**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 157373-08-5 |2,3,4-Trifluorobenzoyl chloride | 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution. Combustible
liquid and vapor. Use of water will produce irritating and toxic
vapors of hydrogen chloride. Hydrochloric acid solutions react with
most metals, forming flammable hydrogen gas.
Extinguishing Media:
Use dry powder or carbon dioxide.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Do not breathe dust, vapor, mist, or
gas. Do not get in eyes, on skin, or on clothing. Empty containers
retain product residue, (liquid and/or vapor), and can be dangerous.
Keep container tightly closed. Do not ingest or inhale. Use only in a
chemical fume hood. Discard contaminated shoes. Do not pressurize,
cut, weld, braze, solder, drill, grind, or expose empty containers
to heat, sparks or open flames. Keep from contact with moist air and
steam. Keep away from heat and flame.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 157373-08-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 143-144 deg C @ 130 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 92 deg C ( 197.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.522
Molecular Formula: C7H2ClF3O
Molecular Weight: 194.54
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Moisture sensitive.
Conditions to Avoid:
Ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, hydrogen fluoride
gas.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 157373-08-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,3,4-Trifluorobenzoyl chloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
IMO
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3265
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 157373-08-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 157373-08-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 157373-08-5 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/12/2000 Revision #5 Date: 9/29/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dichloromethane, extra dry, with molecular sieve, water < 50 ppm
| 75-09-2 |
|
Potassium Carbonate Sesquihydrate
| 584-08-7 |
|
Urazole, 97%
| 3229-73-0 |
|
(4S)-(-)-4-Isopropyl-2-oxazolidinone, 98%
| 17016-83-0 |
|
DL-5-Hydroxytryptophan, 99%
| 114-03-4 |
|
(4R)-(+)-4-Isopropyl-2-Oxazolidinone, 98%
| 95530-58-8 |
|
Ethyl 4-etoxybenzoate, 97%
| 23676-09-7 |
|
2,2,4-Trimethyl-1,3-pentanediol, 96% (gc)
| 144-19-4 |
|
Phenylmercuric nitrate, 62.5 - 64.0% Mercury
| 8003-05-2 |
|
Toluidine Blue O
| 92-31-9 |
|
Bentonite
| 1302-78-9 |
|
Nitrilotris(Methylene)Triphosphonic Acid 50 wt% Solution in Water
| 6419-19-8 |
|
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride
| 72287-26-4 |
|
1,3-Dimethylcyclohexane, mixture of cis and trans, 90%
| 591-21-9 |
|
3-(Dimethylamino)acrylonitrile
| 2407-68-3 |
|
Adenine, 99%
| 73-24-5 |
|
2,4-Dimethyl-2,6-heptadien-1-ol, mixture of isomers, 96%
| 80192-56-9 |
|
Cyclopropyl [4-(1,1-Dimethylethyl)Phenyl]- Methanone
| 38675-79-5 |
|
2,6-Dithiopurine
| 5437-25-2 |
|
N-Carbobenzyloxy-L-isoleucine, 97%
| 3160-59-6 |
|
4,4'-Dichlorobenzhydrol
| 90-97-1 |
|
1-Aminobenzotriazole, 98%
| 1614-12-6 |
|
Succinimide, 98%
| 123-56-8 |
|
N,N'-Dicyclohexylcarbodiimide, 25% solution in acetone
| 67-64-1 |
|
Cyclopropylamine, 80% solution in water, special grade for Novartis
| 765-30-0 |
|
4-Methylcatechol, 95%
| 452-86-8 |
|
N-(2-Hydroxyethyl)ethylenediaminetriacetic acid trisodium salt
| 139-89-9 |
|
Gallocyanine, chloride free
| 524-26-5 |
|
tert.-Butyl methyl sulfide, 97%
| 6163-64-0 |
|
5-Methylquinoxaline, 98%
| 13708-12-8 |
|
2-Methyl-3-propylpyrazine, 97%
| 15986-80-8 |
|
3-Acetyl-2,5-Dimethylfuran, 98%
| 10599-70-9 |
|
(s,s)-chiraphos, 97%
| 64896-28-2 |
|
cis-4-Hydroxy-D-proline, 99%
| 2584-71-6 |
|
Benzene
| 71-43-2 |
|
Tetraethylthiuram disulfide, 97%
| 97-77-8 |
|
1,2-Bis(trimethylsilyloxy)cyclobutene
| 17082-61-0 |
|
6-Hydroxy-2-naphthoic acid
| 16712-64-4 |
|
4-Hydroxypyridine
| 626-64-2 |
|
2,4,6-Trifluorobenzoyl chloride
| 79538-29-7 |
|
2,3,5,6-Tetrafluorobenzoyl chloride, 98%
| 107535-73-9 |
|
2,3-Dihydroxypyridine, 98%
| 16867-04-2 |
|
2,3,4,5-Tetrafluorobenzaldehyde
| 0-01-1 |
|
2,3,4-Trifluorobenzoyl chloride
| 157373-08-5 |
|
2,3,5,6-Tetrafluorobenzaldehyde
| 19842-76-3 |
|
2,3,5,6-Tetrafluorobenzoic acid
| 652-18-6 |
|
4-Bromo-2-fluorobenzoic acid
| 164149-28-4 |
|
2-Chloro-4-fluorobenzoic acid
| 2252-51-9 |
|
3-Mercapto-1-hexanol, 98%
| 51755-83-0 |
|
2-Isopropyl-4-methylthiazole, 99%
| 15679-13-7 |
|
|