%
| 695-96-5 |
|
3-Fluorobenzamide, 99%
| 455-37-8 |
|
2-Chloro-6-fluorotoluene, 97%
| 443-83-4 |
|
1-Methyl-4-(methylamino)piperidine, tech., 90%
| 73579-08-5 |
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11-Aminoundecanoic Acid, 99%
| 2432-90-8 |
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Cadmium iodide, 99%
| 7790-80-9 |
|
3-Amino-L-Tyrosine Dihydrochloride Mono- Hydrate
| 23279-22-3 |
|
N,N-Dipropylacetamide, 99+% (GC)
| 1116-24-1 |
|
Cyclododecane Epoxide, 99% (Mixture of Cis and Trans Isomers)
| 286-99-7 |
|
4-Methyl-2-Oxopentanoic Acid, Sodium Salt, Hydrate, 98+%
| 332360-07-3 |
|
Dl-isoproterenol hydrochloride, 98%
| 949-36-0 |
|
Rhenium, powder, 99.99%
| 7440-15-5 |
|
5,6-Dihydro-2,4,4,6-Tetramethyl-4H-1,3-Oxazine, Tech., 85%
| 26939-18-4 |
|
alpha-Naphthoflavone, 99.5+%
| 604-59-1 |
|
Trimethylsilyl cyanide, 98%
| 7677-24-9 |
|
2-Chloropyrazine,98%
| 14508-49-7 |
|
2-Formylbenzenesulfonic Acid, Sodium Salt, Tech. 90%
| 1008-72-6 |
|
4-Bromoisoquinoline, 98%
| 1532-97-4 |
|
Cyclopentylacetic acid, 97%
| 1123-00-8 |
|
Methyl diethylphosphonoacetate, 98%
| 1067-74-9 |
|
(4-Fluorophenyl)-(2-thienyl) ketone, 97%
| 579-49-7 |
|
2-Amino-6-picoline, 98%
| 1824-81-3 |
|
(r)-4-Isopropyl-2-oxazolidinone, 99% (99% e.e.)
| 95530-58-8 |
|
Pyridine hydrochloride, 98%
| 628-13-7 |
|
(2R)-Bornane-10,2-Sultam, 99+% (>99% e.e.)
| 94594-90-8 |
|
3-Dimethylamino-1-propanol, 99%
| 3179-63-3 |
|
2-Adamantanamine hydrochloride, 99%
| 10523-68-9 |
|
2-Fluorophenol, 98%
| 367-11-3 |
|
3-Picoline-n-oxide, 98%
| 1003-73-2 |
|
Aurintricarboxylic Acid, Trisodium Salt
| 13186-45-3 |
|
2-Piperidineethanol, 95%
| 1484-84-0 |
|
4-Hydroxycinnamic Acid, 98% Predominantly Trans
| 501-98-4 |
|
3-Hydroxytyramine Hydrochloride, 99%
| 62-31-7 |
|
9-Methyl-Delta-5(10)-Octaline-1,6-Dione, 99%
| 20007-72-1 |
|
Ruthenium red
| 11103-72-3 |
|
1,4-Butanediol, 99+%
| 110-63-4 |
|
2-(4-Chlorophenyl)malondialdehyde, 95+% (NMR)
| 0-00-1 |
|
Carbazole, 96%
| 86-74-8 |
|
Indigo, Synthetic
| 482-89-3 |
|
1,3,5-Benzenetricarboxylic acid, 98%
| 554-95-0 |
|
Nile Blue A (Cert)
| 2381-85-3 |
|
2,2,5,5-Tetramethyl-4-Ethyl-3-Imidazoline- - 3-Oxide-1-Oxyl, Free
| 66582-85-2 |
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2-Hydroxyethyl acetate (prac)
| 542-59-6 |
|
|